Static-dissipative coating technology

Patent metadata

Field	Value
Publication number	US-11325859-B2
Application number	US-202016831325-A
Country	US
Kind code	B2
Filing date	Mar 26, 2020
Priority date	Nov 17, 2016
Publication date	May 10, 2022
Grant date	May 10, 2022

Abstract

The invention provides a glass sheet or another transparent substrate on which there is provided a static-dissipative coating. The static-dissipative coating includes a film comprising titania. The film comprising titania preferably is exposed so as to define an outermost face of the static-dissipative coating. The static-dissipative coating is characterized by an indoor dust collection factor of less than 0.145.

First claim

What is claimed is:

1. An insulating glass unit including an exterior pane and an interior pane, the interior pane being a transparent substrate having an exterior surface on which there is provided a static-dissipative coating, the exterior pane having an interior surface that bears a low-emissivity coating, the low-emissivity coating comprising one or more infrared-reflective metallic films comprising silver, the exterior pane having an exterior surface that is a #1 surface, the interior surface of the exterior pane being a #2 surface, and the exterior surface of the interior pane being a #4 or #6 surface, the static-dissipative coating including a film comprising titania over a base film, the film comprising titania having a thickness of less than 300 angstroms but greater than 30 angstroms, and the static-dissipative coating has a surface resistance of greater than 10 8 ohms per square but less than 10 11 ohms per square, wherein the film comprising titania is exposed so as to define an outermost face of the static-dissipative coating, and the static-dissipative coating has a surface roughness R a in a range of between about 0.05 nm and about 5.0 nm, the static-dissipative coating characterized by an indoor dust collection factor of less than 0.142 but greater than 0.050.

2. The insulating glass unit of claim 1 wherein the indoor dust collection factor is less than 0.128 but greater than 0.050.

3. The insulating glass unit of claim 1 wherein the static-dissipative coating is characterized by an outdoor dust collection factor of less than 0.036.

4. The insulating glass unit claim 3 wherein the outdoor dust collection factor is less than 0.032 but greater than 0.010.

5. The insulating glass unit claim 4 wherein the outdoor dust collection factor is less than 0.030 but greater than 0.010.

6. The insulating glass unit of claim 1 wherein the surface resistance of the static-dissipative coating is greater than 3.0×10 9 ohms per square but less than 7.0×10 9 ohms per square.

7. The insulating glass unit of claim 1 wherein the static-dissipative coating is devoid of an electrically conductive film beneath the film comprising titania.

8. The insulating glass unit of claim 1 wherein the static-dissipative coating has a wet dynamic coefficient of friction of less than 0.07.

9. An insulating glass unit comprising two spaced-apart panes bounding a between-pane space, wherein one of the panes has an exterior surface that is exposed to an interior of a building and that bears a static-dissipative coating, the static-dissipative coating including a film comprising titania over a base film, the film comprising titania having a thickness of less than 300 angstroms but greater than 30 angstroms, and the static-dissipative coating has a surface resistance of greater than 3.0×10 9 ohms per square but less than 7.0×10 9 ohms per square, wherein the film comprising titania is exposed so as to define an outermost face of the static-dissipative coating, the static-dissipative coating characterized by an indoor dust collection factor of less than 0.142 but greater than 0.050.

10. The insulating glass unit of claim 9 wherein the indoor dust collection factor is less than 0.128 but greater than 0.050.

11. The insulating glass unit of claim 9 wherein the static-dissipative coating is characterized by an outdoor dust collection factor of less than 0.036.

12. The insulating glass unit of claim 11 wherein the outdoor dust collection factor is less than 0.032 but greater than 0.010.

13. The insulating glass unit of claim 12 wherein the outdoor dust collection factor is less than 0.030 but greater than 0.010.

14. The insulating glass unit of claim 9 wherein the film comprising titania consists of titanium oxide, and the static-dissipative coating is devoid of an electrically conductive film beneath the film comprising titania.

15. The insulating glass unit of claim 9 wherein the static-dissipative coating has a surface roughness R a in a range of between 0.2 nm and 4 nm in combination with having a wet dynamic coefficient of friction of less than 0.07.

16. The insulating glass unit of claim 1 wherein the base film has a thickness of less than about 300 angstroms.

17. The insulating glass unit of claim 1 wherein the film comprising titania includes nitrogen as a dopant.

18. The insulating glass unit of claim 1 wherein the base film consists of silica, the base film is deposited directly onto the exterior surface of the interior pane, and the film comprising titania is deposited directly onto the base film.

19. The insulating glass unit of claim 9 wherein the base film has a thickness of less than about 300 angstroms.

20. The insulating glass unit of claim 9 wherein the film comprising titania includes nitrogen as a dopant.

21. The insulating glass unit of claim 9 wherein the base film consists of silica, the base film is deposited directly onto said exterior surface, and the film comprising titania is deposited directly onto the base film.

22. An insulating glass unit including an exterior pane and an interior pane, the interior pane being a transparent substrate having an exterior surface on which there is provided a static-dissipative coating, the exterior pane having an interior surface that bears a low-emissivity coating, the low-emissivity coating comprising one or more infrared-reflective metallic films comprising silver, the exterior pane having an exterior surface that is a #1 surface, the interior surface of the exterior pane being a #2 surface, and the exterior surface of the interior pane being a #4 or #6 surface, the static-dissipative coating including a film comprising titania over a base film, the film comprising titania having a thickness of less than 300 angstroms but greater than 30 angstroms, and the static-dissipative coating has a surface resistance of greater than 10 8 ohms per square but less than 10 11 ohms per square, wherein the film comprising titania is exposed so as to define an outermost face of the static-dissipative coating, the static-dissipative coating having a surface roughness R a in a range of between 0.2 nm and 4 nm in combination with having a wet dynamic coefficient of friction of less than 0.07, the static-dissipative coating characterized by an indoor dust collection factor of less than 0.140 but greater than 0.050.

Assignees

• Cardinal Cg Co

Inventors

• Burrows Keith James
• Myli Kari B

Classifications

• C03C17/002

  for flat glass, e.g. float glass · CPC title

• C09D5/00

  Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced {(electrically insulating plastics, resins or waxes H01B3/30)}; Filling pastes · CPC title

• C03C17/3435

  comprising a nitride, oxynitride, boronitride or carbonitride · CPC title

• E06B7/28

  Other arrangements on doors or windows, e.g. door-plates, windows adapted to carry plants, hooks for window cleaners {(edge protecting devices for door leaves E06B3/88; special glazing; emergency glazing; double glazing E06B3/66)} · CPC title

• C03C2217/212

  TiO2 · CPC title