Sealable and peelable polyester film

Patent metadata

Field	Value
Publication number	US-11319418-B2
Application number	US-201515531106-A
Country	US
Kind code	B2
Filing date	Nov 26, 2015
Priority date	Nov 27, 2014
Publication date	May 3, 2022
Grant date	May 3, 2022

Abstract

The invention discloses bi-axially oriented coated polyester films having high tear initiation resistance and comprising a polyester base film and a heat sealable coating, said heat sealable coating comprising one or more amorphous copolyester(s) comprising units of terephthalic acid, naphthalene dicarboxylic acid and at least one diol. The films are heat-sealable and peelable to polyester and aluminium containers. The invention also relates to a process for the manufacturing of such films, to the use of said films in food packaging and to the packages obtained therefrom.

First claim

The invention claimed is:

1. A biaxially oriented coated polyester film comprising a polyester base film and a heat sealable coating wherein the heat sealable coating comprises (i) one or more amorphous copolyester(s) comprising units of terephthalic acid, naphthalene dicarboxylic acid, (ii) less than 2% by weight of any polymer that is incompatible with polyesters (anti-PET polymer) and (iii) at least a diol, and wherein the heat sealable coating contains from 20 to 50% by weight of terephthalic acid units and from 5 to 25% by weight of naphthalene dicarboxylic acid units, the biaxially oriented coated polyester film having a tear ratio, between the tear initiation force measured according to ASTM D-1004 and the coated film total thickness, of at least 37 gf/micron in at least one of longitudinal and transverse directions.

2. The film according to claim 1 , wherein the tear ratio is at least 39 gf/micron in at least one of longitudinal and transverse directions.

3. The film according to claim 1 , wherein the tear ratio is at east 39 gf/micron in both longitudinal and transverse directions.

4. The film according to claim 1 , wherein free shrink in each direction is less than 5% at temperatures up to 140° C.

5. The film according to claim 1 , wherein free shrink in each direction does not exceed 20% in the range of from 140° C. to 200° C.

6. The film according to claim 1 , wherein the heat sealable coating contains at least one of from 30 to 40% by weight of terephthalic acid units and from 13 to 19% by weight of naphthalene dicarboxylic acid units.

7. The film according to claim 1 , wherein the at least a diol of the heat sealable coating is selected from the group consisting of neopentyl glycol, diethylene glycol, ethylene glycol and their admixtures.

8. The film according to claim 1 , wherein the heat sealable coating comprises from 10 to 25% by weight of neopentyl glycol, from 10 to 25% by weight of diethylene glycol and from 10 to 25% by weight of ethylene glycol.

9. The film according to claim 1 , wherein the heat sealable coating contains from 30 to 40% by weight of terephthalic acid units, from 13 to 19% by weight of naphthalene dicarboxylic acid units, from 15 to 21% by weight of neopentyl glycol, from 11 to 17% by weight of diethylene glycol and from 14 to 20% by weight of ethylene glycol.

10. The film according to claim 1 , wherein the heat sealable coating comprises less than 1% by weight of any polymer that is incompatible with polyesters (anti-PET polymer).

11. The film according to claim 1 , wherein the heat sealable coating has a Tg value, measured by Differential Scanning Calorimeter according to ASTM E-1356 modified as in the present description, in the range from 10° C. to 70° C.

12. The film according to claim 1 , wherein the heat-sealable coating has a dry coat weight (grammage) from 0.5 to 6.0 g/m 2 .

13. The use of the biaxially oriented coated polyester film according to claim 1 for packaging food.

Assignees

• Cryovac Inc
• Cryovac Llc

Inventors

• Roberto Forloni
• Stracuzzi Serena

Classifications

• B32B27/08

  of synthetic resin · CPC title

• C09D167/00

  Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain (based on polyester-amides C09D177/12; based on polyester-imides C09D179/08); Coating compositions based on derivatives of such polymers · CPC title

• C08G63/189

  containing a naphthalene ring · CPC title

• C08J2367/00

  Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers · CPC title

• C08J7/0427

  with only one layer of a composition containing a polymer binder (with more layers C08J7/042) · CPC title