Method for preparing surface-active onion-like carbon nanospheres based on vapor deposition

Patent metadata

Field	Value
Publication number	US-11326251-B2
Application number	US-202016798827-A
Country	US
Kind code	B2
Filing date	Feb 24, 2020
Priority date	Jul 8, 2019
Publication date	May 10, 2022
Grant date	May 10, 2022

Abstract

The present invention discloses a method for preparing surface-active onion-like carbon nanospheres based on vapor deposition, comprising: directly preparing high-surface-activity onion-like carbon nanospheres formed by coating ferroferric oxide nano-particles on an onion-like graphitized shell by taking liquid small organic molecule alkane n-dodecane as a carbon source to perform chemical vapor deposition at high temperature of 650˜700° C. in an inert carrier gas environment with existence of a ferrocene catalyst. An onion-like carbon nanosphere product prepared according to the present invention has good surface activity and thermal stability, is wide in practicability, and can be widely applied to the fields of adsorbing materials, energy storage materials, catalytic materials, medical materials and the like.

First claim

What is claimed is:

1. A method for preparing surface-active onion-like carbon nanospheres based on vapor deposition, comprising: directly preparing high-surface-activity onion-like carbon nanospheres formed by coating ferroferric oxide nano-particles on an onion-like graphitized shell by taking liquid small organic molecule alkane n-dodecane as a carbon source to perform chemical vapor deposition at high temperature of 650˜700° C. in an inert carrier gas environment with existence of a ferrocene catalyst.

2. The method according to claim 1 , wherein the use amount of the catalyst ferrocene is 0.050˜0.055 time of the mass of the carbon source n-dodecane.

3. The method according to claim 1 , wherein the carbon source and the catalyst are added into water to prepare an aqueous dispersion.

4. The method according to claim 3 , wherein the use amount of the water is 2˜3 times of the volume of the carbon source.

5. The method according to claim 1 , wherein the chemical vapor deposition reaction time is 15˜20 min.

6. The method according to claim 1 , wherein the inert carrier gas flow in the chemical vapor deposition reaction process is 5+/−1 mL/min.

7. The method according to claim 6 , wherein the inert carrier gas flow is controlled to be not greater than 3 mL/min in a temperature rise period, and after temperature rises to a reaction temperature, adjusting the inert carrier gas flow to 5+/−1 mL/min.

8. Surface-active onion-like carbon nanospheres prepared by the method according to claim 1 , wherein an Fe 3 O 4 nanocrystalline metal kernel is coated inside the carbon nanosphere, and an outer layer being of an onion-like graphitized shell structure, with average particle size of 30 nm.

9. Surface-active onion-like carbon nanospheres prepared by the method according to claim 2 , wherein an Fe 3 O 4 nanocrystalline metal kernel is coated inside the carbon nanosphere, and an outer layer being of an onion-like graphitized shell structure, with average particle size of 30 nm.

10. Surface-active onion-like carbon nanospheres prepared by the method according to claim 3 , wherein an Fe 3 O 4 nanocrystalline metal kernel is coated inside the carbon nanosphere, and an outer layer being of an onion-like graphitized shell structure, with average particle size of 30 nm.

11. Surface-active onion-like carbon nanospheres prepared by the method according to claim 4 , wherein an Fe 3 O 4 nanocrystalline metal kernel is coated inside the carbon nanosphere, and an outer layer being of an onion-like graphitized shell structure, with average particle size of 30 nm.

12. Surface-active onion-like carbon nanospheres prepared by the method according to claim 5 , wherein an Fe 3 O 4 nanocrystalline metal kernel is coated inside the carbon nanosphere, and an outer layer being of an onion-like graphitized shell structure, with average particle size of 30 nm.

13. Surface-active onion-like carbon nanospheres prepared by the method according to claim 6 , wherein an Fe 3 O 4 nanocrystalline metal kernel is coated inside the carbon nanosphere, and an outer layer being of an onion-like graphitized shell structure, with average particle size of 30 nm.

14. Surface-active onion-like carbon nanospheres prepared by the method according to claim 7 , wherein an Fe 3 O 4 nanocrystalline metal kernel is coated inside the carbon nanosphere, and an outer layer being of an onion-like graphitized shell structure, with average particle size of 30 nm.

Assignees

• Univ Taiyuan Technology

Inventors

• Qin Lei
• Liu Weifeng
• Cui Yan
• Liu Xuguang
• Yang Yongzhen

Classifications

• C23C16/4417

  Methods specially adapted for coating powder · CPC title

• C01P2002/88

  by thermal analysis data, e.g. TGA, DTA, DSC · CPC title

• C01G49/08

  Ferroso-ferric oxide [Fe3O4] · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• C23C16/26 Primary

  Deposition of carbon only · CPC title