Lubricant with nanoparticulate additive

Patent metadata

Field	Value
Publication number	US-11319504-B2
Application number	US-202117146396-A
Country	US
Kind code	B2
Filing date	Jan 11, 2021
Priority date	Jun 16, 2020
Publication date	May 3, 2022
Grant date	May 3, 2022

Abstract

An engine oil additive includes carbon nanotubes and boron nitride particulates dispersed within a fluid. The additive is configured to be mixed with a quantity of oil such that the quantity of oil has a concentration from 0.05 to 0.5 grams of carbon nanotubes and of boron nitride particulates per quart of oil to improve the lubricity of the oil. The additive improves the horsepower and torque of the engine while reducing fuel consumption. The carbon nanotubes have an —OH functionalized exterior surface. The carbon nanotubes have a diameter from 1 nanometer to 50 nanometers and have a length from 1 micron to 1000 microns. The boron nitride particulates are hex-boron nitride structures having an average size from 30 nanometers to 500 nanometers.

First claim

What is claimed is:

1. A fluid comprising:
an oil;
a plurality of carbon nanotubes dispersed within the oil and each having a diameter between 1 nanometer and 80 nanometers, wherein at least 0.76 percent of the plurality of carbon nanotubes have OH functionalized surfaces; and
a plurality of boron nitride particulates dispersed within the oil, wherein each of the plurality of boron nitride particulates are separate from each of the plurality of carbon nanotubes and have an average particle size between 50 nanometers and 90 nanometers; and
wherein a concentration of the plurality of carbon nanotubes is between 0.08 grams and 0.4 grams per 946 milliliters of the oil and wherein a concentration of the plurality of boron nitride particulates is between 0.08 grams and 0.4 grams per 946 milliliters of the oil.

2. The fluid of claim 1 wherein at least some of the plurality of carbon nanotubes are multi-walled carbon nanotubes.

3. The fluid of claim 1 wherein an average length of the plurality of carbon nanotubes is between 1 micron and 1000 microns.

4. The fluid of claim 1 wherein the boron nitride particulates are hex-boron nitride, cubic boron nitride or wurtzite boron nitride particulates.

5. A concentrate comprising:
a fluid;
a plurality of carbon nanotubes dispersed within the fluid, wherein each carbon nanotube of the plurality of carbon nanotubes has a diameter between 1 nanometer and 80 nanometers and wherein at least 0.76 percent of the plurality of carbon nanotubes have OH functionalized surfaces; and
a plurality of boron nitride particulates dispersed within the fluid, wherein each of the plurality of boron nitride particulates are separate from each of the plurality of carbon nanotubes, and wherein the plurality of boron nitride particulates have an average particle size between 50 nanometers and 90 nanometers; and
wherein the concentrate is configured to be mixed with a predetermined quantity of oil such that the mixture of the predetermined quantity of oil and the concentrate has a carbon nanotube concentration between 0.08 grams and 0.4 grams per 946 milliliters of the oil and a boron nitride particulate concentration between 0.08 grams and 0.4 grams per 946 milliliters of the oil.

6. The concentrate of claim 5 wherein at least some of the plurality of carbon nanotubes are multi-walled carbon nanotubes.

7. The concentrate of claim 5 wherein an average length of the plurality of carbon nanotubes is between 1 micron and 1000 microns.

8. The concentrate of claim 5 wherein each of the boron nitride particulates of the plurality of boron nitride particulates are hex-boron nitride, cubic boron nitride or wurtzite boron nitride particulates.

9. An engine oil additive comprising:
a plurality of unitary carbon nanotubes each having a diameter between 1 nanometer and 80 nanometers, wherein at least 0.76 percent of the plurality of carbon nanotubes have an OH functionalized surface; and
a plurality of unitary boron nitride particulates having an average particle size between 50 nanometers and 90 nanometers;
wherein the additive is configured to be mixed with a predetermined quantity of engine oil such that the mixture has a carbon nanotube concentration between 0.08 grams and 0.4 grams per 946 milliliters of the engine oil and a boron nitride particulate concentration between 0.08 grams and 0.4 grams per 946 milliliters of the engine oil.

10. The engine oil additive of claim 9 wherein at least some of the plurality of carbon nanotubes are multi-walled carbon nanotubes.

11. The engine oil additive of claim 9 wherein an average length of the plurality of carbon nanotubes is between 1 micron and 1000 microns.

12. The engine oil additive of claim 9 wherein each of the boron nitride particulates of the plurality of boron nitride particulates are hex-boron nitride, cubic boron nitride or wurtzite boron nitride particulates.

Assignees

• Novum Nano Llc
• South Dakota Board Of Regents

Inventors

• Bailey Craig
• Christensen Greg
• Hong Haiping

Classifications

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• C10N2030/06

  Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure · CPC title

• C10N2040/25

  Internal-combustion engines · CPC title

• C10M2201/082

  containing nitrogen · CPC title

• C10M125/26

  Compounds containing silicon or boron, e.g. silica, sand · CPC title