Conversion of gas and treatment of a solution

Patent metadata

Field	Value
Publication number	US-11318416-B2
Application number	US-201515301241-A
Country	US
Kind code	B2
Filing date	Apr 2, 2015
Priority date	Apr 2, 2014
Publication date	May 3, 2022
Grant date	May 3, 2022

Abstract

A method and system for reducing ion concentration of a solution and converting gas. The system comprising a multi-chamber unitary dialysis cell comprising a gas chamber, a product chamber, and an acid chamber. Ion exchange barriers separate the chambers of the dialysis cell. A first anion exchange barrier is positioned between the product chamber and the acid chamber and a first cation exchange barrier is positioned between the product chamber and the gas chamber. Anions from the solution being treated associate with cations from the acid chamber to form an acid solution in the acid chamber, and cations from the solution being treated associate with anions from the fluid comprising gas to form salt, thereby reducing the ion concentration of the solution being treated and converting at least a portion of the gas into salt.

First claim

The invention claimed is:

1. A method for producing an acid and a salt, the method comprising:
(a) providing a multi-chamber dialysis cell with ion exchange barriers comprising a first anion exchange barrier and a first cation exchange barrier, the ion exchange barriers separating chambers of the dialysis cell, the dialysis cell comprising:
(i) a gas chamber;
(ii) a product chamber;
(iii) an acid chamber;
(iv) the first anion exchange barrier positioned between the product chamber and the acid chamber;
(v) the first cation exchange barrier positioned between the product chamber and the gas chamber;
(vi) a cathode in the gas chamber; and
(vii) an anode;
wherein the first anion exchange barrier and the first cation exchange barrier are between the cathode and the anode;

(b) flowing a fluid consisting of a gas in the gas phase or a mixture of the gas in the gas phase with one or more other gases in the gas phase through the gas chamber, and flowing a first solution through the product chamber; and
(c) applying an electric potential between the anode and the cathode
wherein:
the gas is carried by the fluid to the cathode and, at the cathode, the gas in the gas phase undergoes a half-cell reaction at the cathode to yield first anions, wherein the gas comprises carbon dioxide, hydrogen sulfide, sulfur dioxide, nitrogen dioxide, or a combination thereof;
second anions in the first solution migrate across the first anion exchange barrier to associate with cations in the acid chamber to form an acid solution comprising the acid in the acid chamber; and
cations in the first solution migrate across the first cation exchange barrier to associate with the first anions to form the salt, thereby reducing the ion concentration of the first solution and converting at least a portion of the gas into the salt.

2. The method according to claim 1 , further comprising removing the acid solution, the first solution with reduced ion concentration, and the salt from the dialysis cell.

3. The method according to claim 1 , further comprising flowing a second solution through a salt concentration chamber positioned between the product chamber and the gas chamber,
wherein the cations from the first solution migrate across the first cation exchange barrier to the salt concentration chamber, and the first anions migrate to the salt concentration chamber across a second anion exchange membrane positioned between the gas chamber and the salt concentration chamber, wherein the cations from the first solution and the first anions associate to form the salt in the salt concentration chamber, thereby increasing the salt concentration of the second solution flowing through the salt concentration chamber.

4. The method according to claim 1 , further comprising flowing the acid solution through the acid chamber.

5. The method according to claim 1 , wherein the anode and/or the cathode comprises a catalyst.

6. The method according to claim 5 , wherein the anode is positioned in the acid chamber.

7. The method according to claim 1 , further comprising monitoring ion concentration of the first solution and controlling conditions within the dialysis cell to maintain the ion concentration of the first solution within a predetermined range.

8. The method according to claim 1 , further comprising monitoring concentration and/or pH of the acid solution in the acid chamber and controlling conditions within the dialysis cell to maintain the concentration and/or pH of the acid solution within a predetermined range.

9. The method of claim 8 , wherein the concentration and/or pH of the acid solution in the acid chamber is monitored using one or more sensors.

10. The method according to claim 1 , wherein one or more of the ion exchange barriers comprise a catalyst.

11. The method of claim 1 , wherein the gas comprises carbon dioxide.

12. The method of claim 11 wherein the first anions comprise bicarbonate anions, carbonate ions, formate anions or a mixture thereof.

13. The method of claim 1 , wherein the gas comprises hydrogen sulphide and/or sulphur dioxide.

14. The method of claim 1 , wherein the gas additionally comprises oxygen.

15. The method of claim 1 , comprises supplying air and/or oxygen to the cathode.

Assignees

• Univ British Columbia
• Mangrove Water Tech Ltd

Inventors

• Wilkinson David
• Bonakdarpour Arman
• Lam Alfred
• Dara Mohammad Saad

Classifications

• Y02C20/40

  of CO2 · CPC title

• B01D61/422

  Electrodialysis · CPC title

• B01D61/46

  Apparatus therefor · CPC title

• Y02W10/37

  using solar energy · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title