Process for the preparation of flocculated filler particles

Patent metadata

Field	Value
Publication number	US-11326307-B2
Application number	US-201515518564-A
Country	US
Kind code	B2
Filing date	Nov 3, 2015
Priority date	Nov 7, 2014
Publication date	May 10, 2022
Grant date	May 10, 2022

Abstract

The present invention concerns a process for the preparation of flocculated filler particles, wherein at least two aqueous suspensions of at least one filler material and at least one flocculating additive are combined.

First claim

The invention claimed is:

1. A process for the preparation of flocculated filler particles comprising:
providing at least one first aqueous suspension S1 in a first vessel that comprises at least one flocculating additive A and at least one first filler material;
providing at least one second aqueous suspension S2 in a second vessel that comprises at least one flocculating additive B and at least one second filler material, wherein the at least one flocculating additive B is different from the at least one flocculating additive A, wherein more than 99 wt.-% of the at least one first filler material in the first aqueous suspension S1 and the at least one second filler in the second aqueous suspension S2 are the same; and
combining the at least one first aqueous suspension S1 with the at least one second aqueous suspension S2 simultaneously in a third vessel, under conditions effective to form a mixture, the mixture comprising an aqueous suspension SM of flocculated filler particles, wherein the aqueous suspension SM of flocculated filler particles fine fractions has a mono-modal particle size distribution, and wherein the content of the at least one flocculating additive A in the first aqueous suspension S1 is from 0.5 to 10 wt.-%, based on the total weight of the first aqueous suspension S1, and/or the content of the at least one flocculating additive B in the second aqueous suspension S2 is from 0.1 to 10 wt.-%, based on the total weight of the second aqueous suspension S2.

2. The process according to claim 1 , wherein a Brookfield viscosity of the first aqueous suspension S1 and/or the second aqueous suspension S2 and/or the aqueous suspension SM is less than 5,000 mPa·s at 25° C.

3. The process according to claim 1 , wherein a Brookfield viscosity of the first aqueous suspension S1 and/or the second aqueous suspension S2 and/or the aqueous suspension SM is less than 1,000 mPa·s at 25° C.

4. The process according to claim 1 , wherein a Brookfield viscosity of the first aqueous suspension S1 and/or the second aqueous suspension S2 and/or the aqueous suspension SM is between 10 and 200 mPa·s at 25° C.

5. The process according to claim 1 , wherein the at least one flocculating additive A is a cationic polymer selected from the group consisting of cationic starch, polyamines, polyethyleneimines, polyacrylamides, cationic amine amide, epichlorohydrin resins, polydiallyldimethylammonium chloride, cationic guar, and any mixture thereof.

6. The process according to claim 1 , wherein the at least one flocculating additive A is a cationic starch.

7. The process according to claim 1 , wherein the at least one flocculating additive B is an anionic carboxymethyl cellulose.

8. The process according to claim 7 , wherein the at least one flocculating additive A is a cationic starch.

9. The process according to claim 8 , wherein the at least one filler material is precipitated calcium carbonate.

10. The process according to claim 1 , wherein the aqueous suspension SM is sheared during and/or after the simultaneous combination of the at least two aqueous suspensions.

11. The process according to claim 1 , wherein the aqueous suspension SM is sheared in at least two steps at different shear rates.

12. The process according to claim 1 , wherein the aqueous suspension SM is sheared in at least two steps at different shear rates, wherein the first shear rate is lower than the second shear rate.

13. The process according to claim 1 , wherein the at least one first filler material and/or the at least one second filler material is selected from the group consisting of a calcium carbonate-comprising material, ground calcium carbonate, precipitated calcium carbonate, modified calcium carbonate, talc, clay, dolomite, marble, titanium dioxide, kaolin, silica, alumina, mica, aluminium trihydrate, magnesium hydroxide, plastic pigments, a hybrid material comprising an organic filler and an inorganic chemical composition, and any mixture thereof.

14. The process according to claim 1 , wherein the at least one first filler material and/or the at least one second filler material is precipitated calcium carbonate.

15. The process according to claim 1 , wherein the content of the at least one flocculating additive A in the first aqueous suspension S1 is from 3 to 5 wt.-%, based on the total weight of the first aqueous suspension S1, and/or the content of the at least one flocculating additive B in the second aqueous suspension S2 is from 0.2 to 0.8 wt.-%, based on the total weight of the second aqueous suspension S2.

16. The process according to claim 1 , wherein the content of the at least one first filler material in the first aqueous suspension S1 is from 15 to 65 wt.-%, based on the total weight of the first aqueous suspension S1, and the content of the at least one second filler material in the second aqueous suspension S2 is from 15 to 65 wt.-%, based on the total weight of the second aqueous suspension S2.

17. The process according to claim 1 , wherein the aqueous suspension SM has a solids content of from 1 to 75 wt.-%, based on the total weight of the aqueous suspension SM.

18. The process according to claim 1 , wherein the aqueous suspension SM has a solids content of from 2 to 60 wt.-%, based on the total weight of the aqueous suspension SM.

19. The process according to claim 1 , wherein the aqueous suspension SM has a solids content of from 5 to 35 wt.-%, based on the total weight of the aqueous suspension SM.

20. The process according to claim 1 , wherein the aqueous suspension SM of flocculated filler particles has a volume defined particle size polydispersity expressed as full width at half maximum height (FWHM) of less than 40 μm.

21. The process according to claim 1 , wherein the aqueous suspension SM of flocculated filler particles has a volume defined particle size polydispersity expressed as full width at half maximum height (FWHM) of less than 20 μm.

22. The process according to claim 1 , wherein the aqueous suspension SM of flocculated filler particles has a volume defined particle size polydispersity expressed as full width at half maximum height (FWHM) of less than 10 μm.

23. The process according to claim 1 , wherein the content of the at least one first filler material in the first aqueous suspension S1 is from 1 to 85 wt.-%, based on the total weight of the first aqueous suspension S1, and the content of the at least one second filler material in the second aqueous suspension S2 is from 1 to 85 wt.-%, based on the total weight of the second aqueous suspension S2.

24. The process according to claim 1 , wherein the at least one flocculating additive B is an anionic polymer selected from the group consisting of carboxymethyl cellulose, anionic starch, anionic guar, anionic xanthan gum, and any mixture thereof.

25. The process according to claim 1 , wherein the mass ratio of the at least one first filler material in the first aqueous suspension and the at least one second filler material in the second aqueous suspension S1:S2 is from 1:100 to 100:1.

Assignees

• Omya Int Ag

Inventors

• Schenker Michel
• Buri Matthias
• Andersson Lars
• Gantenbein Daniel
• Gane Patrick A C

Classifications

• C01P2004/22

  with a polygonal circumferential shape · CPC title

• C01P2006/22

  Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability · CPC title

• C09C1/00

  Treatment of specific inorganic materials other than fibrous fillers (tenebrescent materials C09K9/00; luminescent materials C09K11/00); Preparation of carbon black · CPC title

• C01P2004/64

  Nanometer sized, i.e. from 1-100 nanometer · CPC title

• D21H19/38

  characterised by the pigments · CPC title