Flexible foam using polymer polyols produced via DMC catalyzed polyols

Patent metadata

Field	Value
Publication number	US-11312811-B2
Application number	US-201615138939-A
Country	US
Kind code	B2
Filing date	Apr 26, 2016
Priority date	Apr 26, 2016
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

This invention relates to improved flexible foams prepared from polymer polyols and to a process for preparing these improved flexible foams.

First claim

What is claimed is:

1. A process for producing a flexible polyurethane foam, comprising reacting
(I) at least one diisocyanate or polyisocyanate component which comprises at least one of toluene diisocyanate, diphenylmethane diisocyanate, and polymethylene polyphenylisocyanate,
with
(II) an isocyanate-reactive component comprising
(A) at least polyether polyol having a functionality of from about 3 to about 6 and a molecular weight of from about 1000 to about 12,500;
(B) at least one polymer polyol having a solids content of at least about 30% by weight to about 60% by weight, a total ethylene oxide content of at least about 2% to about 23% by weight, having a viscosity at 25° C. of less than about 14,000 mPa·s, and comprising a reaction product of
(1) at least one base polyol containing active hydrogen atoms having a functionality of 2 to 6, a hydroxyl number of 30 to 200, and a total ethylene oxide content of about 8% to about 25% by weight, said base polyol being prepared via a semi-batch process in which a low molecular weight starter and a DMC catalyst are added to a reactor, and alkylene oxide is continuously added to the reactor over 2 or more hours to the target hydroxyl number of 30 to 200
(2) at least one unsaturated monomer,
and,
(3) a preformed stabilizer,
in the presence of;
(4) at least one free radical initiator consisting essentially of t-amylperoxypivalate,
and optionally
(5) a chain transfer agent;

and
(C) one or more chain extenders and/or crosslinking agents having a functionality of from about 2 to about 3, and a molecular weight of from about 300 or less;

in the presence of
(III) one or more blowing agents,
and, optionally,
(IV) one or more additives and/or auxiliary agents;
at an Isocyanate Index of from about 90 to about 120,
wherein the low molecular weight starter used to prepare the base polyol comprises an alkylene oxide adduct of glycerin and an alkylene oxide adduct of propylene glycol and the continuously added alkylene oxide used to prepare the base polyol comprises ethylene oxide and propylene oxide.

2. The process of claim 1 , wherein said low molecular weight starter in said semi-batch process is prepared via DMC catalysis or via KOH catalysis in which the KOH has been removed and has a hydroxyl number of 650 mg KOH/g to 112 mg KOH/g and 100 wt % of the low molecular weight starter is added to the reaction vessel before starting the alkylene oxide feed.

3. The process of claim 1 , wherein (II)(B)((2) said at least one unsaturated monomer comprises a mixture of styrene and acrylonitrile.

4. The process of claim 3 , wherein styrene and acrylonitrile are present in a weight ratio of from about 80:20 to about 20:80.

5. The process of claim 1 , wherein (C) is present in an amount of from about 0.1 to about 5% by weight, based on 100% by weight of the isocyanate-reactive component (II), and is chosen from ethylene glycol, propanediol, butanediol, hexanediol, 2-methyl-1,3-propanediol, diethylene glycol, triethylene glycol, dipropylene glycol, tripropylene glycol, glycerol, trimethylolpropane, sorbitol, pentaerythritol, ethanolamine, diethanolamine, triethanolamine, alkylene oxides adducts thereof, and mixtures thereof.

