Energy storage device and a method of preparing the same

Patent metadata

Field	Value
Publication number	US-11322312-B2
Application number	US-201916369040-A
Country	US
Kind code	B2
Filing date	Mar 29, 2019
Priority date	Mar 29, 2019
Publication date	May 3, 2022
Grant date	May 3, 2022

Abstract

An energy storage device and a method of fabricating such energy storage device. The energy storage device includes a first electrode, a second electrode, and an electrolyte. The combination of the electrodes and the electrolyte is arranged to elastically deform when subjected to an external mechanical load applied to the energy storage device. The electrolyte includes a polymer matrix of at least two crosslinked structures, including a first polymeric material and a second polymeric material; and an electrolytic solution retained by the polymer matrix.

First claim

The invention claimed is:

1. An energy storage device, comprising:
an anode and a cathode, each of which include an annealed conductive polymer having a wrinkled surface;
an electrolyte sandwiched between the anode and the cathode, the electrolyte includes a polymer matrix including:
a first crosslinked structure defined by a plurality of agar chains forming at least one hydrogen bond between each adjacent pair of the agar chains;
a second crosslinked structure defined by a plurality of polyacrylamide chains forming at least one hydrophobic interaction with a crosslinking agent comprising a polymerizable micelle, the polymerizable micelle includes poly(stearyl methacrylate) and sodium dodecyl sulfate; and
a third crosslinked structure defined by the plurality of agar chains and the polyacrylamide chains forming at least one hydrophobic interaction, through the polymerizable micelle, among adjacent pairs of the agar chains and the polyacrylamide chains, or defined by the adjacent pairs of agar chains and the polyacrylamide chains that are intercrossing and intertwining with each other; and

an electrolytic solution of a sulfuric acid solution retained by the polymer matrix;

wherein the combination of the anode, the cathode, and the electrolyte is arranged to elastically deform when subjected to an external mechanical load applied thereto.

2. The energy storage device according to claim 1 , wherein the crosslinking agent further includes a surfactant, wherein the surfactant is sodium dodecyl sulfate (SDS) forming a micelle with poly(stearyl methacrylate).

3. The energy storage device according to claim 1 , wherein the second crosslinked structure dissipates energy when subjected to the external mechanical load thereby maintaining the elasticity of the electrolyte.

4. The energy storage device according to claim 3 , wherein the second crosslinked structure dissipates energy by rupturing the hydrophobic interactions within the structure when subjected to the external mechanical load; and restoring the interactions when the load is removed.

5. The energy storage device according to claim 1 , wherein the first crosslinked structure is polyacrylamide.

6. The energy storage device according to claim 1 , wherein the second crosslinked structure is agar.

7. The energy storage device according to claim 1 , wherein the conductive polymer is selected from the group consisting of polypyrrole, polyacetylene, polyphenylene vinylene, polythiophene and polyphenylene sulfide.

8. The energy storage device according to claim 1 , wherein the conductive polymer is annealed to enhance electrical conductivity thereof.

9. The energy storage device according to claim 1 , wherein the combination of the anode, the cathode, and the electrolyte elastically deforms in a way of stretching when subjected to the external mechanical load applied to thereto.

10. The energy storage device according to claim 9 , wherein the electrolyte substantially maintains its elasticity after subjecting to stretching for at least 500 times.

11. The energy storage device according to claim 1 , wherein the device substantially maintains its elasticity after subjecting to stretching for at least 500 times.

12. The energy storage device according to claim 1 , wherein the device is a supercapacitor.

Assignees

• Univ City Hong Kong

Inventors

• Zhi Chunyi
• Wang Yukun
• Li Hongfei
• Tang Zijie

Classifications

• H01G11/08

  Structural combinations, e.g. assembly or connection, of hybrid or EDL capacitors with other electric components, at least one hybrid or EDL capacitor being the main component · CPC title

• H01G11/48

  Conductive polymers · CPC title

• H01G11/84

  Processes for the manufacture of hybrid or EDL capacitors, or components thereof · CPC title

• H01G11/56 Primary

  Solid electrolytes, e.g. gels; Additives therein · CPC title

• H01G11/26

  characterised by their structure, e.g. multi-layered, porosity or surface features · CPC title