Hybrid solid-state electrolyte

Patent metadata

Field	Value
Publication number	US-11302957-B1
Application number	US-202016746593-A
Country	US
Kind code	B1
Filing date	Jan 17, 2020
Priority date	Mar 23, 2016
Publication date	Apr 12, 2022
Grant date	Apr 12, 2022

Abstract

A hybrid solid state electrolyte (SSE) can include a plurality of SSE particles suspended in a salt-in-solvent (SIS). A battery can include the hybrid SSE. The battery can be formed by at least forming the hybrid SSE in situ. Forming the hybrid SSE in situ can include: depositing, on a surface of an electrode of the battery, a mixture comprising the SSE particles and at least a portion of salt for the SIS; filling the battery with a solvent; and heating the battery to form the SIS by at least melting and/or dissolving the portion of the salt into the solvent.

First claim

What is claimed is:

1. A battery, comprising:
an electrode having a mixture deposited on at least one surface of the electrode, the mixture including a plurality of solid state electrolyte particles and at least a portion of a salt; and
a solvent, the solvent forming a hybrid solid state electrolyte in situ when the battery is subject to heat, the heating of the battery forming a salt-in-solvent by at least melting and/or dissolving at least the portion of the salt into the solvent, the hybrid solid state electrolyte formed in situ including the plurality of solid state electrolyte particles suspended in the salt-in-solvent.

2. The battery of claim 1 , wherein the solid state electrolyte particles comprise a sulfide-based solid state electrolyte.

3. The battery of claim 2 , wherein the sulfide-based solid state electrolyte comprises Li 2 S—SiS 2 —P 2 S 5 , Li 7 P 3 S 11 , and/or Li 4.34 Ge 0.73 Ga 0.24 S 4 .

4. The battery of claim 1 , wherein the solid state electrolyte particles comprise a garnet-type lithium ion-conducting oxide.

5. The battery of claim 4 , wherein the garnet-type lithium ion-conducting oxide comprises Li 7 La 3 Zr 2 O 12 .

6. The battery of claim 1 , wherein the solid state electrolyte particles comprise a ceramic ion conductor having a frame work structure that includes SiO 4 , PO 4 , and/or ZnO 4 .

7. The battery of claim 1 , wherein the salt-in-solvent includes a salt comprising lithium bis(perfluoroethylsulfonyl) imide [LiN(SO 2 CF 2 CF 3 ) 2 (LiBETI)], lithium bis [(1,1,1,3,3,3-hexafluoro-2-propoxy) sulfonyl] imide (LiN[SO 2 OCH(CF 3 ) 2 ] 2 (LiHFPSI)), lithium hexafluorophoshate (LiFP 6 ), lithium chloride (LiCl), lithium perchlorate (LiClO 4 ), lithium nitrate (LiNO 3 ), lithium bistrifluoromethanesulfonimidate (LiN(SO 2 CF 3 ) 2 (LITFSI)), and/or oligomeric bis[(perfluoroalkyl)sulfonyl]imide (fluorosulfonimide) lithium salts.

8. The battery of claim 1 , wherein the salt-in-solvent includes a solvent comprising poly glycol, propylene carbonate (PC), ethylene carbonate (EC), acetone, acetonitrile, diethyl ether, diglyme (diethylene glycol dimethyl ether), dimethyl sulfoxide, 1, 4-dioxane, ethyl acetate, methyl t-butyl ether (MTBE), N-methyl-2-pyrrolidinone (NMP), pyridine, tetrahydrofuran (THF), crown ether, fluoride, xylene, 1-methoxy-2-propyl acetate, and/or phosphorus.

9. The battery of claim 1 , wherein the salt-in-solvent further includes a gelling agent comprising a polymer.

10. The battery of claim 1 , wherein the salt-in-solvent comprises a concentrated liquid electrolyte without any free solvent molecules.

11. The battery of claim 1 , wherein the battery is heated to a temperature of 60° C.-70° C.

Assignees

• American Lithium Energy Corp

Inventors

• Fan Jiang

Classifications

• H01M2300/0085

  Immobilising or gelification of electrolyte · CPC title

• H01M2300/0071

  Oxides · CPC title

• H01M10/0567

  characterised by the additives · CPC title

• H01M10/0569

  characterised by the solvents · CPC title

• H01M10/052 Primary

  Li-accumulators · CPC title