Circular economy for plastic waste to polyethylene via refinery FCC or FCC/alkylation units

Patent metadata

Field	Value
Publication number	US-11306253-B2
Application number	US-202017131910-A
Country	US
Kind code	B2
Filing date	Dec 23, 2020
Priority date	Mar 30, 2020
Publication date	Apr 19, 2022
Grant date	Apr 19, 2022

Abstract

Provided in one embodiment is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil and optionally wax comprising a naphtha/diesel and heavy fraction, and char. The pyrolysis oil is passed to a refinery FCC unit from which a liquid petroleum gas C 3 olefin/paraffin mixture fraction is recovered, as well as a C 4 olefin/paraffin mixture fraction. The liquid petroleum gas C 3 olefin/paraffin mixture fraction is passed to a steam cracker for ethylene production. The C 4 olefin/paraffin mixture fraction is passed to a refinery alkylation unit, from which a n-butane and naphtha feed for a stream cracker to produce ethylene is recovered.

First claim

What is claimed is:

1. A continuous process for converting waste plastic into recycle for polyethylene polymerization comprising:
(a) selecting waste plastics containing polyethylene and/or polypropylene;
(b) passing the waste plastics from (a) through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent;
(c) separating the pyrolyzed effluent into offgas, char and a pyrolysis oil and optionally pyrolysis wax comprising a naphtha/diesel fraction and a heavy fraction;
(d) passing the pyrolysis oil and wax from (c) to a refinery FCC unit with the volume flow of pyrolysis oil and wax to the refinery FCC unit comprising up to but no more than 50 volume % of the total hydrocarbon flow to the FCC unit, with the remaining hydrocarbon flow to the refinery FCC unit comprising vacuum gas oil (VGO);
(e) recovering a liquid petroleum C 3 olefin/paraffin mixture fraction from the FCC unit;
(f) passing the liquid petroleum gas C 3 olefin/paraffin mixture fraction to a steam cracker for ethylene production; and
(g) recovering a gasoline and heavy fraction from the refinery FCC unit, with the gasoline passed to a gasoline blending pool.

2. The process of claim 1 , wherein a liquid petroleum C 4 olefin/paraffin mixture fraction comprising butanes and butenes is recovered from the FCC unit and passed to a refinery alkylation unit.

3. The process of claim 2 , wherein an alkylate gasoline and n-butane fraction is recovered from the alkylation unit and passed to a stream cracker to generate ethylene.

4. The process of claim 2 , wherein an alkylate gasoline fraction is recovered from the refinery alkylation unit.

5. The process of claim 1 , wherein ethylene produced in (f) is subsequently polymerized.

6. The process of claim 5 , wherein polyethylene products are prepared from the polymerized ethylene.

7. The process of claim 4 , wherein gasoline recovered from the refinery FCC unit is combined with at least a portion of the alkylate gasoline fraction recovered from the alkylation unit.

8. The process of claim 2 , wherein the amount of gasoline produced by the FCC and alkylation units is increased with recycled pyrolysis oil.

9. The process of claim 1 , wherein at least some contaminants are removed from the recovered pyrolysis oil of step (c) before the oil is passed to the FCC unit in (d).

10. The process of claim 1 , wherein the waste plastics selected in (a) are from plastics classification group 2, 4, and/or 5.

11. The process of claim 1 , wherein the waste plastics passed from (a) contain less than 50 ppm halides.

12. The process of claim 1 , wherein the waste plastics contain less than 5 wt. % polyethylene terephthalate and polyvinyl chloride.

13. A continuous process for converting waste plastic into recycle for polyethylene polymerization comprising:
(a) selecting waste plastics containing polyethylene and/or polypropylene;
(b) passing the waste plastics from (a) through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent;
(c) separating the pyrolyzed effluent into offgas, char and a pyrolysis oil comprising a naphtha/diesel fraction and a heavy fraction;
(d) passing the pyrolysis oil from to a refinery FCC unit with the volume flow of pyrolysis oil and wax to the refinery FCC unit comprising up to but no more than 50 volume % of the total hydrocarbon flow to the FCC unit, with the remaining hydrocarbon flow to the refinery FCC unit comprising vacuum gas oil (VGO);
(e) recovering a gasoline and heavy fraction from the refinery FCC unit;
(f) recovering a liquid petroleum gas C 4 olefin/paraffin mixture fraction comprising butanes and butenes from the FCC unit;
(g) passing the liquid petroleum gas C 4 olefin/paraffin mixture fraction to an alkylation unit;
(h) recovering n-butane and a portion of naphtha fraction from the alkylation unit; and
(i) passing the n-butane and a portion of naphtha fraction to a steam cracker for ethylene production.

14. The process of claim 13 , wherein an alkylate gasoline fraction is recovered from the refinery alkylation unit.

15. The process of claim 13 , wherein the gasoline recovered from the refinery FCC unit is combined with an alkylate gasoline fraction recovered from the alkylation unit.

16. The process of claim 13 , wherein at least some contaminants are removed from the recovered pyrolysis oil of step (c) before the oil is passed to the FCC unit in (d).

17. The process of claim 13 , wherein the waste plastics selected in (a) are from plastics classification group 2, 4, and/or 5.

18. The process of claim 15 , wherein the amount of gasoline produced by the FCC and alkylation units is increased with recycled pyrolysis oil.

19. The process of claim 13 , wherein ethylene produced in (i) is subsequently polymerized.

20. The process of claim 19 , wherein polyethylene products are prepared from the polymerized ethylene.

21. The process of claim 13 , further comprising collecting a C 3 olefin/paraffin mixture fraction from the FCC unit and passing the fraction to a steam cracker for ethylene production.

22. A continuous process for converting waste plastic into recycle for polyethylene polymerization comprising:
(a) selecting waste plastics containing polyethylene and/or polypropylene;
(b) passing the waste plastics from (a) through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent;
(c) separating the pyrolyzed effluent into offgas, char and a pyrolysis oil comprising a naphtha/diesel fraction and a heavy fraction;
(d) passing the pyrolysis oil from (c) to a refinery FCC unit with the volume flow of pyrolysis oil and wax to the refinery FCC unit comprising up to but no more than 50 volume % of the total hydrocarbon flow to the FCC unit, with the remaining hydrocarbon flow to the refinery FCC unit comprising vacuum gas oil (VGO);
(e) recovering a liquid petroleum gas C 3 olefin/paraffin mixture fraction from the FCC unit;
(f) separating the C 3 paraffin and C 3 olefin into different fractions;
(g) passing the C 3 paraffin fraction to a steam cracker for ethylene production; and
(h) recovering a gasoline and heavy fraction from the refinery FCC unit, with the gasoline passed to a gasoline blending pool.

Assignees

• Chevron Usa Inc

Inventors

• Timken Hye-Kyung
• Mccord Cameron

Classifications

• C08F10/02

  Ethene · CPC title

• C10G1/10

  from rubber or rubber waste · CPC title

• C10B53/07 Primary

  {of solid raw materials consisting} of synthetic polymeric materials, e.g. tyres (recovery or working-up of waste materials of organic macromolecular compounds or compositions based thereon by dry-heat treatment for obtaining partially depolymerised materials C08J11/10; production of liquid hydrocarbon mixtures from rubber or rubber waste C10G1/10) · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C10G51/023

  only thermal cracking steps · CPC title