Redox desalination system for clean water production and energy storage
US-2016365596-A1 · Dec 15, 2016 · US
US11329353B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11329353-B2 |
| Application number | US-202016818307-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 13, 2020 |
| Priority date | Mar 15, 2019 |
| Publication date | May 10, 2022 |
| Grant date | May 10, 2022 |
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An electrochemical-type power supply source for use in marine environment, is provided with: an electrochemical stack, which generates electric power in the presence, internally, of an electrolytic fluid; a first tank, designed to contain electrolytic fluid at a first temperature; a second tank, designed to contain electrolytic fluid at a second temperature, lower than the first temperature; a thermostatic valve, that mixes electrolytic fluid at a lower temperature with electrolytic fluid at a higher temperature, for generating a mixed electrolytic fluid to be introduced into the electrochemical stack at a controlled temperature for generating a desired electric power. The electrochemical power supply is further provided with an auxiliary tank, adapted to contain electrolytic fluid at a third temperature, higher than the first temperature; and the thermostatic valve is connected to the auxiliary tank and receives, at an input, the electrolytic fluid at the third temperature.
Opening claim text (preview).
The invention claimed is: 1. An electrochemical-type power supply ( 3 ), for use in marine environment, comprising: an electrochemical stack ( 4 ), configured to generate electric power, in the presence, internally, of an electrolytic fluid, a first tank ( 6 ), configured to contain electrolytic fluid at a first temperature; a second tank ( 8 ), configured to contain electrolytic fluid at a second temperature, lower than the first temperature, a thermostatic valve ( 14 ), configured to mix electrolytic fluid at a lower temperature with electrolytic fluid at a higher temperature, for generating a mixed electrolytic fluid to be introduced into the electrochemical stack ( 4 ) at a controlled temperature for generating a desired electric power, said electrochemical power supply source ( 3 ) further comprising an auxiliary tank ( 20 ), configured to contain electrolytic fluid at a third temperature, higher than said first temperature; wherein said thermostatic valve ( 14 ) is configured to be connected to the auxiliary tank ( 20 ) and to receive, at an input, the electrolytic fluid at said third temperature, as said electrolytic fluid at a higher temperature, for generating the mixed electrolytic fluid, in a given operating condition. 2. The power supply source according to claim 1 , wherein said thermostatic valve ( 14 ) has: a fluid outlet ( 15 ) connected to said electrochemical stack ( 4 ) and configured to provide said mixed electrolytic fluid; a first mixing inlet ( 14 a ) fluidically connected to said first tank ( 6 ), to receive the electrolytic fluid at said first temperature; a second mixing inlet ( 14 b ) fluidically connected to said second tank ( 8 ), to receive the electrolytic fluid at said second temperature; and a third mixing inlet ( 14 c ), configured to be fluidically coupled to said auxiliary tank ( 20 ), to receive the electrolytic fluid at said third temperature; wherein said thermostatic valve ( 14 ) is configured to switch the mixing inlets ( 14 a - 14 c ) between: a normal operating condition, wherein said thermostatic valve ( 14 ) is configured to mix the electrolytic fluid at said first temperature received from the first mixing inlet ( 14 a ), as said fluid at a higher temperature, with the electrolytic fluid at said second temperature received from the second mixing inlet ( 14 b ), as said fluid at a lower temperature; a transition operating condition, corresponding to said given operating condition, wherein said thermostatic valve ( 14 ) is configured to mix the electrolytic fluid at said first temperature received from the first mixing inlet ( 14 a ), as said fluid at a lower temperature, with the electrolytic fluid at said third temperature received from the third mixing inlet ( 14 c ), as said fluid at a higher temperature. 3. The power supply source according to claim 2 , wherein said transition operating condition is a high-power generation condition by said power supply source ( 3 ), in which said thermostatic valve ( 14 ) is configured to directly introduce, in said electrochemical stack ( 4 ), mixed electrolytic fluid at a high temperature, as a result of the mixing between the fluids at said first and third temperatures. 