Low speed cross-linking catalyst for silane-grafted plastomers

Patent metadata

Field	Value
Publication number	US-11299617-B2
Application number	US-201917276322-A
Country	US
Kind code	B2
Filing date	Sep 26, 2019
Priority date	Oct 2, 2018
Publication date	Apr 12, 2022
Grant date	Apr 12, 2022

Abstract

The present invention relates to silane crosslinking catalyst comprising: —75 to 85 wt.-% of an olefin acrylate interpolymer and—15 to 25 wt.-% of a hindered amine light stabilizer (HALS) having a number average molecular weight Mn of 1500 to 4000 g/mol; and—optionally up to 5 wt.-% wax, wherein the silane crosslinking catalyst is free of tin, carboxylic acid(s) and sulphonic acid(s), all weight percentages with respect to the total weight of the silane crosslinking catalyst.

First claim

The invention claimed is:

1. A silane crosslinking catalyst comprising
 75 to 85 wt.-% of an olefin acrylate interpolymer and
 15 to 25 wt.-% of a hindered amine light stabilizer (HALS) having a number average molecular weight Mn of 1500 to 4000 g/mol; and
 optionally up to 5 wt.-% wax,
 wherein said olefin acrylate interpolymer is ethylene butyl acrylate copolymer (EBA) having a content of butyloxy group O—CH 2 —CH 2 —CH 2 —CH 3 of 15 to 20 wt.-% with respect to the ethylene butyl acrylate copolymer (EBA), and/or a melt flow rate of 5.0 to 10.0 g/10 min (ISO1133, 2.16 kg load, 190° C.);
wherein the silane crosslinking catalyst is free of tin, carboxylic acid(s), and sulphonic acid(s), and
wherein all weight percentages are with respect to the total weight of the silane crosslinking catalyst.

2. The silane crosslinking catalyst according to claim 1 , wherein
the hindered amine light stabilizer (HALS) has a melting temperature of at least 95° C.; and/or
the wax is present in an amount of 2.0 wt.-% or less with respect to the total weight of the silane crosslinking catalyst.

3. The silane crosslinking catalyst according to claim 1 , wherein the silane crosslinking catalyst does not contain a butylated reaction product of p-cresol and dicyclopentadiene.

4. The silane crosslinking catalyst according to claim 1 , wherein the silane crosslinking catalyst does not contain an alkoxysilane.

Assignees

• Borealis Ag

Inventors

• Prieto Oscar
• Oderkerk Jeroen
• Ruskeeniemi Jari-Jussi
• Hellström Stefan
• Piel Tanja
• Mileva Daniela

Classifications

• C08F255/08 Primary

  on to polymers of olefins having four or more carbon atoms · CPC title

• C08F2800/20

  as weight or mass percentages · CPC title

• C08F8/12

  Hydrolysis · CPC title

• C08L2310/00

  Masterbatches · CPC title

• C08J3/248

  Measuring crosslinking reactions · CPC title