Functionalization of carbon for embedding in chalcogen particles to enhance electronic conductivity

Patent metadata

Field	Value
Publication number	US-11316166-B2
Application number	US-201514985170-A
Country	US
Kind code	B2
Filing date	Dec 30, 2015
Priority date	Dec 30, 2015
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

A particle having a core of elemental chalcogen elements, such as sulfur, selenium and tellurium, and a coating of at least one polymeric layer on the core. A functionalized conductive carbon material is dispersed in the core. A cathode containing the particles and a battery constructed with the cathode are also provided.

First claim

The invention claimed is:

1. An electrode active material, comprising:
a core particle of at least one element selected from the group consisting of sulfur, selenium and tellurium; and
a coating of at least one polymeric layer encapsulating the core particle;
wherein the core particle comprises particles of a functionalized conductive carbon material which are homogenously dispersed throughout the at least one element of the core particle,
wherein an amount of the functionalized conductive carbon material homogenously dispersed throughout the at least one element of the core particle is from 1.0 to 15% by weight of a total weight of the core particle,
the functionalized conductive carbon material comprises carboxyl groups on at least a surface of the particle of the functionalized conductive carbon material, and
a Zeta potential of the functionalized conductive carbon material ranges from −20 mV to −60 mV when measured in distilled water.

2. The electrode active material of claim 1 , wherein an amount of the functionalized conductive carbon material homogenously dispersed throughout the at least one element of the core particle is from 1.0 to 10% by weight of a total weight of the core particle.

3. The electrode active material of claim 1 , wherein a particle size of the functionalized conductive carbon material particle is from 25 nm to 500 nm.

4. The electrode active material of claim 1 , wherein a BET surface area of the functionalized conductive carbon material particle is from 1000 to 1600 m 2 /g.

5. The electrode active material of claim 1 , wherein the coating comprises a layer of at least one polymer selected from the group consisting of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate, polyvinylpyrrolidone, polyaniline, poly(ethylene oxide), carboxymethyl cellulose, sodium carboxymethylcellulose, polymethacrylic acid, [poly(2-acrylamido-2-methyl-1-propanesulfonic acid)], branched polyethylenimine, and poly(diallyldimethylammoniumchloride).

6. The electrode active material of claim 1 , wherein the functionalized conductive carbon material is COOH functionalized superconductive carbon black.

7. A method for preparing an electrode active material, comprising:
a core particle of at least one element selected from the group consisting of sulfur, selenium and tellurium; and
a coating of at least one polymeric layer encapsulating the core particle;
wherein the core particle comprises particles of a functionalized conductive carbon material which are homogenously dispersed throughout the at least one element of the core particle;
the method comprising:
mixing an aqueous solution of a polymer with an aqueous solution of a soluble precursor of at least one element selected from the group consisting of sulfur, selenium and tellurium to form a first mixture;
mixing an acid with the particles of functionalized conductive carbon material to form a second mixture; and
adding the second mixture to the first mixture to obtain the electrode active material.

8. The method of claim 7 , wherein the soluble precursor of sulfur is sodium thiosulfate.

9. The method of claim 7 , wherein an amount of the functionalized conductive carbon material particles is from 1.0 to 15% by weight of a total weight of the core particle.

10. The method of claim 7 , wherein a Zeta potential of the functionalized conductive carbon material particle is from −20 mV to −60 mV when measured in distilled water.

11. The method of claim 7 , wherein the functionalized conductive carbon material comprises carboxyl groups on at least a surface of the functionalized conductive carbon material particle.

12. The method of claim 7 , wherein a particle size of the functionalized conductive carbon material particle is from 25 nm to 500 nm.

13. The method of claim 7 , wherein a BET surface area of the functionalized conductive carbon material particle is from 1000 to 1600 m 2 /g.

14. The method of claim 7 , wherein the acid is at least one selected from the group consisting of hydrochloric acid, oxalic acid, ascorbic acid, concentrated sulfuric acid, nitric acid, methanesulfonic acid and a mixture thereof.

15. The method of claim 7 , wherein the polymer is at least one polymer selected from the group consisting of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate, polyvinylpyrrolidone, polyaniline, poly(ethylene oxide), carboxymethyl cellulose, sodium carboxymethylcellulose, polymethacrylic acid, [poly(2-acrylamido-2-methyl-1-propanesulfonic acid)], branched polyethylenimine, and poly(diallyldimethylammoniumchloride).

16. A cathode comprising:
a conductive substrate, and
the electrode active material of claim 1 .

17. A battery, comprising:
an anode comprising a metal as an active source of metal ions, and
the cathode of claim 16 .

18. A vehicle, comprising the battery of claim 17 .

Assignees

• Toyota Eng & Mfg North America

Inventors

• Bucur Claudiu B
• Osada Naoki
• Muldoon John
• Jones Mike

Classifications

• H01M4/366

  as layered products · CPC title

• H01M4/38

  of elements or alloys · CPC title

• H01M2220/20

  Batteries in motive systems, e.g. vehicle, ship, plane · CPC title

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title