Energy storage device

Patent metadata

Field	Value
Publication number	US-11316206-B2
Application number	US-202016857198-A
Country	US
Kind code	B2
Filing date	Apr 24, 2020
Priority date	Apr 25, 2019
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

An energy storage device comprises two electrodes; and a separator disposed between the electrodes; wherein at least one of the electrodes and the separator comprises a copolymer, which serves as a non-aqueous binder and/or solid electrolyte for the electrodes and the separator of the energy storage device, and the copolymer is a copolymerized product or its derivative formed by the polymerization reaction of acrylonitrile and vinyl acetate. Therefore, the charge and discharge properties of the energy storage device using the copolymer can be improved, thereby effectively extending the efficiency and lifetime of the energy storage device.

First claim

What is claimed is:

1. An energy storage device, comprising:
two electrodes; and
a separator disposed between the electrodes;
wherein at least one of the electrodes and the separator comprises a copolymer having the following structure:

wherein:
G I is derived from acrylonitrile;
G II is derived from vinyl acetate;
G III is derived from at least one monomer having a reactive functional group, wherein R 3 comprises an ester group having a C 1 -C 30 saturated or unsaturated alkyl group, a hydroxy group, an epoxy group, an isocyanate group, an amino group or a combination thereof; and
G IV is derived from at least one olefinic monomer; wherein R 4 comprises an amide group, a pyrrolidone group, a C 1 -C 30 saturated or unsaturated alkyl group, a phenyl group, a benzyl group or a combination thereof;
wherein R 1 is H or CH 3 ; and
wherein the number of repeating units of the copolymer satisfies the following conditions:

a

a
+
b
+
c
+
d

>
0

,

b

a
+
b
+
c
+
d

>
0

,

c

a
+
b
+
c
+
d

≥
0

,

and
⁢

⁢

d

a
+
b
+
c
+
d

≥

0
.

2. The energy storage device of claim 1 , wherein:
G III is derived from at least one monomer having a reactive functional group, wherein the monomer having the reactive functional group are selected from the group consisting of methyl acrylate, Glycidyl methacrylate, Glycidyl acrylate, Vinyl epoxy cyclohexane, 2-(2-Oxiranylmethoxy)ethyl methacrylate, 2-Hydroxyethyl methacrylate, Allylamine and vinylamine; and
G IV is derived from at least one olefinic monomer; wherein the olefinic monomer is selected from the group consisting of Acrylamide, N-Vinylpyrrolidone, N,N-Dimethylacrylamide, 2-Ethylhexyl acrylate, N-Vinylpyrrolidone, Vinyl chloride, vinylidene chloride, vinyl bromide, n-Butyl acrylate, isobutyl acrylate, Dibutyl Itaconate, Dimethyl maleate, Diethyl maleate, Dibutyl maleate, Styrene, Methyl acrylate, Vinyl pyridine, Methyl methacrylate, 1,3-Butadiene, and Isoprene.

3. The energy storage device of claim 2 , wherein the energy storage device is a battery, and the electrodes comprise an anode and a cathode.

4. The energy storage device of claim 3 , wherein an anode of the energy storage device comprises an active material, a conductive carbon and the copolymer, and a content of the copolymer is 0.01 to 30% by weight of the anode, wherein the copolymer is used alone or blended with a polymer to serve as an anode adhesive.

5. The energy storage device of claim 3 , wherein a content of the copolymer is 0.01 to 30% by weight of a cathode of the energy storage device, wherein the copolymer is used alone or blended with a polymer to serve as a cathode adhesive.

6. The energy storage device of claim 2 , wherein the copolymer is further modified or cross-linked with a compound having an amino group, an isocyanate group, a Hydroxyl group, a Carboxylic group or an imidazole group; or Taurine, 1,3-Propanesultone, a derivative thereof, or a combination thereof.

7. The energy storage device of claim 2 , wherein the separator is formed by coating a slurry or formula, wherein a content of the copolymer is 0.1 to 30% by weight of the slurry or formula.

8. The energy storage device of claim 2 , wherein the copolymer is blended with a polymer as a solid electrolyte of the energy storage device, and a content of the copolymer is 0.1 to 90% by weight of the solid electrolyte.

9. The energy storage device of claim 1 , wherein the energy storage device is a battery, and the electrodes comprise an anode and a cathode.

10. The energy storage device of claim 9 , wherein an anode of the energy storage device comprises an active material, a conductive carbon and the copolymer, and a content of the copolymer is 0.01 to 30% by weight of the anode, wherein the copolymer is used alone or blended with a polymer to serve as an anode adhesive.

11. The energy storage device of claim 9 , wherein a content of the copolymer is 0.01 to 30% by weight of a cathode of the energy storage device, wherein the copolymer is used alone or blended with a polymer to serve as a cathode adhesive.

12. The energy storage device of claim 1 , wherein the copolymer is further modified or cross-linked with a compound having an amino group, an isocyanate group, a Hydroxyl group, a Carboxylic group or an imidazole group; or Taurine, 1,3-Propanesultone, a derivative thereof, or a combination thereof.

13. The energy storage device of claim 1 , wherein the separator is formed by coating a slurry or formula, wherein a content of the copolymer is 0.1 to 30% by weight of the slurry or formula.

14. The energy storage device of claim 1 , wherein the copolymer is blended with a polymer as a solid electrolyte of the energy storage device, and a content of the copolymer is 0.1 to 90% by weight of the solid electrolyte.

Assignees

• Univ Nat Cheng Kung
• Rising Chemical Co Ltd
• Polybatt Mat Co Ltd

Inventors

• Kuo Ping-Lin
• Tsao Chih-Hao
• Chin Chia-Wei

Classifications

• H01M50/414

  Synthetic resins, e.g. thermoplastics or thermosetting resins · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• H01G11/48

  Conductive polymers · CPC title

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• H01G11/52

  Separators · CPC title