4. The power supply source according to claim 3 , wherein said normal operating condition for said thermostatic valve ( 14 ) corresponds to: a low-power generation condition by said power supply source ( 3 ), prior to said transition operating condition; and a high-power generation condition by said power supply source ( 3 ), after said transition operating condition is terminated. 5. The power supply source according to claim 2 , further comprising an electronic control module ( 18 ), operatively coupled to said thermostatic valve ( 14 ) and configured to provide a control signal (Se) to switch and, appropriately choke, said mixing inlets ( 14 a - 14 c ) and obtain a desired regulation of the temperature of the mixed electrolytic fluid at said fluid outlet ( 15 ). 6. The power supply source according to claim 2 , wherein said thermostatic valve ( 14 ) comprises: a valve body ( 30 ) in which a first chamber ( 32 a ) is defined, designed to receive said electrolytic fluid at a higher temperature, and a second chamber ( 32 b ) is defined, designed to receive said electrolytic fluid at a lower temperature, said first and second chambers ( 32 a , 32 b ) having a respective outlet opening ( 33 a , 33 b ) leading into said fluid outlet ( 15 ); and an adjustment actuator element ( 34 ), operable to vary the orifices of said outlet openings ( 33 a , 33 b ) and, therefore, the quantities of electrolytic fluid at a higher temperature and of electrolytic fluid at a lower temperature being mixed to generate said mixed electrolytic fluid at said fluid outlet ( 15 ). 7. The power supply source according to claim 6 , wherein said first chamber ( 32 a ) has an inlet opening ( 35 a ) selectively and alternatively fluidically connectable to the first mixing inlet ( 14 a ) and to said first tank ( 6 ) in said normal operating condition, or to the third mixing inlet ( 14 c ) and to said auxiliary tank ( 20 ) in said transition operating condition; and wherein said second chamber ( 32 b ) has a respective inlet opening ( 35 b ) selectively and alternatively fluidically connectable to the first mixing inlet ( 14 a ) and to said first tank ( 6 ) in said transition operating condition, or to the second mixing inlet ( 14 b ) and to said second tank ( 8 ) in said normal operating condition. 8. The power supply source according to claim 7 , wherein said thermostatic valve ( 14 ) further comprises a moving selector ( 38 ), defining a first and a second portion ( 38 ′, 38 ″), integral with each other, movable in rotation between a first position and a second position; wherein, in said first position, corresponding to said normal operating condition, the first portion ( 38 ′) closes the inlet to the first chamber ( 32 a ) from said auxiliary tank ( 20 ) and at a same time opens the inlet to said first chamber ( 32 a ) from said first tank ( 6 ), and furthermore, jointly, said second portion ( 38 ″) closes the inlet to the second chamber ( 32 b ) from said first tank ( 6 ) and, at a same time, opens the inlet to said second chamber ( 32 b ) from said second tank ( 8 ); and in said second position, corresponding to the transition operating condition, said first portion ( 38 ′) opens the inlet to the first chamber ( 32 a ) from said auxiliary tank ( 20 ) and, at a same time, closes the inlet to said first chamber ( 32 a ) from said first tank ( 6 ) and, furthermore, said second portion ( 38 ″) opens the inlet to the second chamber ( 32 b ) from said first tank ( 6 ) and, at a same time, closes the inlet to said second chamber ( 32 b ) from said second tank ( 8 ). 9. The power supply source according to claim 2 , wherein said thermostatic valve ( 14 ) is housed inside said first tank ( 6 ); said first mixing inlet ( 14 a ) is constituted by an opening in direct fluidic communication with said first tank ( 6 ); and said second inlet ( 14 b ) is connected to said second tank ( 8 ) through a connecting duct ( 16 ); further comprising a heat exchanger ( 12 ) which fluidically connects said first tank ( 6 ) and said second tank ( 8 ), cooling electrolytic fluid drawn from said first tank ( 6 ) which is introduced into said second tank ( 8 ). 10. The power supply source according to claim 2 , further comprising: a fluid-gas separator ( 10 ), having an inlet which receives electrolytic fluid drawn from the inside of said electrochemical stack ( 4 ), and an outlet for the outflow of liquid separated from reaction gas; and a pump ( 11 ) coupled to
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