Gas sensor and method of manufacturing the same

Patent metadata

Field	Value
Publication number	US-11313825-B2
Application number	US-202016912233-A
Country	US
Kind code	B2
Filing date	Jun 25, 2020
Priority date	Jul 18, 2019
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

A gas sensor (1) including a sensor element (10) and a separator (90) having an element hole (90 h), as viewed from one of a forward-end or a rear-end side in the axial direction. The separator has end surfaces (90 e) located axially farthest toward the one of the forward-end or the rear-end side, recess regions (90 h), (90 r 1) and (90 r 2) recessed from the end surfaces, and regions R1 and R2. First regions R1 are determined by eliminating a region SB occupied by the sensor element from a region SA defined by imaginary short-side lines and the outer edge of the separator. Second regions R2 are determined by eliminating the region SB from a region SC defined by imaginary long-side lines and the outer edge of the separator. S2/S1≥0.5 is satisfied, where S1 is the total area of R1 and R2, and S2 is the total area of the recess regions.

First claim

What is claimed is:

1. A gas sensor comprising:
a sensor element extending in an axial direction, having an approximately rectangular cross section taken perpendicularly to the axial direction and having a pair of long sides and a pair of short sides, the sensor element having an electrode pad on an outer surface of a rear end portion thereof;
a metal terminal member in direct contact with the electrode pad for electrical connection; and
a separator formed of ceramic, having an element hole that extends therethrough in the axial direction while surrounding the rear end portion of the sensor element, and holding the metal terminal member such that the metal terminal member is exposed to the element hole,
as viewed from one of a forward-end side or a rear-end side in the axial direction, the separator has an end surface which is a surface located farthest in the axial direction toward the one of the forward-end side or the read-end side, and recess regions recessed from the end surface and including the element hole;
wherein, in a view of the gas sensor from the one of the forward-end side or the rear-end side, a pair of first regions and a pair of second regions are present in the separator, where the first regions are determined by eliminating a region SB occupied by the sensor element from a region SA defined by an outer edge of the separator and imaginary short-side lines obtained by imaginarily extending the two short sides and where the second regions are determined by eliminating the region SB from a region SC defined by the outer edge of the separator and imaginary long-side lines obtained by imaginarily extending the two long sides such that the second regions do not overlap the first regions,
wherein the recess regions are present in all the first regions and the second regions which are located around the sensor element and the total number of which is four, and
wherein a relation of S2/S1≥0.5 is satisfied, where s1 is a total area of the first regions and the second regions, and S2 is a total area of the recess regions including the element hole.

2. The gas sensor as claimed claim 1 , wherein a relation of S4/S1≥0.5 is satisfied, where S4 is a remainder after eliminating an area S3 of the element hole from the total area S2 of the recess regions.

3. The gas sensor as claimed in claim 1 , wherein the recess regions extend to an outer circumference of the separator.

4. The gas sensor as claimed in claim 1 , wherein the recess regions are present on both of the forward-end and rear-end sides of the separator.

5. The gas sensor as claimed in claim 1 , wherein when the separator is placed on a horizontal surface with the end surface facing vertically downward, the separator stands by itself with only the end surface in contact with the horizontal surface.

6. The gas sensor as claimed in claim 1 , wherein two of the recess regions are present at opposing short sides of the sensor element and another two of the recess regions are present at opposing long sides of the sensor element.

7. A method of manufacturing a gas sensor, the gas sensor comprising:
a sensor element extending in an axial direction, having an approximately rectangular cross section taken perpendicularly to the axial direction and having a pair of long sides and a pair of short sides, the sensor element having an electrode pad on an outer surface of a rear end portion;
a metal terminal member in direct contact with the electrode pad for electrical connection; and
a separator formed of ceramic, having an element hole that extends therethrough in the axial direction while surrounding the rear end portion of the sensor element, and holding the metal terminal member such that the metal terminal member is exposed to the element hole,
as viewed from one of a forward-end side or a rear-end side in the axial direction, the separator has an end surface which is a surface located farthest in the axial direction toward the one of the forward-end side or the rear-end side, and recess regions recessed from the end surface and including the element hole;
the method comprising a step of placing a green separator on a firing bed with its end surface facing the firing bed, followed by firing to obtain the separator,
wherein, in a view of the green separator from the one of the forward-end side or the rear-end side, a pair of first regions and a pair of second regions are present, where the first regions are determined by eliminating an element-insertion-expected region SD into which the sensor element is to be inserted, from a region SA defined by an outer edge of the green separator and imaginary short-side lines obtained by imaginarily extending a pair of short sides of the region SD and where the second regions are determined by eliminating the region SD from a region SC defined by the outer edge of the green separator and imaginary long-side lines obtained by imaginarily extending a pair of long sides of the region SD such that the second regions do not overlap the first regions,
wherein the recess regions are present in all the first regions and the second regions which are located around the element-insertion-expected region SD and the total number of which is four, and
wherein a relation of S2/S1≥0.5 is satisfied, where S1 is a total area of the first regions and the second regions, and S2 is a total area of the recess regions including the element hole of the green separator.

Assignees

• Ngk Spark Plug Co

Inventors

• Liu Sunchao
• Oba Takehiro

Classifications

• C04B35/00

  Shaped ceramic products characterised by their composition {(porous ceramic products C04B38/00; ceramic articles characterised by particular shape, see the relevant classes, e.g. linings for casting ladles, tundishes, cups or the like B22D41/02; ceramic substrates for microelectronic semi-conductors H10W70/692)}; Ceramics compositions ({shaping of ceramics B28B;} containing free metal bonded to carbides, diamond, oxides, borides, nitrides, silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides or sulfides other than as macroscopic reinforcing agents C22C); Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products {(infiltration of sintered ceramic preforms with molten metal C04B41/51; chemical preparation of powders of inorganic compounds C01)} · CPC title

• G01N27/409

  Oxygen concentration cells · CPC title

• G01N27/4062 Primary

  Electrical connectors associated therewith · CPC title

• G01N27/4077 Primary

  Means for protecting the electrolyte or the electrodes · CPC title

• C04B35/64

  Burning or sintering processes (C04B33/32 takes precedence {; powder metallurgy B22F}) · CPC title