Method for producing polyarylene sulphide resin

Patent metadata

Field	Value
Publication number	US-11312823-B2
Application number	US-201816622964-A
Country	US
Kind code	B2
Filing date	Jun 26, 2018
Priority date	Jun 29, 2017
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

Provided is a method for producing a polyarylene sulfide resin, the method including subjecting a dihaloaromatic compound and a sulfidizing agent to a polymerization reaction in the presence of an aliphatic cyclic compound having a ring openable by hydrolysis, in which corrosion of a production apparatus is suppressed. More particularly, provided is a method for producing a polyarylene sulfide resin, the method including a dehydration step (1) in which a water-containing sulfidizing agent and an aliphatic cyclic compound having a ring openable by hydrolysis are heated in the presence of a dihaloaromatic compound to a liquid temperature in the range of 90° C. or higher and 170° C. or lower under the atmospheric pressure, and then dehydration is performed while maintaining the liquid temperature and reducing the pressure to a pressure in the range of 30 [kPa abs] or higher and 80 [kPa abs] or lower to thus obtain a mixture.

First claim

The invention claimed is:

1. A method for producing a polyarylene sulfide resin in which a dihaloaromatic compound is reacted with a sulfidizing agent in the presence of an aliphatic cyclic compound having a ring openable by hydrolysis,
the method comprising a dehydration step (1) in which in the presence of a dihaloaromatic compound, a water-containing sulfidizing agent and an aliphatic cyclic compound having a ring openable by hydrolysis are heated to a liquid temperature in the range of 90° C. or higher and 170° C. or lower under the atmospheric pressure and then dehydration is performed while maintaining the liquid temperature and reducing pressure to a pressure in the range of 30 [kPa abs] or higher and 80 [kPa abs] or lower to thus obtain a mixture.

2. The production method according to claim 1 , wherein the dihaloaromatic compound is in an amount in the range of 0.2 mol or more and 5.0 mol or less based on 1 mol of total sulfur atoms in the sulfidizing agent.

3. The production method according to claim 1 , wherein water present in a reaction system at the time after completion of the dehydration step (1) is in an amount in the range of 0.4 mol or less based on 1 mol of total sulfur atoms in the sulfidizing agent.

4. The production method according to claim 1 , wherein the aliphatic cyclic compound is in an amount in the range of 0.01 mol or more and 0.9 mol or less based on 1 mol of total sulfur atoms in the sulfidizing agent.

5. The production method according to claim 1 , wherein the sulfidizing agent is an alkali metal sulfide, or an alkali metal hydrosulfide and an alkali metal hydroxide.

6. The production method according to claim 1 , wherein after completion of the dehydration step (1), the mixture is a slurry containing a solid anhydrous sulfidizing agent.

7. The production method according to claim 1 , further comprising a polymerization step in which the mixture obtained through the dehydration step (1) is heated with an amount of water present at the time in a reaction system in the range of 0.4 mol or less based on 1 mol of the dihaloaromatic compound to perform a polymerization reaction.

8. The production method according to claim 1 , subsequently comprising a dehydration step (2) in which an aprotic polar organic solvent is further added to the mixture obtained through the dehydration step (1) and water is removed by distillation to perform dehydration,
and further subsequently comprising a polymerization step in which a mixture obtained by the dehydration step (2) is subjected to a polymerization reaction with an amount of water present at the time in a reaction system that is less than 0.03 mol based on 1 mol of the dihaloaromatic compound.

9. The production method according to claim 1 , wherein in the dehydration step (1), a contact part of a reaction apparatus with raw materials or a mixture obtained after a reaction is formed of at least one material selected from the group consisting of titanium, zirconium, and nickel alloy.

10. A method for producing a polyarylene sulfide resin composition, comprising
a step of producing a polyarylene sulfide resin by the production method according to claim 1 , and
a step of blending the obtained polyarylene sulfide resin with at least one other component selected from the group consisting of a filler, a thermoplastic resin other than the polyarylene sulfide resin, an elastomer, a crosslinkable resin having two or more functional groups, and a silane coupling agent, heating the blend to a melting point of the polyarylene sulfide resin or higher, and melt-kneading the mixture.

11. A method for producing a polyarylene sulfide resin molded article, the method comprising
a step of producing a polyarylene sulfide resin composition by the production method according to claim 10 , and
a step of subjecting the obtained polyarylene sulfide resin composition to melt-molding.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Kadoki Masaya
• Nara Saori
• Ibaraki Taku
• Watanabe Hideki
• Inoue Satoshi

Classifications

• C08G75/0204

  Polyarylenethioethers · CPC title

• C08G75/0277

  Post-polymerisation treatment (chemical after-treatment C08G75/0286) · CPC title

• C08G75/0213

  containing elements other than carbon, hydrogen or sulfur · CPC title

• C08G75/0263

  using elemental sulfur · CPC title

• C08K5/54

  Silicon-containing compounds {(C08K5/0091 takes precedence)} · CPC title