Additive manufactured interpenetrating phase composite

Patent metadata

Field	Value
Publication number	US-11325206-B2
Application number	US-201916389280-A
Country	US
Kind code	B2
Filing date	Apr 19, 2019
Priority date	Apr 20, 2018
Publication date	May 10, 2022
Grant date	May 10, 2022

Abstract

A method for preparing metal/metal interpenetrating phase composites is provided. The method includes forming a preform using additive manufacturing. The preform defines a materially continuous three-dimensional open-cell mesh structure. The preform includes a first metal having a melting point. The method further includes pre-heating the preform to a first temperature less than the melting point of the first metal. The method includes infiltrating the preform with a second metal in liquid form. The second metal has a melting point lower than the melting point of the first metal. The method also includes allowing the second metal to cool and form a solid matrix. The solid matrix defines a continuous material network.

First claim

The invention claimed is:

1. A method for preparing metal/metal interpenetrating phase composites, the method comprising:
forming a preform using additive manufacturing, the preform defining a materially continuous three-dimensional open-cell mesh structure and an outer skin, wherein the open-cell mesh structure includes a plurality of interconnected struts that define a plurality of repeating unit cells each defining a void therein, wherein the outer skin at least partially encapsulates the open-cell mesh structure and includes a base, a sidewall, a top wall, and an ingate extending upwardly from the top wall, the ingate being cylindrical and centrally disposed along the top wall, wherein the base, the sidewall, and the top wall collectively define a mold cavity, wherein the ingate is in fluid communication with the mold cavity, and wherein the preform includes a first metal having a melting point;
pre-heating the preform to a first temperature less than the melting point of the first metal;
infiltrating the open-cell mesh structure of the preform with a second metal in liquid form by flowing the second metal through the ingate, such that the second metal occupies the voids in the plurality of repeating unit cells and contacts an interior surface of the base and an interior surface of the sidewall, such that the base and the sidewall retain the second metal within the mold cavity, the second metal having a melting point lower than the melting point of the first metal;
allowing the second metal to cool within the mold cavity and form a solid matrix, wherein the solid matrix defines a continuous material network; and
removing the outer skin from the solid matrix, wherein the solid matrix encapsulates the plurality of interconnected struts to yield a metal/metal interpenetrating phase composite, further defining an intermetallic-free gap between the solid matrix and the plurality of interconnected struts to improve toughness of the metal/metal interpenetrating phase composite,
wherein the first metal is 316L and the second metal is A356.

2. The method of claim 1 , wherein the metal/metal interpenetrating phase composite has a strain to failure that is greater than a strain to failure of the second metal.

3. The method of claim 2 , wherein the strain to failure of the metal/metal interpenetrating phase composite is an order of magnitude higher than the strain to failure of the second metal.

4. The method of claim 1 , wherein the skin has a thickness of from 0.5 to 1.5 mm.

5. The method of claim 1 , wherein the three-dimensional open-cell mesh structure defines a-body-centered cubic symmetry.

6. The method of claim 1 , wherein the three-dimensional open-cell mesh structure defines a stretch-dominated lattice.

7. The method of claim 1 , wherein the three-dimensional open-cell mesh structure defines a bending-dominated lattice.

8. The method of claim 1 , wherein the preform is a functionally-graded preform, wherein a geometry of the three-dimensional open-cell mesh structure varies as a function of position within the preform.

9. The method of claim 8 , wherein the plurality of struts each have a strut diameter wherein strut diameter decreases along a major dimension of the preform.

10. The method of claim 1 , wherein the plurality of struts include a cross-section conforming to a dendritic shape.

11. A method for preparing metal/metal interpenetrating phase composites, the method comprising:
selecting a preform geometry including a continuous three-dimensional open-cell mesh structure and an outer skin, wherein the open-cell mesh structure includes a plurality of interconnected struts that define a plurality of repeating unit cells each defining a void therein, wherein the outer skin at least partially encapsulates the open-cell mesh structure and includes a base, a sidewall, a top wall, and an ingate extending upwardly from the top wall, the ingate being cylindrical and centrally disposed along the top wall, wherein the base, the sidewall, and the top wall collectively define a mold;
preparing a print file encoding the preform geometry;
using the print file to print a preform having the preform geometry using an additive manufacturing device, wherein the preform comprises a first metal having a melting point;
preheating the preform to a first temperature less than the melting point of the first metal;
infiltrating the open-mesh structure of the preform with a second metal in liquid form by flowing the second metal through the ingate, the second metal having a melting point lower than the melting point of the first metal, such that the second metal occupies the voids in the plurality of repeating unit cells and contacts an interior surface of the base and an interior surface of the sidewall, such that the base and the sidewall retain the second metal within the mold cavity;
allowing the second metal to cool within the mold cavity and form a solid matrix, wherein the solid matrix defines a continuous material network; and
removing the outer skin from the solid matrix, wherein the solid matrix encapsulates the plurality of interconnected struts to yield a metal/metal interpenetrating phase composite, further defining an intermetallic-free gap between the solid matrix and the plurality of interconnected struts to improve toughness of the metal/metal interpenetrating phase composite,
wherein the first metal is 316L and the second metal is A356.

12. The method of claim 11 , wherein the additive manufacturing device prints using selective laser melting.

13. The method of claim 11 , wherein the metal/metal interpenetrating phase composite has a porosity of from 0% to 10%.

14. The method of claim 11 , wherein the metal/metal interpenetrating phase composite has a 0.2% offset yield strength, σ γ of from 100 MPa to 300 MPa.

15. The method of claim 11 further comprising mounting the preform in plaster.

16. The method of claim 11 , wherein the metal/metal interpenetrating phase composite has a specific gravity of from 4 to 6.

17. The method of claim 11 , wherein the struts have a diameter of from 0.5 mm to 1 mm.

18. The method of claim 11 , wherein a volume fraction of the first metal in the metal/metal interpenetrating phase composite is from 0.25 to 0.55.

Assignees

• Ut Battelle Llc

Inventors

• Pawlowski Alex E
• Shyam Amit
• Splitter Derek A
• Elliott Amelia M
• Cordero Zachary C

Classifications

• B22F10/28

  Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM] · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title

• B22F3/1115

  comprising complex forms, e.g. honeycombs · CPC title

• B22F5/10

  of articles with cavities or holes, not otherwise provided for in the preceding subgroups · CPC title