Hydrophobic, water-redispersible polymer powder composition

Patent metadata

Field	Value
Publication number	US-11325862-B2
Application number	US-201816772413-A
Country	US
Kind code	B2
Filing date	Nov 7, 2018
Priority date	Nov 7, 2018
Publication date	May 10, 2022
Grant date	May 10, 2022

Abstract

A hydrophobic, water-redispersible polymer powder composition containsa) a main polymer havinga1) more than 60 parts by weight of vinyl laurate monomer unitsa2) 5 to 30 parts by weight of vinyl acetate monomer units,a3) 5 to 30 parts by weight of ethylene monomer units,a4) 0 to 10 parts by weight of other ancillary monomer units,where the parts by weight total 100 parts by weight,b) 0.5 to 30% by weight of one or more protective colloids,c) 0 to 30% by weight of antiblocking agent,d) 0 to 20% by weight of organosilicon compound, ande) 0 to 20% by weight of fatty acid or derivatives of the fatty acids,where the % s by weight are based on the total weight of the polymer a).

First claim

What is claimed is:

1. A hydrophobic, water-redispersible polymer powder composition, comprising:
a) a main polymer, comprising
a1) 65 to 90 parts by weight of vinyl laurate monomer units
a2) 5 to 30 parts by weight of vinyl acetate monomer units,
a3) 5 to 30 parts by weight of ethylene monomer units,
a4) 0 to 10 parts by weight of other ancillary monomer units,

where the parts by weight of a1) to a4) total 100 parts by weight,
b) 0.5 to 30% by weight of one or more protective colloids,
c) 0 to 30% by weight of antiblocking agent(s),
d) 0 to 20% by weight of organosilicon compound(s),
e) 0 to 20% by weight of fatty acid(s) or derivatives thereof,

where the %s by weight are based on the total weight of the polymer a).

2. The hydrophobic, water-redispersible polymer powder composition of claim 1 , wherein the main polymer a) comprises 70 to 90 parts by weight of vinyl laurate a1).

3. The hydrophobic, water-redispersible polymer powder composition of claim 1 , wherein the main polymer a) comprises:
a1) 65 to 90 parts by weight of vinyl laurate monomer units,
a2) 5 to 30 parts by weight of vinyl acetate monomer units, and
a3) 5 to 20 parts by weight of ethylene monomer units, and it optionally also comprises
a4) up to 10 parts by weight of ancillary monomer units.

4. The hydrophobic, water-redispersible polymer powder composition of claim 1 , wherein protective colloid b) comprises one or more partially hydrolyzed polyvinyl alcohols whose degree of hydrolysis is 85 to 94 mol % and whose Höppler viscosity in 4% aqueous solution is 3 to 15 mPas.

5. A process for the production of a hydrophobic, water-redispersible polymer powder composition of claim 1 , comprising free-radical-initiated emulsion polymerizing the monomers in an aqueous medium, followed by drying a resultant aqueous polymer dispersion.

6. A dry mortar composition, comprising a hydrophobic, water-redispersible polymer powder composition of claim 1 .

7. A dry mortar composition for production of construction adhesives, renders, troweling compositions, floor-filling compositions, leveling compositions, sealing slurries, jointing mortars, skimcoats, or paints, comprising at least one hydrophobic, water-redispersible polymer powder composition of claim 1 .

8. A construction adhesive or coating for composite thermal insulation systems, comprising a hydrophobic, water-redispersible polymer powder composition of claim 1 .

9. A skimcoat formulation, comprising at least one hydrophobic, water-redispersible polymer powder composition of claim 1 .

10. A dry mortar composition, comprising:
i) 0 to 50% by weight of one or more mineral binders,
ii) 1 to 20% by weight of one or more dispersion powders,
iii) 40 to 90% by weight of one or more fillers,
iv) 0.05 to 0.8% by weight of one or more thickeners,
v) optionally up to 5% by weight of other additives,

wherein at least one dispersion powder ii) comprises a hydrophobic, water-redispersible polymer powder composition of claim 1 .

11. The dry mortar composition of claim 10 , wherein the dispersion powders ii) further comprise one or more non-hydrophobic dispersion powders, selected from the group consisting of vinyl acetate homopolymers; vinyl acetate-ethylene copolymers comprising 1 to 40% by weight of ethylene; vinyl acetate copolymers comprising 1 to 50% by weight of vinyl esters having 1 to 12 carbon atoms in the carboxylic acid moiety; vinyl acetate copolymers comprising 1 to 40% by weight of ethylene and 1 to 50% by weight of one or more vinyl esters other than vinyl acetate having 1 to 12 carbon atoms in the carboxylic acid moiety; vinyl acetate copolymers comprising 1 to 40% by weight of ethylene and 1 to 50% by weight of (meth)acrylates of unbranched or branched alcohols having 1 to 15 carbon atoms; vinyl acetate copolymers comprising 1 to 30% by weight of vinyl laurate or vinyl esters of an alpha-branched carboxylic acid having 5 to 13 carbon atoms and also 1 to 30% by weight of (meth)acrylates of unbranched or branched alcohols having 1 to 15 carbon atoms and optionally 1 to 40% by weight of ethylene; vinyl acetate copolymers comprising 1 to 40% by weight of ethylene and 1 to 60% by weight of vinyl chloride; methyl methacrylate copolymers comprising n-butyl acrylate and/or 2-ethylhexyl acrylate and optionally ethylene; styrene copolymers comprising one or more of the monomers methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, and 2-ethylhexyl acrylate; and styrene-butadiene copolymers.

Assignees

• Wacker Chemie Ag

Inventors

• Weitzel Hans-Peter
• Dietrich Ulf

Classifications

• C04B2111/00672

  Pointing or jointing materials · CPC title

• C04B28/02

  containing hydraulic cements other than calcium sulfates · CPC title

• C04B2111/00508

  Cement paints · CPC title

• C04B2111/27

  Water resistance, i.e. waterproof or water-repellent materials · CPC title

• C04B40/0042 Primary

  Powdery mixtures · CPC title