Polymer composition comprising an impact modifier and method of making the same

Patent metadata

Field	Value
Publication number	US-11306175-B2
Application number	US-201616062265-A
Country	US
Kind code	B2
Filing date	Nov 3, 2016
Priority date	Dec 22, 2015
Publication date	Apr 19, 2022
Grant date	Apr 19, 2022

Abstract

The present invention relates to a polymer composition comprising a polymeric matrix and particles of an impact modifier within the polymeric matrix, wherein the impact modifier comprises at least one urethane group and the impact modifier is obtainable by reacting in situ within the polymeric matrix a) a polyol comprising a dimer fatty residue; and b) a polyisocyanate. The invention also relates to a method of making the polymer composition.

First claim

The invention claimed is:

1. A polymer composition comprising a polymeric matrix and particles of an impact modifier within the polymeric matrix, wherein the impact modifier comprises at least one urethane group and is obtained by reacting in situ within the polymeric matrix:
a) a polyester polyol comprising a dimer fatty diacid; and
b) an aromatic or aliphatic polyisocyanate,

wherein:
the polymeric matrix comprises polylactic acid (PLA),
the impact modifier is obtained by forming phase-separated particles of the polyol within a continuous phase of the polymeric matrix and then reacting the polyol with the polyisocyanate,
the polyisocyanate reacts with the polyol and with the polymeric matrix,
the polymer composition has an unnotched impact strength of at least 40 kJ/m 2 as measured by ISO 179 and an elongation at break of at least 10% as measured by ISO 527, and
the polymer composition comprises 1 to 25 wt % of the polyol and 0.1 to 10 wt % of the polyisocyanate.

2. The polymer composition according to claim 1 wherein the polyol comprises from 20 to 100 wt % of the dimer fatty diacid.

3. The polymer composition according to claim 1 wherein the polymer composition comprises from 5 to 20 wt % of the polyol.

4. The polymer composition according to claim 1 wherein the polymer composition comprises from 2 to 10 wt % of the polyisocyanate.

5. The polymer composition according to claim 1 wherein the particles of impact modifier have an average diameter of 0.1 to 10 μm which is measured by inspection of an image obtained by electron microscopy.

6. The polymer composition according to claim 1 wherein the polymer composition has an elongation at break of at least 30%.

7. A method of making a polymer composition comprising the steps of:
blending a polyester polyol comprising a dimer fatty diacid with a polymeric matrix to form phase-separated particles of the polyol within the polymeric matrix; and
forming particles of an impact modifier within the polymeric matrix by then reacting the polyol with an aromatic or aliphatic polyisocyanate, wherein the impact modifier comprises at least one urethane group,

wherein:
the polymeric matrix comprises a polylactic acid (PLA),
the polyisocyanate reacts with the polyol and with the polymeric matrix,
the polymer composition has an unnotched impact strength of at least 40 kJ/m 2 as measured by ISO 179 and an elongation at break of at least 10% as measured by ISO 527, and
the polymer composition comprises 1 to 25 wt % of the polyol and 0.1 to 10 wt % of the polyisocyanate.

8. A polymer composition obtained by the method according to claim 7 .

9. A panel, film, sheet or injection-moulded article comprising the polymer composition according to claim 1 .

10. An adhesive, coating or coated article comprising the polymer composition according to claim 1 .

11. The method according to claim 7 wherein the polyol comprises from 20 to 100 wt % of the dimer fatty diacid.

12. The method according to claim 7 wherein the polymer composition comprises from 5 to 20 wt % of the polyol.

13. The method according to claim 7 wherein the polymer composition comprises from 2 to 10 wt % of the polyisocyanate.

14. The method according to claim 7 wherein the particles of impact modifier have an average diameter of 0.1 to 10 μm which is measured by inspection of an image obtained by electron microscopy.

15. The method according to claim 7 wherein the polymer composition has an elongation at break of at least 30%.

Assignees

• Croda Int Plc

Inventors

• Smits Angela Leonarda Maria
• Knoop Johannes Rutger Idsard

Classifications

• C08G18/73 Primary

  acyclic · CPC title

• C08G18/4233

  derived from polymerised higher fatty acids or alcohols · CPC title

• C08J2375/06

  from polyesters · CPC title

• C08G18/4286

  prepared from a combination of hydroxycarboxylic acids and/or lactones with polycarboxylic acids or ester forming derivatives thereof and polyhydroxy compounds · CPC title

• C08G18/792

  formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates · CPC title