Powder slush molded body of vinyl chloride resin composition, and laminate

Patent metadata

Field	Value
Publication number	US-11312848-B2
Application number	US-201816756660-A
Country	US
Kind code	B2
Filing date	Oct 12, 2018
Priority date	Oct 16, 2017
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

The present invention relates to a powder slush molded body of a polyvinyl chloride composition, the polyvinyl chloride composition containing a polyvinyl chloride, a plasticizer, and an acrylic polymer. The polyvinyl chloride composition contains the plasticizer in an amount of 110 parts by mass or more and 150 parts by mass or less with respect to 100 parts by mass of the polyvinyl chloride. When a cross section of the powder slush molded body extending in parallel with a thickness direction is observed under an optical microscope using reflected light, irregular scale-like polyvinyl chloride particles having a long diameter of 30 μm or more and 500 μm or less are continuous with one another via interfacial portions, and the number of aggregated particles of the acrylic polymer having a long diameter of 30 μm or more and 100 μm or less is 10 particles/mm2 or less. Thus, provided are a powder slush molded body of a polyvinyl chloride composition having high flexibility after heat aging as well as favorable surface characteristics, and a laminate.

First claim

The invention claimed is:

1. A powder slush molded body of a polyvinyl chloride composition, the polyvinyl chloride composition comprising:
a polyvinyl chloride in an amount of 100 parts by mass,
a plasticizer in an amount of 110 to 150 parts by mass, and
an acrylic polymer in an amount of 4 to 23 parts by mass,

wherein the acrylic polymer contains a constitutional unit derived from methyl (meth)acrylate in an amount of 50 to 90 mass %, and a constitutional unit derived from at least one (meth)acrylic ester one (meth)acrylic ester selected from the group consisting of n-butyl (meth)acrylate, isobutyl (meth)acrylate, and tert-butyl (meth)acrylate in an amount of 10 to 50 mass %,
wherein when a cross section of the powder slush molded body extending in parallel with a thickness direction is observed under an optical microscope using reflected light, irregular scale-like polyvinyl chloride particles having a long diameter of 30 μm to 500 μm are continuous with one another via interfacial portions,
wherein the number of aggregated particles of the acrylic polymer having a long diameter of 30 μm to 100 μm is 10 particles/mm 2 or less, and
wherein the powder slush molded body has a dynamic friction coefficient is from 0.467 to 0.655.

2. The powder slush molded body according to claim 1 ,
wherein, when the cross section of the powder slush molded body extending in parallel with the thickness direction is analyzed using laser Raman spectroscopy, a peak at a wave number of 600±5 cm −1 originating from the acrylic polymer is present in a Raman spectrum of the interfacial portion.

3. The powder slush molded body according to claim 1 ,
wherein, when the cross section of the powder slush molded body extending in parallel with the thickness direction is analyzed using laser Raman spectroscopy, an intensity of a peak at a wave number of 666±5 cm −1 originating from the plasticizer observed in a Raman spectrum of an inner portion of the polyvinyl chloride particle is higher than an intensity of a peak at a wave number of 666±5 cm −1 originating from the plasticizer observed in a Raman spectrum of the interfacial portion.

4. The powder slush molded body according to claim 1 ,
wherein the interfacial portion has a thickness of 1 μm to 20 μm.

5. The powder slush molded body according to claim 1 ,
wherein the plasticizer includes a trimellitate-based plasticizer.

6. A facing for a vehicle interior material, comprising the powder slush molded body according to claim 1 .

7. A laminate obtained by laminating a polyurethane foam layer and the powder slush molded body according to claim 1 .

8. A vehicle interior material, comprising the laminate according to claim 7 .

Assignees

• Kaneka Corp
• Tatsuta Chemical Co Ltd

Inventors

• Takesada Kentaro
• Hosomi Kohei

Classifications

• B32B27/306

  comprising vinyl acetate or vinyl alcohol (co)polymers · CPC title

• B32B27/304

  comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF · CPC title

• B32B2307/746

  Slipping, anti-blocking, low friction · CPC title

• B32B2307/54

  Yield strength; Tensile strength · CPC title

• B32B27/22

  using plasticisers · CPC title