6. A flexible polyurethane foam comprising the reaction product of:
(I) at least one diisocyanate or polyisocyanate component which comprises at least one of toluene diisocyanate, diphenylmethane diisocyanate, and polymethylene polyphenylisocyanate,
with
(II) an isocyanate-reactive component comprising
(A) at least polyether polyol having a functionality of from about 3 to about 5 and a molecular weight of from about 1000 to about 12,500;
(B) at least one polymer polyol having a solids content of at least about 30% by weight to about 60% by weight, a total ethylene oxide content of at least about 2% to about 23% by weight, having a viscosity at 25° C. of less than about 14,000 mPa·s, and comprising a reaction product of
(1) at least one base polyol containing active hydrogen atoms having a functionality of 2 to 6, a hydroxyl number of 30 to 200, and a total ethylene oxide content of about 8 to about 25% by weight, said base polyol being prepared via a semi-batch process in which a low molecular weight starter and a DMC catalyst are added to a reactor, and alkylene oxide is continuously added in a random distribution to the reactor over 2 or more hours to the target hydroxyl number of 30 to 200,
(2) at least one unsaturated monomer,
and,
(3) a preformed stabilizer,
in the presence of;
(4) at least one free radical initiator consisting essentially of t-amylperoxypivalate,
and optionally
(5) a chain transfer agent;

and
(C) one or more chain extenders and/or crosslinking agents having a functionality of from about 2 to about 3, and a molecular weight of from about 300 or less;

in the presence of
(III) one or more blowing agents,
and, optionally,
(IV) one or more additives and/or auxiliary agents;
at an Isocyanate Index of from about 90 to about 120,
wherein the low molecular weight starter used to prepare the base polyol comprises an alkylene oxide adduct of glycerin and an alkylene oxide adduct of propylene glycol and the continuously added alkylene oxide used to prepare the base polyol comprises ethylene oxide and propylene oxide.

7. The flexible polyurethane foam of claim 6 , wherein said low molecular weight starter in said semi-batch process is prepared via DMC catalysis or via KOH catalysis in which the KOH has been removed and has a hydroxyl number of 650 mg KOH/g to 112 mg KOH/g and 100 wt % of the low molecular weight starter is added to the reaction vessel before starting the alkylene oxide feed.

8. The flexible polyurethane foam of claim 6 , wherein (II)(B)((2) said at least one unsaturated monomer comprises a mixture of styrene and acrylonitrile.

9. The flexible polyurethane foam of claim 8 , wherein styrene and acrylonitrile are present in a weight ratio of from about 80:20 to about 20:80.

10. The flexible polyurethane foam of claim 6 , wherein (C) is present in an amount of from about 0.1 to about 5% by weight, based on 100% by weight of the isocyanate-reactive component (II), and is chosen from ethylene glycol, propanediol, butanediol, hexanediol, 2-methyl-1,3-propanediol, diethylene glycol, triethylene glycol, dipropylene glycol, tripropylene glycol, glycerol, trimethylolpropane, sorbitol, pentaerythritol, ethanolamine, diethanolamine, triethanolamine, alkylene oxides adducts thereof, and mixtures thereof.

11. The process of claim 1 , wherein (II)(B)(1) said base polyol has an OH number of 30 to 150 and a functionality of 2 to 4.

12. The process of claim 11 , wherein (II)(B)(1) said base polyol has a functionality of 2 to 3.

13. The flexible polyurethane foam of claim 6 , wherein (II)(B)(1) said base polyol has an OH number of 30 to 150 and a functionality of 2 to 4.

14. The flexible polyurethane foam of claim 13 , wherein (II)(B)(1) said base polyol has a functionality of 2 to 3.

15. The process of claim 1 , wherein the alkylene oxide adduct of glycerin is a propylene oxide adduct of glycerin and the alkylene oxide adduct of propylene glycol is a propylene oxide adduct of propylene glycol.

16. The flexible polyurethane foam of claim 6 , wherein the alkylene oxide adduct of glycerin is a propylene oxide adduct of glycerin and the alkylene oxide adduct of propylene glycol is a propylene oxide adduct of propylene glycol.

Assignees

• Covestro Llc

Inventors

• Adkins Rick L
• Neal Brian L
• Uthe Peter
• Reese Jack R

Classifications

• C08G18/7621

  being toluene diisocyanate including isomer mixtures · CPC title

• C08F283/06

  on to polyethers, polyoxymethylenes or polyacetals {(C08F283/004 takes precedence)} · CPC title

• C08G18/3275

  containing two hydroxy groups · CPC title

• C08G18/4866

  having a low unsaturation value · CPC title

• C08G18/8108

  having only one isocyanate or isothiocyanate group · CPC title