Rubber-containing graft polymer, resin composition containing rubber-containing graft polymer, and shaped article thereof

Patent metadata

Field	Value
Publication number	US-11306203-B2
Application number	US-202016818306-A
Country	US
Kind code	B2
Filing date	Mar 13, 2020
Priority date	Oct 4, 2017
Publication date	Apr 19, 2022
Grant date	Apr 19, 2022

Abstract

Provided is a rubber-containing graft polymer that can be uniformly dispersed in a thermoplastic resin containing an alloy in a particle size of 100 to 300 nm and can improve strength developability required as a rubber-containing graft polymer. In a rubber-containing graft polymer (A) of the present invention, a rubber to be grafted has a particle size of 100 to 300 nm, a content of an organic solvent insoluble component in the rubber-containing graft polymer (100% by mass) is 92% to 99.5% by mass, and an organic solvent soluble component of the rubber-containing graft polymer has a weight average molecular weight of 250,000 to 700,000.

First claim

The invention claimed is:

1. A rubber-containing graft polymer,
wherein a rubber to be grafted has a particle size of 100 to 300 nm,
a content of an organic solvent insoluble component in the rubber-containing graft polymer (100% by mass) is 92% to 99.5% by mass, and
an organic solvent soluble component of the rubber-containing graft polymer has a weight average molecular weight of 250,000 to 700,000.

2. The rubber-containing graft polymer according to claim 1 ,
wherein a content of a methyl methacrylate-derived product in the organic solvent soluble component (100% by mass) of the rubber-containing graft polymer is 84% by mass or more.

3. A rubber-containing graft polymer having,
a content of a methyl methacrylate-derived product of 43% or higher grafted to the rubber-containing graft polymer, and
a content of an organic solvent soluble component with a styrene-equivalent molecular weight of 300,000 or more determined by integral molecular weight distribution of 10% or higher obtainable by freeze-grinding an organic solvent insoluble component of the rubber-containing graft polymer.

4. A rubber-containing graft polymer, which is obtainable by polymerizing, using a persulfate, a vinyl monomer for grafting containing 95% by mass or more of methyl methacrylate to rubber latex with a volume average particle size of 100 to 300 nm, which is obtainable by polymerizing, using a persulfate, 0.5 to 3.0 parts by mass of an aromatic vinyl monomer containing 100 parts by mass of acrylate (a1) and 0.1 to 0.7 parts by mass of allyl methacrylate (a2), or before polymerizing the vinyl monomer for grafting containing 95% by mass or more of the methyl methacrylate.

5. A resin composition containing a rubber-containing graft polymer, comprising:
the rubber-containing graft polymer according to claim 1 ; and
a thermoplastic resin (B).

6. The resin composition containing a rubber-containing graft polymer according to claim 5 ,
wherein the thermoplastic resin (B) comprises an aromatic polycarbonate (b1).

7. The resin composition containing a rubber-containing graft polymer according to claim 5 ,
wherein the thermoplastic resin (B) comprises a styrene-based resin (b2).

8. The resin composition containing a rubber-containing graft polymer according to claim 5 ,
wherein the thermoplastic resin (B) comprises polyester (b3).

9. A shaped article obtained by shaping the resin composition containing a rubber-containing graft polymer according to claim 5 .

10. The shaped article according to claim 9 , which is an injection molded article.

11. The rubber-containing graft polymer according to claim 1 , wherein the organic solvent insoluble components are components of (Rg+R0) derived from the rubber cross-linking component, wherein:
Rg is a rubber cross-linking component and graft chain derived from vinyl monomer chemically bonding thereto; and
R0 is a non-grafted rubber cross-linking component.

12. The rubber-containing graft polymer according to claim 1 , wherein the rubber-containing graft polymer comprises:
a rubber cross-linking component and graft chain derived from vinyl monomer chemically bonding thereto;
a non-grafted rubber cross-linking component;
a non-gross-linking rubber component and graft chain derived from vinyl monomer chemically bonding thereto; and
a non-grafted rubber non-cross-linking component.

13. The rubber-containing graft polymer according to claim 1 , wherein the rubber-containing graft polymer has a graft chain with length of 250,000 to 700,000 in terms of a weight average molecular weight.

14. The rubber-containing graft polymer according to claim 1 , wherein a content of a methyl methacrylate-derived product in the graft chain is 84% by mass or more.

Assignees

• Mitsubishi Chem Corp

Inventors

• Matsuoka Shinji
• SUENAGA Naotaka
• Fujita Saki
• Iimori Masashi
• MAENAKA Yuuta
• HAGI Misaki
• ARAI Hiroya

Classifications

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08L25/06

  Polystyrene · CPC title

• C08F279/02

  on to polymers of conjugated dienes · CPC title

• C08F265/06 Primary

  Polymerisation of acrylate or methacrylate esters on to polymers thereof · CPC title

• C08F285/00

  Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers · CPC title