Methods and apparatuses for production of carbon, carbide electrodes, and carbon compositions

Patent metadata

Field	Value
Publication number	US-11306401-B2
Application number	US-201815866660-A
Country	US
Kind code	B2
Filing date	Jan 10, 2018
Priority date	Oct 21, 2014
Publication date	Apr 19, 2022
Grant date	Apr 19, 2022

Abstract

An apparatus containing at least one electrochemical cell with an electrode structure. The electrode structure contains at least one carbide chemical compound. The carbide chemical compound may be a salt-like carbide. The electrode may contain at least one electronically conductive element different from the carbide. Carbon compositions of various forms may be formed by the methods and apparatus using the electrode structure. Large pieces of pure carbon may be produced. Post-reaction processing of the carbon may be carried out such as exfoliation.

First claim

What is claimed is:

1. An apparatus comprising at least one electrochemical cell comprising:
at least one anode comprising at least one carbide chemical compound, and
at least one cathode,
wherein the electrochemical cell apparatus is a galvanic cell apparatus and is capable of producing an elemental carbon material, and
wherein the carbide chemical compound is a salt-like carbide, an aluminum carbide, or a beryllium carbide.

2. The apparatus of claim 1 , wherein the carbide chemical compound has an electronic conductivity of at least 10 −8 S/cm.

3. The apparatus of claim 1 , wherein the carbide chemical compound is in the form of individual pieces or particles.

4. The apparatus of claim 1 , wherein the carbide chemical compound is in the form of individual pieces or particles having a size of less than one cm.

5. The apparatus of claim 1 , wherein the carbide chemical compound contacts at least one electrically conductive material.

6. The apparatus of claim 1 , wherein the carbide chemical compound is held in an electrically conductive container.

7. The apparatus of claim 1 , wherein the electrochemical cell apparatus cathode is a metal cathode.

8. The apparatus of claim 1 , wherein the electrochemical cell apparatus comprises at least one salt bridge or at least one ion exchange membrane.

9. The apparatus of claim 1 , wherein the electrochemical cell apparatus comprises an external voltage source to regulate an oxidation reaction of carbide in the carbide chemical compound.

10. The apparatus of claim 1 , wherein the apparatus further comprises at least one solution comprising at least one solvent and at least one dissolved salt, and the solution is free of dissolved carbide chemical compound.

11. The apparatus of claim 1 , wherein the anode comprises at least one electronically conductive structural element different from the carbide chemical compound and contacting the at least one carbide chemical compound.

12. The apparatus of claim 11 , wherein the carbide chemical compound is methanide, acetylide, or sesquicarbide.

13. The apparatus of claim 11 , wherein the carbide chemical compound is calcium carbide, aluminum carbide, sodium carbide, magnesium carbide, lithium carbide, or beryllium carbide.

14. The apparatus of claim 11 , wherein the carbide chemical compound is in the form of individual pieces or particles having a size of less than one cm.

15. The apparatus of claim 11 , wherein the carbide chemical compound is in the form of individual pieces or particles having a size of at least one micron.

16. The apparatus of claim 11 , wherein the carbide chemical compound is divided into separate portions which are each contacted with at least one electrically conductive structural element.

17. The apparatus of claim 11 , wherein the carbide chemical compound is at least about 95% pure.

18. The apparatus of claim 11 , wherein the electronically conductive structural element is a binder for the carbide chemical compound.

19. The apparatus of claim 11 , wherein the electronically conductive structural element is a container and the carbide chemical compound is held in the container.

20. The apparatus of claim 11 , wherein the electronically conductive structural element is a container and the carbide chemical compound is held in the container, and the container has openings which allow fluid to enter the container and contact the carbide chemical compound.

21. The apparatus of claim 11 , wherein the electronically conductive structural element is a metallic container and the carbide chemical compound is held in the metallic container.

22. The apparatus of claim 11 , wherein the electronically conductive structural element comprises at least one conductive rod.

23. The apparatus of claim 11 , wherein the electronically conductive structural element of the electrode structure comprises at least one current collector.

24. The apparatus of claim 11 , wherein the electrode structure is adapted for use as an anode in an electrochemical cell apparatus for production of the elemental carbon material.

25. The apparatus of claim 11 , wherein the electrode structure is adapted for use as an anode in a galvanic cell apparatus for production of the elemental carbon material.

26. The apparatus of claim 11 , wherein the carbide chemical compound has an electronic conductivity of at least 10 −8 S/cm.

27. The apparatus of claim 11 , wherein the carbide chemical compound is in the form of individual pieces or particles.

28. The apparatus of claim 1 , wherein each of the at least one anode and the at least one cathode is contacted with a solution comprising at least one organic solvent and at least one dissolved salt.

29. An apparatus comprising at least one electrochemical cell comprising:
at least one anode comprising at least one carbide chemical compound, and
at least one cathode,
wherein the electrochemical cell apparatus is a galvanic cell apparatus and is capable of producing an elemental carbon material, and
wherein the carbide chemical compound is in the form of individual pieces or particles having a size of less than one cm.

30. The apparatus of claim 29 , wherein the carbide chemical compound is a salt-like carbide or an intermediate transition metal carbide.

31. The apparatus of claim 29 , wherein the carbide chemical compound is a salt-like carbide.

32. The apparatus of claim 29 , wherein the carbide chemical compound is calcium carbide or aluminum carbide.

33. The apparatus of claim 29 , wherein the carbide chemical compound contacts at least one electrically conductive material.

34. The apparatus of claim 29 , wherein the electrochemical cell apparatus cathode is a metal cathode.

35. The apparatus of claim 29 , wherein the electrochemical cell apparatus comprises at least one salt bridge or at least one ion exchange membrane.

36. The apparatus of claim 29 , wherein the electrochemical cell apparatus comprises an external voltage source to regulate an oxidation reaction of carbide in the carbide chemical compound.

37. The apparatus of claim 29 , wherein the apparatus further comprises at least one solution comprising at least one solvent and at least one dissolved salt, and the solution is free of dissolved carbide chemical compound.

38. The apparatus of claim 29 , wherein the anode comprises at least one electronically conductive structural element different from the carbide chemical compound and contacting the at least one carbide chemical compound.

39. The apparatus of claim 29 , wherein each of the at least one anode and the at least one cathode is contacted with a solution comprising at least one organic solvent and at least one dissolved salt.

Assignees

• Univ West Virginia

Inventors

• Stiller Alfred H
• Yurchick Christopher L

Classifications

• H04W72/20

  Control channels or signalling for resource management · CPC title

• H04W88/10

  adapted for operation in multiple networks, e.g. multi-mode access points · CPC title

• H04W48/16

  Discovering, processing access restriction or access information · CPC title

• H04W88/06

  adapted for operation in multiple networks {or having at least two operational modes}, e.g. multi-mode terminals · CPC title

• H04W74/002

  Transmission of channel access control information · CPC title