Dense boron nitride ceramic with high plasticity and high elasticity and preparation for the same

Patent metadata

Field	Value
Publication number	US-11312660-B2
Application number	US-202016829362-A
Country	US
Kind code	B2
Filing date	Mar 25, 2020
Priority date	Aug 26, 2019
Publication date	Apr 26, 2022
Grant date	Apr 26, 2022

Abstract

The present disclosure relates to a dense boron nitride ceramic with high plasticity and high elasticity and the preparation process thereof. The preparation process includes the following steps: A) weighing a predetermined amount of spherical boron nitride nano-powders with onion-like structure, pre-pressing them into a pre-pressed body and putting the pre-pressed body into a sintering mold; B) putting the pre-pressed body obtained in step A) together with the sintering mold into a spark plasma sintering apparatus or a hot-pressing sintering apparatus for sintering; and C) taking out the mold after cooling, and removing the mold to obtain the boron nitride dense ceramic block with high plasticity and high elasticity. According to the present invention, a boron nitride ceramic with high strength and high plasticity is obtained via sintering spherical boron nitride nano-powders with onion-like structure.

First claim

The invention claimed is:

1. A boron nitride ceramic, wherein the ceramic has a room-temperature compressive strength of not less than about 400 MPa, a total room-temperature compressive strain of not less than about 9%, a room-temperature plastic strain of not less than about 4%, a room-temperature elastic strain of not less than about 4%, and a relative density, calculated as the ratio of the measured density relative to its theoretical density, of not less than about 85%.

2. The boron nitride ceramic as claimed in claim 1 , wherein its room-temperature elastic strain is not less than about 5%.

3. A process for the preparation of a boron nitride ceramic according to claim 1 , comprising the following steps:
A) Weighing a predetermined amount of spherical boron nitride nano-powders with onion-like structure, pre-pressing them into a pre-pressed body and putting the pre-pressed body into a sintering mold;
B) Putting the pre-pressed body obtained in step A) together with the sintering mold into a spark plasma sintering apparatus or a hot-pressing sintering apparatus for sintering; and
C) Taking out the mold after cooling, and removing the mold to obtain the boron nitride ceramic block.

4. The process for the preparation of a boron nitride ceramic as claimed in claim 3 , wherein the cooling operation in step C) is effected by allowing the temperature in the apparatus of B) to be naturally decreased to room temperature.

5. The process for the preparation of a boron nitride ceramic as claimed in claim 3 , wherein the sintering mold in step A) is a graphite mold wrapped with a carbon felt.

6. The process for the preparation of a boron nitride ceramic as claimed in claim 4 , wherein the sintering mold in step A) is a graphite mold wrapped with a carbon felt.

7. The process for the preparation of a boron nitride ceramic as claimed in claim 3 , wherein the pre-pressing in step A) is carried out by applying pressure in two directions at a pressure of 2 MPa to 5 MPa with a pressure holding time of 1 min to 5 min.

8. The process for the preparation of a boron nitride ceramic as claimed in claim 4 , wherein the pre-pressing in step A) is carried out by applying pressure in two directions at a pressure of 2 MPa to 5 MPa with a pressure holding time of 1 min to 5 min.

9. The process for the preparation of a boron nitride ceramic as claimed in claim 3 , wherein the spherical boron nitride nano-powders with onion-like structure used in step A) have a particle size of 10 nm to 1000 nm.

10. The process for the preparation of a boron nitride ceramic as claimed in claim 4 , wherein the spherical boron nitride nano-powders with onion-like structure used in step A) have a particle size of 10 nm to 1000 nm.

11. The process for the preparation of a boron nitride ceramic as claimed in claim 3 , wherein the sintering step in step B) comprises evacuating to a vacuum degree not less than 1×10 −1 Pa, pressurizing to a sintering pressure, heating to a sintering temperature after the sintering pressure reaches a steady state, carrying out high-temperature sintering, and then stopping heating and releasing pressure.

12. The process for the preparation of a boron nitride ceramic as claimed in claim 4 , wherein the sintering step in step B) comprises evacuating to a vacuum degree not less than 1×10 −1 Pa, pressurizing to a sintering pressure, heating to a sintering temperature after the sintering pressure reaches a steady state, carrying out high-temperature sintering, and then stopping heating and releasing pressure.

13. The process for the preparation of a boron nitride ceramic as claimed in claim 11 , wherein the temperature in step B) is increased at a rate of 20° C./min to 100° C./min.

14. The process for the preparation of a boron nitride ceramic as claimed in claim 12 , wherein the temperature in step B) is increased at a rate of 20° C./min to 100° C./min.

15. The process for the preparation of a boron nitride ceramic as claimed in claim 3 , wherein the sintering step in step B) is carried out at a sintering pressure of 30 MPa to 50 MPa and a sintering temperature of 1600° C. to 2000° C. with a holding time of 1 min to 30 min.

16. The process for the preparation of a boron nitride ceramic as claimed in claim 4 , wherein the sintering step in step B) is carried out at a sintering pressure of 30 MPa to 50 MPa and a sintering temperature of 1600° C. to 2000° C. with a holding time of 1 min to 30 min.

17. The process for the preparation of a boron nitride ceramic as claimed in claim 3 , wherein the ceramic has a room-temperature compressive strength of not less than about 400 MPa, a total room-temperature compressive strain of not less than about 9%, a room-temperature plastic strain of not less than about 4% and a room-temperature elastic strain of not less than about 4%.

18. The process for the preparation of a boron nitride ceramic as claimed in claim 4 , wherein the ceramic has a room-temperature compressive strength of not less than about 400 MPa, a total room-temperature compressive strain of not less than about 9%, a room-temperature plastic strain of not less than about 4% and a room-temperature elastic strain of not less than about 4%.

Assignees

• Univ Yanshan

Inventors

• Zhao Zhisheng
• Zhang Yang
• Wu Yingju
• Zhang Shuangshuang
• Hu Wentao
• Yu Dongli
• He Julong
• Xu Bo
• Liu Zhongyuan
• Tian Yongjun

Classifications

• C04B2235/96

  Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance · CPC title

• C04B2235/528

  Spheres · CPC title

• C04B2235/6581

  Total pressure below 1 atmosphere, e.g. vacuum · CPC title

• C04B2235/5454

  nanometer sized, i.e. below 100 nm · CPC title

• C04B2235/6565

  Cooling rate · CPC title