Pesticidal compositions and methods

Patent metadata

Field	Value
Publication number	US-11332452-B2
Application number	US-202017263928-A
Country	US
Kind code	B2
Filing date	Jan 30, 2020
Priority date	Feb 4, 2019
Publication date	May 17, 2022
Grant date	May 17, 2022

Abstract

This disclosure relates to the field of molecules having pesticidal utility against pests in phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the structure of Formula A.

First claim

We claim:

1. The molecule having the structure of Formula One, Formula Two, or Formula Three:

wherein:
(A) AR 1 is a substituted phenyl having one or more substituents independently selected from C 1 -C 6 haloalkyl and C 1 -C 6 haloalkoxy;
(B) L 1 is selected from the group consisting of:

wherein R 5 is selected from H, C 1 -C 8 alkyl, C 1 -C 8 haloalkyl, C 1 -C 8 alkoxy, C 1 -C 8 haloalkoxy, phenyl, or substituted phenyl, wherein said substituted phenyl has one or more substituents selected from H, F, Cl, Br, I, CN, NO 2 , NR x R y , C 1 -C 8 alkyl, C 1 -C 8 haloalkyl, C 3 -C 8 cycloalkyl, C 3 -C 8 halocycloalkyl, C 3 -C 8 cycloalkoxy, C 3 -C 8 halocycloalkoxy, C 1 -C 8 alkoxy, C 1 -C 8 haloalkoxy, C 2 -C 8 alkenyl, C 3 -C 8 cycloalkenyl, C 2 -C 8 haloalkenyl, C 3 -C 8 halocycloalkenyl, and C 2 -C 8 alkynyl;
(C) Ar 2 is a phenyl;
(D) each R 6 , R 7 , R 8 , and R 9 is selected from H, F, Cl, Br, and C 1 -C 6 alkyl;
(E) Q 1 is O or S;
(F) Q 2 is O or S;
(G) R 2 and R 3 is a 1- to 4-membered saturated or unsaturated, hydrocarbyl link, and together with (Q 2 )(C)(N) forms a 4- to 7-membered cyclic structure, wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO 2 , NR x R y , C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, S(═O) n (C 1 -C 6 alkyl), S(═O) n (C 1 -C 6 haloalkyl), phenyl, and oxo;
(H) R 4 is phenyl, wherein the phenyl may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO 2 , NR x R y , C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 cycloalkyl, C 3 -C 6 halocycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, (C 1 -C 6 alkyl)O(C 1 -C 6 alkyl), (C 1 -C 8 alkyl)O(C 1 -C 8 haloalkyl), (C 1 -C 6 alkyl)S(═O) n (C 1 -C 6 alkyl), C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, S(═O) n (C 1 -C 6 alkyl), S(═O) n (C 1 -C 6 haloalkyl), phenyl, and oxo, or wherein two adjacent substituents form a 5- or 6-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO 2 , NR x R y , C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, S(═O) n (C 1 -C 6 alkyl), and S(═O) n (C 1 -C 6 haloalkyl);
(I) R x and R y are independently selected from H, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 cycloalkyl, C 3 -C 6 halocycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, and phenyl; and
(J) n is each individually 0, 1, or 2.

2. The molecule of claim 1 , wherein R 2 and R 3 is 1- to 4-membered saturated or unsaturated, hydrocarbyl link and together with (Q 2 )(C)(N) forms a 5-membered cyclic structure, wherein said hydrocarbyl link is optionally substituted with H, OH, F, Cl, Br, I, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkoxy, or C 1 -C 6 haloalkoxy.

3. The molecule of claim 1 , wherein AR 1 is a substituted phenyl having one or more substituents independently selected from OCF 3 , OCF 2 CF 3 , and CF 3 .

4. The molecule of claim 1 , wherein L 1 is selected from the group consisting of:

wherein R 5 is selected from H, C 1 -C 8 alkyl, C 1 -C 8 haloalkyl, C 1 -C 8 alkoxy, C 1 -C 8 haloalkoxy, phenyl, and substituted phenyl,
wherein said substituted phenyl has one or more substituents selected from H, F, Cl, Br, I, CN, NO 2 , NR x R y , C 1 -C 8 alkyl, C 1 -C 8 haloalkyl, C 3 -C 8 cycloalkyl, C 3 -C 8 halocycloalkyl, C 3 -C 8 cycloalkoxy, C 3 -C 8 halocycloalkoxy, C 1 -C 8 alkoxy, C 1 -C 8 haloalkoxy, C 2 -C 8 alkenyl, C 3 -C 8 cycloalkenyl, C 2 -C 8 haloalkenyl, C 3 -C 8 halocycloalkenyl, and C 2 -C 8 alkynyl.

5. The molecule of claim 1 , wherein each of R 6 , R 7 , R 8 , and R 9 is independently H, F, Cl, or a C 1 -C 6 alkyl.

6. The molecule of claim 1 , wherein R 4 is a substituted phenyl with one or more H, F, Cl, Br, I, C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 3 -C 6 cycloalkyl, C 2 -C 6 alkenyl, C 2 -C 6 haloalkenyl, (C 1 -C 6 alkyl)O(C 1 -C 6 alkyl), C 1 -C 6 alkoxy, or C 1 -C 6 haloalkoxy, or wherein two adjacent substituents form a 5- or 6-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO 2 , NR x R y , C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, C 1 -C 6 alkoxy, C 1 -C 6 haloalkoxy, S(═O) n (C 1 -C 6 alkyl), and S(═O) n (C 1 -C 6 haloalkyl).

7. The molecule of claim 1 having a structure selected from compounds listed in Table 1

TABLE 1

Structures for Compounds

A1

A2

A3

A4

A5

A6

A7

Assignees

• Corteva Agriscience Llc

Inventors

• Giampietro Natalie C
• Ward Andrew
• Crouse Gary D
• Sparks Thomas C
• Barton Thomas J
• Horty Lindsey G
• Demeter David A

Classifications

• C07D277/48

  by radicals derived from carbonic acid, or sulfur or nitrogen analogues thereof, e.g. carbonylguanidines · CPC title

• C07D277/54 Primary

  Nitrogen and either oxygen or sulfur atoms · CPC title

• A01N47/36

  containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof · CPC title

• A01P7/04 Primary

  Insecticides · CPC title