Polyolefin catalyst and method for preparing polyolefin using same

Patent metadata

Field	Value
Publication number	US-11312796-B2
Application number	US-202016843986-A
Country	US
Kind code	B2
Filing date	Apr 9, 2020
Priority date	Oct 12, 2017
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

Disclosed are a novel metallocene catalyst and a method for preparing a polyolefin having a high molecular weight and a low melt index by using the same. The present invention provides a transition metal compound represented by formula 1.

First claim

The invention claimed is:

1. A transition metal compound represented by Formula 1 below:

wherein, in Formula 1,
M is a Group 4 transition metal;
R1, R2, R3 and R4 are each independently hydrogen; (C 1 -C 20 )alkyl including or not including acetal, ketal or an ether group; (C 2 -C 20 )alkenyl including or not including acetal, ketal or an ether group; (C 6 -C 20 )aryl including or not including acetal, ketal or an ether group; (C 1 -C 20 )alkyl(C 6 -C 20 )aryl including or not including acetal, ketal or an ether group; (C 6 -C 20 )aryl(C 1 -C 20 )alkyl including or not including acetal, ketal or an ether group; or (C 1 -C 20 ) silyl including or not including acetal, ketal or an ether group; and two or more among R1, R2, R3, and R4 are able to be connected with each other to form an aliphatic ring or an aromatic ring;
R5, R6, R7 and R8 are each independently hydrogen; (C 1 -C 20 )alkyl including or not including acetal, ketal or an ether group; (C 2 -C 20 )alkenyl including or not including acetal, ketal or an ether group; (C 1 -C 20 )alkyl(C 6 -C 20 )aryl including or not including acetal, ketal or an ether group;
R9, R10, R11, R12, R13, R14, R15 and R16 are each independently hydrogen; (C 1 -C 20 )alkyl including or not including acetal, ketal or an ether group; (C 2 -C 20 )alkenyl including or not including acetal, ketal or an ether group; (C 1 -C 20 )alkyl(C 6 -C 20 )aryl including or not including acetal, ketal or an ether group; (C 6 -C 20 )aryl(C 1 -C 20 )alkyl including or not including acetal, ketal or an ether group; or (C 1 -C 20 )silyl including or not including acetal, ketal or an ether group; and two or more among R9, R10, R11, R12, R13, R14, R15 and R16 are able to be connected with each other to form an aliphatic ring or an aromatic ring;
R17 and R18 are each independently hydrogen, (C 1 -C 20 )alkyl, (C 2 -C 20 )alkenyl, (C 2 -C 20 )alkynyl, (C 6 -C 20 )aryl, (C 1 -C 20 )alkyl(C 6 -C 20 )aryl, (C 6 -C 20 )aryl(C 1 -C 20 )alkyl, (C 1 -C 20 )alkylamido, (C 6 -C 20 )arylamido, or (C 1 -C 20 )alkylidene; and
n is an integer of 1 or 2.

2. The transition metal compound of claim 1 , wherein at least one among R1, R2, R3 and R4 above is hydrogen, and the others are each independently able to be substituted with (C 1 -C 20 )alkyl, (C 2 -C 20 )alkenyl, (C 6 -C 20 )aryl or (C 1 -C 20 )silyl including or not including acetal, ketal, or an ether group; and two or more among R1, R2, R3 and R4 above are able to be connected with each other to form an aliphatic ring or an aromatic ring.

3. The transition metal compound of claim 1 , wherein at least one among R1, R2, R3 and R4 above is hydrogen, and the others are each independently substituted with (C 1 -C 20 )alkyl.

4. The transition metal compound of claim 1 , wherein at least two among R1, R2, R3 and R4 above are hydrogen, and the others are each independently able to be substituted with (C 1 -C 20 )alkyl, (C 2 -C 20 )alkenyl, (C 6 -C 20 )aryl or (C 1 -C 20 )silyl including or not including acetal, ketal, or an ether group; and two or more among R1, R2, R3 and R4 above are able to be connected with each other to form an aliphatic ring or an aromatic ring.

5. The transition metal compound of claim 1 , wherein at least two among R1, R2, R3 and R4 above are hydrogen, and the others are each independently substituted with (C 1 -C 20 )alkyl.

6. A transition metal catalyst composition comprising:
the transition metal compound according to claim 1 ; and
at least one cocatalyst compound selected from the group consisting of an aluminum compound represented by Formula 2 below, a compound represented by Formula 3 below, and a boron compound represented by Formula 4 below:
—[Al(R19)-O] n -  [Formula 2]

wherein, in Formula 2, R19 is a halogen radical, or a halogen-substituted or unsubstituted C 1 -C 20 hydrocarbyl radical; and n is an integer of 2 or more,
A(R20) 3   [Formula 3]

in Formula 3, A is aluminum or boron; and R20's are the same as or different from each other, and each independently a halogen radical, or a halogen-substituted or unsubstituted C 1 -C 20 hydrocarbyl radical,
[L-H] + [Z(B) 4 ] − or [L] + [Z(B) 4 ] −   [Formula 4]

in Formula 4, L is a neutral or cationic Lewis acid; H is a hydrogen atom; and
Z is a Group 13 element; and Bs are each independently a C 6 -C 20 aryl or alkyl radical having at least one hydrogen atom substituted with a halogen radical, a C 1 -C 20 hydrocarbyl radical, a C 1 -C 20 alkoxy radical, or a C 1 -C 20 phenoxy radical.

7. The transition metal catalyst composition of claim 6 , wherein the aluminum compound cocatalyst is one selected from alkylaluminoxane, and is a single one selected from among methylaluminoxane, modified methylaluminoxane, tetraisobutylaluminoxane, and the compound represented by Formula 3 is one selected from trimethylaluminum, triethylaluminum, triisobutylaluminum and trioctylaluminum, or a mixture of two or more thereof, and the boron compound cocatalyst is a single one selected from among tris(pentafluorophenyl)borane, N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate and triphenylmethylinium tetrakis(pentafluorophenyl)borate, or a mixture thereof.

8. A method for preparing a polyolefin, the method comprising a step for polymerizing olefin-based monomers in the presence of the transition metal catalyst composition of claim 6 .

9. The method for preparing a polyolefin of claim 8 , wherein the olefin-based monomers comprise at least one selected from the group consisting of ethylene, propylene, 1-butene, 1-pentene, 1-hexene, 1-octene, 1-nonene, 1-decene, 1-undecene, 1-dodecene, 1-tridecene, 1-tetradecene, 1-pentadecene, 1-hexadecene, 1-heptadecene, 1-octadecene, 1-nonadecene, and 1-eicosene.

10. The method for preparing a polyolefin of claim 8 , wherein particles of 125 μm or less are produced by 0.5 wt % or less.

Assignees

• Lotte Chemical Corp

Inventors

• Min Joon Keun
• Jeong Su Jeong
• Woo Hyun Yul
• Lee Rai Ha
• Shin Eun Hye
• Chae Byung Hun

Classifications

• C08F110/06

  Propene · CPC title

• C08F10/06

  Propene · CPC title

• C08F10/02

  Ethene · CPC title

• C08F4/642

  Component covered by group C08F4/64 with an organo-aluminium compound {(C08F4/64003 - C08F4/64196 take precedence)} · CPC title

• C07F17/00 Primary

  Metallocenes · CPC title