Process for reducing the amount of carbon disulphide (CS2) in a hydrocarbon feed

Patent metadata

Field	Value
Publication number	US-11299681-B2
Application number	US-201716325028-A
Country	US
Kind code	B2
Filing date	Aug 12, 2017
Priority date	Aug 12, 2016
Publication date	Apr 12, 2022
Grant date	Apr 12, 2022

Abstract

The present disclosure relates to a process for reducing the amount of carbon disulphide (CS2) in a hydrocarbon feed containing C5-C8 fractions. The hydrocarbon feed is treated with an amine functionalized anion exchange resin (basic anion exchange resin) to obtain a mixture comprising a liquid fraction containing treated hydrocarbon and a solid mass containing an adduct of CS2 and the amine functionalized anion exchange resin. The so obtained liquid fraction containing the treated hydrocarbon is separated from the solid mass to obtain the hydrocarbon having CS2 content less than 2 ppm. The amine functionalized anion exchange resin can be regenerated from the solid mass.

First claim

The invention claimed is:

1. A process for reducing the amount of CS 2 in hydrocarbon feed; said process comprising the following steps:
i. treating said hydrocarbon feed with an amine functionalized anion exchange resin at a pre-determined temperature, and at a pre-determined pressure, for a pre-determined time period, to obtain a mixture comprising a liquid fraction and a solid mass; wherein said liquid fraction comprises a treated hydrocarbon having reduced CS 2 ; and said solid mass comprises an adduct of CS 2 and said amine functionalized anion exchange resin;
ii. separating said solid mass from said liquid fraction to obtain said treated hydrocarbon having CS 2 content less than CS 2 content of said hydrocarbon feed; and
iii. optionally, regenerating said amine functionalized anion exchange resin from said solid mass,

wherein, said amine is a secondary amine selected from the group consisting of diethyl amine, dimethyl amine, di-isopropyl amine, di-n-propyl amine, dibutyl amine, and dibenzyl amine;
wherein said anion exchange resin is at least one selected from the group consisting of styrene divinylbenzene, polyethylene amine, and polyacrylamide.

2. The process as claimed in claim 1 , wherein said hydrocarbon feed is petrochemical naphtha comprising C 5 -C 8 fractions.

3. The process as claimed in claim 1 , wherein the CS2 content of said hydrocarbon feed is more than 6 ppm before treatment and the content of CS2 in said treated hydrocarbon is less than 2 ppm after treatment.

4. The process as claimed in claim 1 , wherein said pre-determined temperature is in the range of 20° C. to 40° C.

5. The process as claimed in claim 1 , wherein said pre-determined pressure is in the range of 1 bar to 5 bar.

6. The process as claimed in claim 1 , wherein said pre-determined time period is in the range of 1 hour to 10 hours.

7. The process as claimed in claim 1 , wherein said process is a continuous process.

8. A process for regenerating said amine functionalized anion exchange resin from said solid mass as claimed in claim 1 , said process comprising the following steps:
a. treating said solid mass obtained in step iii) of claim 1 with at least one first fluid medium to obtain a first biphasic mixture comprising an organic layer and a solid mass;
b. separating said organic layer comprising said first fluid medium from said first biphasic mixture to obtain a first residue;
c. treating said first residue with at least one second fluid medium to obtain a second biphasic mixture comprising an organic layer and a solid mass;
d. separating said organic layer comprising said second fluid medium from said second biphasic mixture to obtain a second residue;
e. treating said second residue with a pre-determined amount of an aqueous acid to obtain a first resultant mixture, followed by washing said first resultant mixture with water to obtain a third residue and a first effluent;
f. treating said third residue with a pre-determined amount of an aqueous base to obtain a second resultant mixture, followed by washing said second resultant mixture to obtain a fourth residue and a second effluent; and
g. treating said fourth residue with at least one third fluid medium to obtain said regenerated amine functionalized anion exchange resin.

9. The process as claimed in claim 8 , wherein said acid is at least one selected from the group consisting of H 2 SO 4 , HNO 3 and HCl.

10. The process as claimed in claim 8 , wherein the concentration of said acid is in the range of 1% to 5%.

11. The process as claimed in claim 8 , wherein said base is at least one selected from the group consisting of NaOH, KOH, and Ca(OH) 2 .

12. The process as claimed in claim 8 , wherein the concentration of said base is in the range of 1% to 5%.

13. The process as claimed in claim 8 , wherein said first fluid medium is at least one selected from the group consisting of toluene, hexane, benzene, ethylbenzene, and cyclohexane.

14. The process as claimed in claim 8 , wherein said second fluid medium, and said third fluid medium are at least one independently selected from the group consisting of methanol, ethanol, propanol, isopropanol, and butanol.

Assignees

• Reliance Industries Ltd

Inventors

• Ghosh Swapan Kumar
• BAISHYA Mukunda Madhab
• Salgarkar Suyog Subhash
• Shown Biswajit
• Sulakhe Swapnil Prakash
• Bhide Vilas Shirikrishna
• Patidar Prafull
• Patel Mitra Bhanu
• Das Asit Kumar

Classifications

• C10G19/08

  Recovery of used refining agents · CPC title

• B01J41/07

  in the weakly basic form · CPC title

• C10G25/02

  with ion-exchange material · CPC title

• B01J49/57 Primary

  for anionic exchangers · CPC title

• B01J41/04

  Processes using organic exchangers · CPC title