Method for producing a separation product containing predominantly hydrocarbons with two carbon atoms

Patent metadata

Field	Value
Publication number	US-11319264-B2
Application number	US-201716325058-A
Country	US
Kind code	B2
Filing date	Aug 14, 2017
Priority date	Aug 12, 2016
Publication date	May 3, 2022
Grant date	May 3, 2022

Abstract

The invention relates to a method (100) for the recovery of a separation product which contains predominantly hydrocarbons with two carbon atoms, with the use of a separation feedstock which contains predominantly methane, hydrogen and hydrocarbons with two carbon atoms, wherein the methane content of the separation feedstock is up to 20%, and the separation feedstock is provided in a gaseous state. It is provided that, at a first pressure level, the separation feedstock is partially condensed in a single step by cooling from a first temperature level to a second temperature level, thereby obtaining precisely one first liquid fraction and precisely one first gaseous fraction; at least one part of the first gaseous fraction is partially condensed in a single step through further cooling from the second temperature level to a third temperature level, thereby obtaining precisely one second liquid fraction and precisely one second gaseous fraction; at least one part of the second gaseous fraction at the second pressure level is subjected to a contraflow absorption in the contraflow to an absorption liquid containing predominantly methane, thereby obtaining precisely one third liquid fraction and precisely one third gaseous fraction; the first, the second and the third liquid fraction are at least partially combined and, at least partially, at a second pressure level above the first pressure level, subjected to a low-temperature rectification, thereby obtaining a sump liquid and an overhead gas; at least one part of the overhead gas at the second pressure level is partially condensed in a single step through further cooling from the second temperature level to the third temperature level, thereby obtaining a fourth liquid fraction and a fourth gaseous fraction; and the absorption liquid containing predominantly methane is formed through further cooling of at least a part of the fourth gaseous fraction to a fourth temperature level. A corresponding plant also forms the subject matter of the invention.

First claim

The invention claimed is:

1. A method for the recovery of a separation product which contains predominantly hydrocarbons with two carbon atoms comprising:
providing a separation feedstock which contains predominantly methane, hydrogen and hydrocarbons with two carbon atoms, wherein the methane content of the separation feedstock is up to 30%, and the separation feedstock is provided in a gaseous state,
partially condensing the separation feedstock at a first pressure level in a single step by cooling from a first temperature level at −20 to −35° C. to a second temperature level at −75 to −80° C., and recovering one first liquid fraction and one first gaseous fraction
partially condensing at least a part of the first gaseous fraction at the first pressure level in a single step through further cooling to a third temperature level, thereby obtaining one second liquid fraction and one second gaseous fraction,
subjecting at least one part of the second gaseous fraction at the first pressure level to a contraflow absorption with an absorption liquid containing predominantly methane, thereby obtaining one third liquid fraction and one third gaseous fraction,
combining, at least partially, the first, the second and the third liquid fraction and, at a second pressure level above the first pressure level, at least partially subjecting the combined liquid fractions to a low-temperature rectification, thereby obtaining a sump liquid and an overhead gas,
partially condensing at least a part of the overhead gas at the second pressure level in a single step through further cooling to a fourth temperature level, thereby obtaining a fourth liquid fraction and a fourth gaseous fraction,
cooling at least a part of the fourth gaseous fraction to a fifth temperature level to form at least a portion of the absorption liquid containing predominantly methane.

2. The method according to claim 1 , in which the third temperature level is at −100 to −105° C., and/or the fourth temperature level is at −95 to −100° C., and/or the fifth temperature level is at −140 to −155° C.

3. The method according to claim 1 , in which the first pressure level is at 32 to 37 bar, and/or the second pressure level is at 35 to 40 bar.

4. The method according to claim 1 , in which, for the contraflow absorption, an absorption column is used, which comprises a sump region and an absorption region separated from the sump region by a liquid barrier, which is arranged above the sump region, wherein the liquid barrier is constituted in such a manner that it allows liquid which collects in a lower region of the absorption region on the liquid barrier, to drain downwards into the sump region and, in this context, prevents a rising upwards of gas from the sump region into the absorption region.

5. The method according to claim 4 , in which the separation feedstock cooled from the first temperature level to the second temperature level is fed into the sump region as a two-phase mixture, wherein, within the latter, the first liquid fraction is separated from the first gaseous fraction.

6. The method according to claim 5 , in which the first gaseous fraction or its part further cooled to the third temperature level is fed at the sump end as a two-phase mixture into the absorption region, wherein, within the latter, the second liquid fraction is separated from the second gaseous fraction.

7. The method according to claim 6 , in which the third liquid fraction is combined with the second liquid fraction, the liquid barrier and released via the liquid barrier into the sump region, where it is combined with the first liquid fraction.

8. The method according to claim 1 , in which the first, the second and the third liquid fraction or their combined parts are compressed by means of a sump pump and transferred into a rectification column used for the low-temperature rectification.

9. The method according to claim 8 , in which, for the partial condensation of the overhead gas or of its part, an overhead condenser of the rectification column which is cooled with the use of low-pressure ethylene is used.

10. The method according to claim 1 , in which at least a part of the third gaseous fraction at the first pressure level is partially condensed in a single step through further cooling to the fifth temperature level, thereby obtaining precisely one fifth liquid fraction and precisely one fifth gaseous fraction.

11. The method according to claim 10 , in which, for the cooling of the third and of the fourth gaseous fraction or their parts, at least one heat exchanger is used, which is cooled with the use of at least one part of the fifth liquid fraction and the fifth gaseous fraction.

12. The method according to claim 10 , in which, for the cooling of the separation feedstock, at least one heat exchanger is used, which is cooled with the use of at least one part of the fifth liquid fraction and of the fifth gaseous fraction and with high-pressure and medium-pressure ethylene.

13. The method according to claim 1 , in which, for the cooling of the first gaseous fraction, at least one heat exchanger is used, which is cooled with the use of at least one part of the fifth liquid fraction and of the fifth gaseous fraction and with low-pressure ethylene.

Assignees

• Linde Ag

Inventors

• Pham Duc Tuat
• Spindelndreher Anne
• Kurz Benedikt

Classifications

• B01D53/1487

  Removing organic compounds · CPC title

• C07C4/04

  Thermal processes {(C07C4/025 takes precedence)} · CPC title

• B01D3/143 Primary

  by two or more of a fractionation, separation or rectification step · CPC title

• C07C7/09 Primary

  by fractional condensation · CPC title

• Y02P30/40

  Ethylene production · CPC title