Method for recovering carbon fibers from composite material waste

Patent metadata

Field	Value
Publication number	US-11319489-B2
Application number	US-201816482430-A
Country	US
Kind code	B2
Filing date	Mar 30, 2018
Priority date	Apr 1, 2017
Publication date	May 3, 2022
Grant date	May 3, 2022

Abstract

A method for recovering carbon fibers from composite material waste includes coating a solid acid powder onto a surface of a composite material waste having carbon fibers and a resin matrix, pyrolyzing the resin matrix of the coated composite material waste in an inert environment, and oxidizing the pyrolyzed resin of the composite material waste in an air environment.

First claim

What is claimed is:

1. A method for recovering carbon fibers from composite material waste, the method comprising:
coating a solid acid powder onto a surface of a composite material waste having carbon fibers and a resin matrix;
pyrolyzing the resin matrix of the coated composite material waste in an inert environment;
oxidizing the pyrolyzed resin of the composite material waste in an environment containing air; and
after the oxidizing, recovering carbon fibers from the composite material waste.

2. The method of claim 1 wherein the step of coating includes spraying a layer of solid super acid powder onto the surface of the composite material waste.

3. The method of claim 1 wherein the step of pyrolyzing includes putting the composite material waste into a pyrolysis device and connecting nitrogen to expel air from the device to form the inert environment.

4. The method of claim 1 wherein the step of pyrolyzing includes heating the coated composite material waste to a temperature of 500-700° C. for 10 to 30 minutes in the inert environment.

5. The method of claim 4 , further comprising stopping the heating and naturally cooling to 350-450° C.

6. The method of claim 1 wherein the step of oxidizing includes keeping a temperature at 350-450° C. for 10 to 60 minutes.

7. The method of claim 6 , further comprising stopping the heating and naturally cooling to room temperature.

8. The method of claim 1 wherein the resin matrix in the composite material waste includes a thermoset resin.

9. The method of claim 8 wherein the thermoset resin includes at least one of epoxy resin, unsaturated polyester, and phenolic resin.

10. The method of claim 1 wherein the resin matrix in the composite material waste includes a thermoplastic resin.

11. The method of claim 10 wherein the thermoplastic resin includes at least one of polyolefin, nylon, and polyester.

12. The method of claim 1 wherein the carbon fiber in the composite material waste includes at least one of polyacrylonitrile-based carbon fiber and asphalt-based carbon fiber.

13. The method of claim 1 wherein the carbon fiber in the composite material waste includes at least one of continuous fiber, long fiber, short fiber, powder fiber and carbon fiber fabric.

14. The method of claim 1 further comprising crushing the composite material waste before the pyrolyzing step.

15. The method of claim 1 further comprising processing the carbon fibers recovered from the composite material waste after the oxidizing step.

16. A method for recovering carbon fibers from composite material waste, the method comprising:
coating a solid acid powder onto a surface of a composite material waste having carbon fibers and a resin matrix;
heating the coated composite material waste to a temperature of 500-700° C. for 10 to 30 minutes in an inert environment; and
cooling the heated composite material and keeping at a temperature at 350-450° C. for 10 to 60 minutes in an environment containing air; and
after the cooling, recovering carbon fibers from the composite material waste.

17. The method of claim 16 wherein the step of coating includes spraying a layer of solid super acid powder onto the surface of the composite material waste.

18. The method of claim 16 wherein the step of heating the coated composite material waste includes putting the composite material waste into a pyrolysis device and connecting nitrogen to expel air containing oxygen from the device to form the inert environment.

19. The method of claim 16 wherein the resin matrix in the composite material waste includes a thermoset resin.

20. The method of claim 16 wherein the resin matrix in the composite material waste includes a thermoplastic resin.

Assignees

• Boeing Co

Inventors

• Sui Gang
• Yang Xiaoping
• Jin Xin
• Ming Zhu
• Wang Zhandong

Classifications

• C08K7/06

  Elements · CPC title

• C10B57/06 Primary

  containing additives · CPC title

• B29B2017/0496

  Pyrolysing the materials · CPC title

• Y02P20/143

  the feedstock being recycled material, e.g. plastics · CPC title

• D01F9/12

  Carbon filaments; Apparatus specially adapted for the manufacture thereof · CPC title