Water-based compositions that resist dirt pick-up

Patent metadata

Field	Value
Publication number	US-11312879-B2
Application number	US-202017111027-A
Country	US
Kind code	B2
Filing date	Dec 3, 2020
Priority date	Mar 15, 2013
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

Water-based compositions containing a low VOC coalescent, a latex or water-dispersible polymer, and a water-insoluble UV-VIS (preferably, ultraviolet) absorber.

First claim

What is claimed is:

1. A latex-based paint comprising:
a latex polymer; and
methyl-o-benzoyl benzoate;
wherein the paint includes no greater than 5 grams of total VOC per 100 grams polymer solids; and
wherein the paint has a pigment volume concentration range of 20 to 75.

2. The paint of claim 1 wherein the latex polymer is not a multi-stage latex polymer.

3. The paint of claim 1 wherein the latex polymer comprises the polymerization product of ethylenically unsaturated monomers comprising acetoacetyl ethyl methacrylate (AAEM), diacetone acrylamide, or mixtures thereof.

4. The paint of claim 1 wherein the latex polymer comprises the polymerization product of ethylenically unsaturated monomers that do not include styrene.

5. The paint of claim 1 wherein the latex polymer comprises a surfactant and polymer particles comprising a copolymer including at least one of an acrylate or a methacrylate.

6. The paint of claim 1 comprising at least 0.1 wt-% and up to 5.0 wt-% of methyl-o-benzoyl benzoate, based on the weight of the polymer solids.

7. The paint of claim 1 further comprising one or more low VOC coalescents having a volatile organic content of 30% or less, or that elutes from a GC column at the same time or after methyl palmitate under the same conditions.

8. The paint of claim 7 wherein at least one coalescent is selected from the group of bis(2-ethylhexyl) maleate, bis(2-ethylhexyl) adipate, bis(2-ethylhexyl) azelate, isodecyl benzoate, tri(ethylene glycol)bis(2-ethylhexanoate), tetra(ethylene glycol)bis(2-ethylhexanoate), tributyl citrate, octyl benzoate, di(ethylene glycol)dibenzoate, octadecenoic acid methyl ester, and oleic acid monoester of propylene glycol.

9. The paint of claim 1 further comprising a defoamer and at least one of a mildewcide or a biocide.

10. The paint of claim 1 further comprising a pigment, a defoamer, a thickener, a surfactant, a dispersant, a filler, and combinations thereof.

11. The paint of claim 1 further comprising a surfactant.

12. The paint of claim 11 wherein the surfactant comprises sodium laureth sulfate.

13. The paint of claim 1 comprising sufficient TiO 2 pigment to be substantially visually opaque when applied at a thickness of 3 mils (0.0762 mm) and dried.

14. The paint of claim 1 which has a minimum film forming temperature.

15. The paint of claim 14 which has a minimum film-forming temperature of less than 25° C.

16. The paint of claim 1 which does not include a water-dispersible polymer selected from the group of a polyurethane, an epoxy, a polyamide, a chlorinated polyolefin, a polyester, and a mixture or copolymer thereof.

17. A method, comprising:
providing a water-based composition, comprising:
a latex polymer;
methyl-o-benzoyl benzoate; and
sodium laureth sulfate;
wherein the composition includes no greater than 5 grams of total VOC per 100 grams polymer solids; and

causing the composition to be formed into a latex-based paint.

18. The method of claim 17 wherein the paint has a pigment volume concentration range of 20 to 75.

19. The method of claim 17 wherein the latex polymer is not a multi-stage latex polymer.

20. The method of claim 17 wherein the latex polymer comprises the polymerization product of ethylenically unsaturated monomers comprising butyl acrylate and methyl methacrylate.

21. The method of claim 20 wherein the ethylenically unsaturated monomers do not include styrene.

22. The method of claim 17 wherein the water-based composition has a minimum film-forming temperature of less than 25° C.

23. A method, comprising:
providing a water-based composition, comprising:
a latex polymer; and
methyl-o-benzoyl benzoate;
wherein the composition includes no greater than 5 grams of total VOC per 100 grams polymer solids; and
wherein the water-based composition does not include benzophenone; and

causing the composition to be formed into a latex-based paint.

24. The method of claim 23 wherein the water-based composition further comprises a surfactant.

25. The method of claim 24 wherein the surfactant comprises sodium laureth sulfate.

26. The method of claim 17 comprising a sufficient amount of methyl-o-benzoyl benzoate to improve dirt pick-up resistance by at least 10%, relative to the same water-based composition without the methyl-o-benzoyl benzoate, based on a change in ΔE value.

27. The method of claim 26 wherein the water-based composition comprises at least 0.1 wt-% and up to 5.0 wt-% methyl-o-benzoyl benzoate, based on the weight of the polymer solids.

28. The method of claim 27 wherein the water-based composition comprises at least 0.3 wt-% and up to 3.0 wt-% methyl-o-benzoyl benzoate, based on the weight of the polymer solids.

29. The method of claim 17 wherein the latex polymer has a molecular weight of greater than 50,000.

30. The method of claim 17 wherein the latex polymer comprises the polymerization product of ethylenically unsaturated monomers comprising acetoacetyl ethyl methacrylate (AAEM), diacetone acrylamide, or mixtures thereof.

31. The method of claim 23 wherein the latex polymer comprises the polymerization product of ethylenically unsaturated monomers comprising acetoacetyl ethyl methacrylate (AAEM), diacetone acrylamide, or mixtures thereof.

Assignees

• Swimc Llc

Inventors

• Hibben Mary Jane
• Wildman Mike
• Killilea T Howard
• Harvey Iain

Classifications

• C09D7/63

  organic · CPC title

• C09D5/16 Primary

  Antifouling paints; Underwater paints · CPC title

• C08K5/11

  of acyclic polycarboxylic acids · CPC title

• C08K5/103

  with polyalcohols · CPC title

• C08K5/053

  Polyhydroxylic alcohols · CPC title