Stretchable film structure and method of making the same

Patent metadata

Field	Value
Publication number	US-11319210-B2
Application number	US-201916379287-A
Country	US
Kind code	B2
Filing date	Apr 9, 2019
Priority date	Jun 29, 2018
Publication date	May 3, 2022
Grant date	May 3, 2022

Abstract

A method of making a stretchable film structure is provided. An elastic substrate is pre-stretched in a first direction and a second direction to obtain a pre-stretched elastic substrate. A carbon nanotube film structure is laid on a surface of the pre-stretched elastic substrate. The carbon nanotube film structure comprises a plurality of super-aligned carbon nanotube films stacked with each other. The pre-stretching the elastic substrate is removed and a plurality of wrinkles is formed on a surface of the carbon nanotube film structure to form the stretchable film structure. The present disclosure also relates to the stretchable film structure obtained by the above method.

First claim

What is claimed is:

1. A method of making a stretchable film structure comprising:
step (S 1 ): providing an elastic substrate, and pre-stretching the elastic substrate along a first direction and a second direction intersecting with the first direction, to obtain a pre-stretched elastic substrate;
step (S 2 ): laying a carbon nanotube film structure on a surface of the pre-stretched elastic substrate, and the carbon nanotube film structure comprising a plurality of super-aligned carbon nanotube films stacked with each other, each of the plurality of super-aligned carbon nanotube films comprising a plurality of carbon nanotubes substantially parallel with each other;
step (S 3 ): releasing the pre-stretching of the elastic substrate to restore deformations of the elastic substrate, and forming a plurality of wrinkles on a surface of the carbon nanotube film structure, wherein the plurality of wrinkles are able to unfold simultaneously in multiple different stress directions; and
step (S 4 ): removing the elastic substrate after step (S 3 ).

2. The method of claim 1 , wherein the first direction is perpendicular with the second direction.

3. The method of claim 1 , wherein the elastic substrate is biaxial pre-stretched along each of the first direction the second direction.

4. The method of claim 3 , wherein a shape of the elastic substrate is a rectangle, the elastic substrate is biaxial pre-stretched both along the first direction and the second direction, the first direction is parallel with a long side of the rectangle, and the second direction is parallel with a short side of the rectangle.

5. The method of claim 1 , wherein the elastic substrate is uniaxial pre-stretched along the first direction and the second direction.

6. The method of claim 1 , wherein in step (S 1 ) the elastic substrate is pre-stretched to a same amount of strain in the first direction and in the second direction.

7. The method of claim 6 , wherein the elastic substrate is pre-stretched to 150% strain in both the first and the second directions.

8. The method of claim 1 , wherein the plurality of carbon nanotubes are differently aligned between adjacent two of the super-aligned carbon nanotube films to form a grid structure, and alignment directions of the plurality of carbon nanotubes between adjacent two of the super-aligned carbon nanotube films intersect with each other/are different.

9. The method of claim 8 , wherein a angle of an angle of the alignment directions of the plurality of carbon nanotubes between adjacent two of the super-aligned carbon nanotube films is about 90 degrees.

10. The method of claim 1 , wherein each of the plurality of super-aligned carbon nanotube films is drawn from a super-aligned carbon nanotube array.

11. The method of claim 1 , wherein a method of laying the carbon nanotube film structure on the surface of the pre-stretched elastic substrate comprises: step (I), drawing a first carbon nanotube film from a carbon nanotube array and laying the first carbon nanotube film on the surface of the pre-stretched elastic substrate; step (II), drawing a second carbon nanotube film from the carbon nanotube array and laying the second carbon nanotube film on a surface of the first carbon nanotube film, to make the second carbon nanotube film stack with the first carbon nanotube film; and step (III), repeating step (III) to obtain the carbon nanotube film structure.

12. The method of claim 1 , wherein an extending direction of the carbon nanotubes of the carbon nanotube film structure is parallel with the first direction or the second direction.

13. The method of claim 1 , wherein after step (S 2 ) and before step (S 3 ), an organic solvent is applied on the carbon nanotube film structure to soak the carbon nanotube film structure.

14. The method of claim 1 , wherein the plurality of wrinkles is formed by a plurality of carbon nanotubes of the carbon nanotube film structure bending along a direction substantially perpendicular to the surface of the elastic substrate.

15. The method of claim 1 , wherein a material of the elastic substrate is silicone rubber, polyvinyl chloride, polytetrafluoroethylene, polyurethane, polyvinyl chloride, or poly dimethylsiloxane.

16. A stretchable film structure consisting of a plurality of super-aligned carbon nanotube films stacked with each other, wherein each of the plurality of super-aligned carbon nanotube films consists of a plurality of carbon nanotubes joined end to end by van der Waals forces and parallel with each other; a surface of the plurality of super-aligned carbon nanotube films comprises a plurality of wrinkles, and the plurality of wrinkles are able to unfold simultaneously in multiple different stress directions.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Yu Yang
• Wang Jia-Ping
• Jiang Kai-Li
• Fan Shou-Shan

Classifications

• C01B2202/26

  Mechanical properties · CPC title

• C01B32/16 Primary

  Preparation · CPC title

• B32B2307/5825

  Tear resistant · CPC title

• B32B9/04

  comprising such {particular} substance as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a glass layer B32B17/06; layered products with at least two ceramic layers composed mainly of ceramic B32B18/00)} · CPC title

• C01B2202/08

  Aligned nanotubes · CPC title