Sequential processing of materials and coatings of variable and controllable density with nanometer and micrometer sub-structures

Patent metadata

Field	Value
Publication number	US-11325185-B2
Application number	US-201916673419-A
Country	US
Kind code	B2
Filing date	Nov 4, 2019
Priority date	Nov 2, 2018
Publication date	May 10, 2022
Grant date	May 10, 2022

Abstract

A multi-step method to produce materials, and coatings of materials, which has three key characteristics. The first is that the density of the resulting materials or coatings can be controllably and widely variable from less than ten percent of normal density up to normal density. The second key characteristic of the invention is the use of starting materials having powders that have grains (particles) with one, two or three dimensions on the size scales of nanometers or micrometers. The third major characteristic part of the invention is the use of microwave radiation or induction heating to quickly raise the temperature of the powders to produce materials or coatings before deleterious diffusion and densification can occur. These features produce new types of materials with properties favorable to many applications, such as chemical and other catalysis, electrolysis in batteries and fuel cells, and light weight structural components.

First claim

The invention claimed is:

1. A method for production of a desired material or desired coating, said method comprising a sequence of process steps to produce the desired materials or the desired coatings with variable and controllable porosity, including:
providing a powder material having a sub-structure of particles, the particles having a nanometer or micrometer size, wherein the powder material comprises any of metallic, semiconductor, insulating, ceramic, glass, polymer or organic materials, carbon allotropes, or combinations thereof;
compacting the powder material in the absence of any binder or filler, to a selected density; and
rapid heating the compacted powder material at a selected temperature, in the absence of any binder or filler and in the absence of pyrolysis, for no more than about 10 minutes with any variation of temperature as a function of time to bind the powder material and produce the desired material or coating having a desired porosity,
wherein the desired porosity is controlled based on the compositions, shapes and sizes of the particles of the powered material, the type and degree of compaction, the selected temperature, and time and temperature-time history during the rapid heating.

2. The method of claim 1 , further comprising placing the powder in a mold prior to the step of compacting.

3. The method of claim 1 , wherein the selected temperature is 0.25-0.95 of a melting point for the powder material.

4. The method of claim 1 , wherein the desired material has a thickness of 1 to 500 mm or the desired coating has a thickness of 0.1-10 mm.

5. The method of claim 1 , wherein the desired material or coating has a width and length of 1-100 mm.

6. The method of claim 1 , wherein the particles have a size of 0.1-100 nm or 0.1 micrometers to 10 millimeters in width, height, or length, regardless of particle shape.

7. The method of claim 1 , wherein the selected density comprises 10% to substantially 100% of full density of the final material.

8. The method of claim 1 , wherein said particles have desired properties and their mixture has a desired porosity, wherein said compacting and said heating decrease the porosity of said particle but preserve the desired properties.

9. The method of claim 8 , wherein said desired properties are chemical, mechanical, electronic, optical, magnetic, or other properties of utility.

10. The method of claim 1 , wherein the desired material comprises macroscopic porous materials with internal structure on the scale of nanometers or micrometers.

11. The method of claim 1 , wherein said heating comprises microwave or induction heating with any variation of temperature as a function of time.

12. The method of claim 11 , wherein said microwave is in the frequency range of 100 MHz-1 THz.

13. The method of claim 11 , wherein said induction heating is in the frequency range of 1 kHz-10 MHz.

14. A method for production of a desired material or desired coating, said method comprising a sequence of process steps to produce the desired materials or the desired coatings with variable and controllable porosity, including:
providing a powder material having a sub-structure of particles, the particles having a nanometer or micrometer size, wherein the powder material comprises any of metallic, semiconductor, insulating, ceramic, glass, polymer or organic materials, carbon allotropes, or combinations thereof;
placing the powder material in a container;
after placing the powder in the container, compacting the powder material to a selected density; and
after the step of compacting the powder material, no more than a single heating step of rapid heating the compacted powder material at a selected temperature for no more than about 10 minutes with any variation of temperature as a function of time to produce the desired material or coating having a desired porosity, in the absence of any fillers or binders and in the absence of pyrolysis.

15. The method of claim 14 , wherein the rapid heating includes sintering the compacted power material in the container.

16. The method of claim 15 , wherein the desired porosity is controlled based on the compositions, shapes and sizes of the particles of the powered material, the type and degree of compaction, the selected temperature, and time and temperature-time history during the rapid heating.

Assignees

• Univ George Washington

Inventors

• Nagel David Joseph
• Imam M Ashraf

Classifications

• B22F1/054

  Nanosized particles · CPC title

• B22F1/052

  characterised by a mixture of particles of different sizes or by the particle size distribution · CPC title

• B22F1/05

  Metallic powder characterised by the size or surface area of the particles · CPC title

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title

• B22F2202/05

  Use of magnetic field · CPC title