Integrated process for mesophase pitch and petrochemical production

Patent metadata

Field	Value
Publication number	US-11319490-B2
Application number	US-202117141963-A
Country	US
Kind code	B2
Filing date	Jan 5, 2021
Priority date	Sep 12, 2017
Publication date	May 3, 2022
Grant date	May 3, 2022

Abstract

An integrated method for mesophase pitch and petrochemicals production. The method including supplying crude oil to a reactor vessel; heating the crude oil in the reactor vessel to a predetermined temperature for a predetermined amount of time; reducing asphaltene content in the crude oil by allowing polymerization reactions to occur in the reactor vessel at an elevated pressure in the absence of oxygen; producing a three-phase upgraded hydrocarbon product comprising gas, liquid, and solid hydrocarbon components, where the liquid hydrocarbon component comprises deasphalted oil and the solid hydrocarbon component comprises mesophase pitch; separating the gas, liquid, and solid hydrocarbon components; directly utilizing the liquid hydrocarbon component for petrochemicals production; and directly utilizing the solid hydrocarbon component for carbon artifact production.

First claim

What is claimed is:

1. An integrated system for mesophase pitch and petrochemicals production, the system comprising:
a crude oil supply fluidly coupled to a reactor vessel, the reactor vessel operable to be heated to a predetermined temperature for a predetermined amount of time, and operable to reduce asphaltene content in the crude oil supply by allowing polymerization reactions to occur in the reactor vessel at an elevated pressure in absence of oxygen, wherein the reactor vessel maintains a void space to be occupied by nitrogen in addition to or alternative to other inert gases between about 10 volume percent and about 80 volume percent of the reactor vessel apart from the crude oil supply during heating to between about 350° C. and about 575° C. and a pressure greater than 1,000 psig;
a three-phase gas, liquid, solid separator operable to separate a three-phase upgraded hydrocarbon product produced in the reactor vessel, the three-phase upgraded hydrocarbon product comprising gas, liquid, and solid hydrocarbon components, where the liquid hydrocarbon component comprises deasphalted oil and the solid hydrocarbon component comprises mesophase pitch; and
a cracking unit, where the cracking unit is fluidly coupled to receive the liquid hydrocarbon component and to crack the liquid hydrocarbon component for petrochemicals production.

2. The system according to claim 1 , further comprising a unit to produce carbon fiber from the mesophase pitch.

3. The system according to claim 1 , where the predetermined temperature is between about 350° C. and about 575° C.

4. The system according to claim 1 , where the predetermined temperature is between about 400° C. and about 450° C.

5. The system according to claim 1 , where the predetermined amount of time is between about 2 hours and about 15 hours.

6. The system according to claim 1 , where the predetermined amount of time is between about 4 hours and about 8 hours.

7. The system according to claim 1 , where asphaltene content in the deasphalted oil is less than about 2% by weight.

8. The system according to claim 1 , where the elevated pressure is greater than about 1,000 psig.

9. The system according to claim 1 , where the elevated pressure is between about 1,800 psig and 1,900 psig.

10. The system according to claim 1 , where the cracking unit includes a fluidized catalytic cracking process.

11. The system according to claim 1 , where the cracking unit includes a steam cracking process.

12. The system according to claim 1 , where the crude oil comprises at least one hydrocarbon selected from the group consisting of: heavy crude oil, light crude oil, and crude oil residue with a boiling point greater than about 500° C.

13. The system according to claim 1 , where an asphaltene compound content of the deasphalted oil is reduced by at least about 50% by mass relative to an asphaltene compound content of the crude oil supply.

14. The system according to claim 1 , where an asphaltene compound content of the deasphalted oil is reduced by at least about 90% by mass relative to an asphaltene compound content of the crude oil supply.

15. The system according to claim 1 , where a metal content in the liquid hydrocarbon component is less than a metal content in the crude oil supply.

16. The system according to claim 1 , where the solid hydrocarbon component is at least about 90% pure mesophase pitch.

17. The system according to claim 1 , where the elevated pressure in the reactor vessel is between about 1,700 psig and about 2,500 psig.

Assignees

• Saudi Arabian Oil Co
• King Abdullah Univ Of Science And Technology Kaust
• Univ King Abdullah Sci & Tech

Inventors

• Mahfouz Remi
• Ali Ola
• Morales Osorio Isidoro
• Xu Wei
• Dong Xinglong
• Han Yu

Classifications

• C10G2300/206

  Asphaltenes · CPC title

• C10G2300/104

  Light gasoline having a boiling range of about 20 - 100 °C · CPC title

• C10C3/002 Primary

  by thermal means · CPC title

• C10G31/06

  by heating, cooling, or pressure treatment · CPC title

• C10G2400/02

  Gasoline · CPC title