Method for preparing organometallic composite material

Patent metadata

Field	Value
Publication number	US-11306200-B2
Application number	US-202016858739-A
Country	US
Kind code	B2
Filing date	Apr 27, 2020
Priority date	Jun 27, 2019
Publication date	Apr 19, 2022
Grant date	Apr 19, 2022

Abstract

The present invention provides a method for preparing organometallic composite material, comprising: providing PVC resin, activated calcium carbonate, plant fiber, calcium stearate, barium sulfate, paraffin, sodium bicarbonate, zinc laurate, nanometre titanium dioxide, organometallic salt, shell powder, carbon nanotube, talcum powder and stabilizer; mixing and heating; subject to first cooling after extrusion and second cooling under vacuum; towing to obtain the organometallic composite material, wherein the organometallic salt is a benzoic acid metal salt mixture. The present method can significantly reduce the processing temperature of PVC composite by 20 to 50° C., and also increase the toughness and strength of the material so as to alleviate the exudation of the composite material as in the conventional technologies and extend the lifespan of the composite material.

First claim

The invention claimed is:

1. A method for preparing a composite material, comprising:
providing a PVC resin, an activated calcium carbonate, a plant fiber, calcium stearate, barium sulfate, paraffin wax, sodium bicarbonate, zinc laurate, nanometer-sized titanium dioxide, an organometallic salt, shell powder, carbon nanotubes, talcum powder, and a stabilizer to create a first mixture;
mixing and heating the first mixture to obtain a second mixture;
extruding the second mixture to obtain a molded article;
subjecting the molded article to a first cooling to obtain a cooled molded article;
subjecting the cooled molded article to a second cooling under vacuum to obtain the composite material.

2. The method of claim 1 , wherein the organometallic salt is a benzoic acid metal salt represented by the following formula:

wherein n=1, 2 or 3; M is selected from copper, iron, zinc, magnesium, calcium, or combinations thereof.

3. The method of claim 1 , wherein the PVC resin is from 50 to 70 parts by mass; the activated calcium carbonate is from 16 to 30 parts by mass; the plant fiber is from 2 to 6 parts by mass; the calcium stearate is from 4 to 14 parts by mass; the barium sulfate is from 2 to 8 parts by mass; the paraffin wax is from 12 to 18 parts by mass; the sodium bicarbonate is from 1 to 3 parts by mass; the zinc laurate is from 2 to 6 parts by mass; the nanometer-sized titanium dioxide is from 4 to 8 parts by mass; the organometallic salt is from 10 to 50 parts by mass; the shell powder is from 4 to 8 parts by mass; the carbon nanotubes are from 2 to 4 parts by mass; the talcum powder is from 3 to 5 parts by mass; and the stabilizer is from 2 to 4 parts by mass.

4. The method of claim 2 , wherein the PVC resin is from 50 to 70 parts by mass; the activated calcium carbonate is from 16 to 30 parts by mass; the plant fiber is from 2 to 6 parts by mass, the calcium stearate is from 4 to 14 parts by mass; the barium sulfate is from 2 to 8 parts by mass; the paraffin wax is from 12 to 18 parts by mass; the sodium bicarbonate is from 1 to 3 parts by mass; the zinc laurate is from 2 to 6 parts by mass; the nanometer-sized titanium dioxide is from 4 to 8 parts by mass; the organometallic salt is from 10 to 50 parts by mass; the shell powder is from 4 to 8 parts by mass; the carbon nanotubes are from 2 to 4 parts by mass; the talcum powder is from 3 to 5 parts by mass; and the stabilizer is from 2 to 4 parts by mass.

5. The method of claim 1 , wherein the mixing and heating comprises mixing at a first speed from 400 to 500 r/min for 1 to 2 hours at a first temperature from 100 to 120° C., followed by mixing at a second speed from 80 to 120 r/min for 30 to 50 minutes at a second temperature from 30 to 40° C., and wherein said extruding is performed at different temperatures according to different zones: 110 to 120° C. in zone 1; 125 to 135° C. in zone 2; 140 to 150° C. in zone 3; 165 to 175° C. in zone 4; and 105 to 110° C. in a confluence core, and wherein said first cooling is water cooling, and wherein said second cooling under vacuum has a temperature from −10 to −15° C.

6. The method of claim 1 , wherein the mixing and heating comprises mixing at a speed of 450 r/min for 1.1 hours at a temperature of 101° C., followed by mixing at a speed of 80 r/min for 40 minutes at a temperature of 31° C.

7. A composite material prepared by the method according to claim 1 ,
wherein the PVC resin is from 50 to 70 parts by mass; the activated calcium carbonate is from 16 to 30 parts by mass; the plant fiber is from 2 to 6 parts by mass; the calcium stearate is from 4 to 14 parts by mass; the barium sulfate is from 2 to 8 parts by mass; the paraffin wax is from 12 to 18 parts by mass; the sodium bicarbonate is from 1 to 3 parts by mass; the zinc laurate is from 2 to 6 parts by mass; the nanometer-sized titanium dioxide is from 4 to 8 parts by mass; the organometallic salt is from 10 to 50 parts by mass; the shell powder is from 4 to 8 parts by mass; the carbon nanotube is from 2 to 4 parts by mass; the talcum powder is from 3 to 5 parts by mass; and the stabilizer is from 2 to 4 parts by mass.

8. The composite material according to claim 7 , wherein the organometallic salt is a benzoic acid metal salt represented by the following formula:

wherein n=1, 2 or 3; M is selected from copper, iron, zinc, magnesium, calcium, or combinations thereof.

9. The composite material according to claim 7 , wherein the material has an exudation rate from 0.3% to 15%.

10. The composite material according to claim 8 , wherein the material has an exudation rate from 0.3% to 15%.

Assignees

• Univ Changzhou

Inventors

• Chen Qun
• Chen Haiqun
• Lu Jian
• Fang Chunping
• Yi Wen
• Li Feng
• Wang Shuhua
• Chen Zhongjing
• Zhang Lina
• He Mingyang

Classifications

• C08L2205/03

  containing three or more polymers in a blend · CPC title

• B29C2948/9259

  Angular velocity · CPC title

• B29C48/16 Primary

  Articles comprising two or more components, e.g. co-extruded layers · CPC title

• C08K2003/262

  Alkali metal carbonates · CPC title

• B29C2948/92704

  Temperature · CPC title