Polyethylene sheets

Patent metadata

Field	Value
Publication number	US-11299607-B2
Application number	US-201716082026-A
Country	US
Kind code	B2
Filing date	Feb 8, 2017
Priority date	Apr 22, 2016
Publication date	Apr 12, 2022
Grant date	Apr 12, 2022

Abstract

Sheets made from metallocene-catalyzed polyethylene polymers, optionally, with other polymers, are disclosed.

First claim

What is claimed is:

1. A sheet made from at least one metallocene-catalyzed polyethylene polymer comprising from 75.0 mol % to 100.0 mol % ethylene derived units and having:
a density of from 0.910 g/cm 3 to 0.923 g/cm 3 ,
a melt index (I 2.16 ) of from 0.1 g/10 min to 1.2 g/10 min,
a melt index ratio (I 21.6 /I 2.16 ) of from 28 to 35,
a CDBI of 20% to <50%;
an orthogonal comonomer distribution, wherein the polyethylene polymer has a molecular weight range and polymer fractions across the molecular weight range vary by more than 10 wt %, and/or at least a first peak and at least a second peak in a comonomer distribution analysis, wherein the first peak has a maximum at a log (M w ) value of 4.0 to 5.4, and the second peak has a maximum at a log (M w ) value of 5.0 to 6.0, and
a weight average molecular weight (M w ) of from 150,000 g/mol to 400,000 g/mol;
wherein:
the sheet has a thickness of ≥20 mil (508 μm), has a dart drop impact strength (DIS) of ≥2,200 g, a permeance of ≤0.1 perms, and comprises a blend of the polyethylene polymer and at least one additional polymer, wherein the at least one additional polymer is a Ziegler-Natta linear low density polyethylene polymer having a density of from 0.915 g/cm 3 to 0.940 g/cm 3 and a melt index (I 2.16 ) of from 0.1 g/10 min to 1.0 g/10 min.

2. The sheet of claim 1 , wherein the sheet has a tensile strength of ≥45 lbf/in (7.9 kN/m).

3. The sheet of claim 1 , wherein the sheet has a tensile strength of ≥61.9 lbf/in (10.84 kN/m).

4. The sheet of claim 1 , wherein the sheet has a dart drop impact strength (DIS) of ≥2,500 g.

5. The sheet of claim 1 , wherein the sheet has a dart drop impact strength (DIS) of ≥3,000 g.

6. The sheet of claim 1 , wherein the sheet has zero failures (F=0) at a dart drop impact strength (DIS) of at least 2,200 g or greater.

7. The sheet of claim 1 , wherein the sheet has a permeance of ≤0.05 perms.

8. The sheet of claim 1 , wherein the polyethylene polymer has a density of from 0.910 g/cm 3 to 0.920 g/cm 3 .

9. The sheet of claim 1 , wherein the polyethylene polymer has a melt index (I 2.16 ) of from 0.2 g/10 min to 1.1 g/10 min.

10. The sheet of claim 1 , wherein the polyethylene polymer has a melt index (I 2.16 ) of from 0.4 g/10 min to 1.0 g/10 min.

11. The sheet of claim 1 , wherein the polyethylene polymer has a melt index ratio (I 21.6 /I 2.16 ) of from 28 to 32.

12. The sheet of claim 1 , wherein the polyethylene polymer has a melt index ratio (I 2.16 /I 2.16 ) of from 28 to 31.

13. The sheet of claim 1 , wherein the polyethylene polymer has a melt strength of from 1 to 25 cN.

14. The sheet of claim 1 , wherein the polyethylene polymer has a melt strength of from 3 to 15 cN.

15. The sheet of claim 1 , wherein the sheet comprises two or more layers.

16. The sheet of claim 15 , wherein the two or more layers comprise at least one skin layer, a core layer, and optionally, one or more intermediary layers.

17. The sheet of claim 16 , wherein at least one of the skin layer, the core layer, or optional intermediary layer comprises from 30 wt % to 100 wt % of the polyethylene polymer, based upon the total weight of the skin layer, the core layer, or optional intermediary layer.

18. The sheet of claim 16 , wherein at least one of the skin layer, the core layer, or optional intermediary layer comprises from 50 wt % to 100 wt % of the polyethylene polymer, based upon the total weight of the skin layer, the core layer, or optional intermediary layer.

19. An industrial or construction liner comprising the sheet of any one of claim 1 .

Assignees

• Exxonmobil Chemical Patents Inc
• Exxon Mobil Chemical Patents Inc

Inventors

• Gururajan Giriprasath
• Li Wen
• Dunaway David B
• Best Steven A
• Lernoux Etienne R H

Classifications

• C08L2207/066

  LDPE (radical process) · CPC title

• B32B27/20

  using fillers, pigments, thixotroping agents · CPC title

• B32B2307/732

  Dimensional properties · CPC title

• B32B2250/04

  4 layers · CPC title

• B32B2250/242

  All polymers belonging to those covered by group B32B27/32 · CPC title