Ceramic heat shields having surface infiltration for preventing corrosion and erosion attacks

Patent metadata

Field	Value
Publication number	US-11319257-B2
Application number	US-201716339727-A
Country	US
Kind code	B2
Filing date	Sep 22, 2017
Priority date	Oct 17, 2016
Publication date	May 3, 2022
Grant date	May 3, 2022

Abstract

An improved ceramic heat shield for a gas turbine is provided. The ceramic heat shield has a porous ceramic body and according to the embodiments an infiltration coating that is provided in a surface layer of the porous ceramic body and contains an infiltration coating material designed to gas-tightly seal pores of the ceramic body.

First claim

The invention claimed is:

1. A ceramic heat shield for a gas turbine, comprising:
a porous ceramic body, including a surface, a surface layer and pores, wherein the porous ceramic body comprises mullite; and
an infiltration coating which is infiltrated and penetrated into the surface layer of the porous ceramic body, which includes yttrium aluminum garnet that is configured for closing the pores of the surface layer of the porous ceramic body, and which has been fired in a firing procedure to establish a crystalline compound with the porous ceramic body and yttrium aluminum garnet and reactive phases, transition phases and dendrites between the porous ceramic body and the infiltration coating,
wherein the infiltration coating does not extend past the surface of the porous ceramic body.

2. The ceramic heat shield of claim 1 , wherein the porous ceramic body consists substantially of mullite.

3. The ceramic heat shield of claim 1 , wherein the infiltration coating material consists substantially of yttrium aluminum garnet.

4. The ceramic heat shield as claimed in claim 1 , wherein the infiltration coating is at least 10 μm thick and up to 600 μm thick.

5. The ceramic heat shield as claimed in claim 1 , wherein the surface layer extends across an end face and across lateral faces of the porous ceramic body.

6. The ceramic heat shield as claimed in claim 1 , wherein the infiltration coating comprises a thickness of 400 μm.

7. A gas turbine or a combustion chamber having a ceramic heat shield as claimed in claim 1 .

8. A method for producing a ceramic heat shield for a gas turbine, comprising the following method steps:
providing a porous ceramic body, wherein the porous ceramic body comprises mullite;
generating an infiltration coating in a surface layer of the porous ceramic body, wherein the infiltration coating contains an infiltration coating material which is configured for closing pores of the porous ceramic body in a gas-tight manner, wherein the infiltration coating does not extend past the surface of the porous ceramic body, wherein the infiltration coating material comprises yttrium aluminum garnet, and wherein the generating of the infiltration coating includes immersing the porous ceramic body in a suspension containing the infiltration coating material and firing the porous ceramic body to establish a crystalline compound with the porous ceramic body and yttrium aluminum garnet and reactive phases, transition phases and dendrites between the porous ceramic body and the infiltration coating.

9. The method as claimed in claim 8 , comprising a step of masking part of a surface of the porous ceramic body prior to immersing the porous ceramic body in the suspension.

10. The method as claimed in claim 8 , wherein one or a plurality steps of preparing the suspension comprises/comprise a step of melting and stabilizing the melt of the infiltration coating material.

11. The method as claimed in claim 10 , wherein the step of preparing the suspension comprises a step of grinding the infiltration material to at least one of the sub-micrometer range, a particle size ≤1 μm, and 500 nm to 100 nm.

12. The method as claimed in claim 8 , wherein the infiltration is performed at a plurality of cycles.

13. The method as claimed in claim 8 , wherein an overcoating of the infiltrated region is performed.

14. The method as claimed in claim 8 , wherein the infiltration is performed at a positive pressure of up to 5 bar.

15. A refurbishment method comprising the following steps:
removing at least one existing ceramic heat shield from a gas turbine; and
installing a replacement ceramic heat shield in the gas turbine, the replacement ceramic heat shield comprising:
a porous ceramic body, including a surface, a surface layer and pores, wherein the porous ceramic body comprises mullite; and
an infiltration coating which is infiltrated and penetrated into the surface layer of the porous ceramic body, which includes yttrium aluminum garnet that is configured for closing the pores of the surface layer of the porous ceramic body, and which has been fired in a firing procedure to establish a crystalline compound with the porous ceramic body and yttrium aluminum garnet and reactive phases, transition phases and dendrites between the porous ceramic body and the infiltration coating,
wherein the infiltration coating does not extend past the surface of the porous ceramic.

Assignees

• Siemens Ag
• Siemens Energy Global Gmbh & Co Kg

Inventors

• Reinger Marco
• Stamm Werner

Classifications

• F23R3/007

  constructed mainly of ceramic components · CPC title

• F23M5/00

  Casings; Linings; Walls · CPC title

• C04B41/87 Primary

  Ceramics · CPC title

• F23M2900/05004

  Special materials for walls or lining · CPC title

• C04B41/009

  characterised by the material treated · CPC title