Method of preparing conjugated diene-based polymer and apparatus for preparing conjugated diene-based polymer

Patent metadata

Field	Value
Publication number	US-11299565-B2
Application number	US-201916489544-A
Country	US
Kind code	B2
Filing date	Jan 11, 2019
Priority date	Feb 9, 2018
Publication date	Apr 12, 2022
Grant date	Apr 12, 2022

Abstract

A method of preparing a conjugated diene-based polymer is provided including: a step of polymerizing a first conjugated diene-based monomer in solution in a first polymerization reactor to prepare a first polymer solution including a first conjugated diene-based polymer; a step of polymerizing a second conjugated diene-based monomer in solution in a second polymerization reactor to prepare a second polymer solution including a second conjugated diene-based polymer; a step of supplying a first fluid separated from the first polymer solution to a first purification unit and purifying the first fluid; and a step of supplying a second fluid separated from the second polymer solution to a second purification unit and purifying the second fluid. An apparatus for preparing a conjugated diene-based polymer is also provided.

First claim

The invention claimed is:

1. A method of preparing a conjugated diene-based polymer, comprising:
polymerizing a first conjugated diene-based monomer in solution in a first polymerization reactor to prepare a first polymer solution including a first conjugated diene-based polymer (S 10 );
polymerizing a second conjugated diene-based monomer in solution in a second polymerization reactor to prepare a second polymer solution including a second conjugated diene-based polymer (S 20 );
supplying a first fluid separated from the first polymer solution to a first purification unit and purifying the first fluid (S 30 ); and
supplying a second fluid separated from the second polymer solution to a second purification unit and purifying the second fluid (S 40 ), wherein
the first purification unit comprises a first feed tank, a first column connected to the first feed tank, and a first′ column connected to the first column,
the second purification unit comprises a second feed tank, a second column connected to the second feed tank, and a second′ column connected to the second column,
a fluid discharged from an upper portion of the first column is supplied to the second feed tank, and
the first feed tank is supplied with a third fluid from the second feed tank.

2. The method of preparing a conjugated diene-based polymer of claim 1 , wherein the first conjugated diene-based polymer is prepared in a solvent having a purity of 99.5% or more, and
the second conjugated diene-based polymer is prepared in a solvent having a purity of 95.0% or more.

3. The method of preparing a conjugated diene-based polymer of claim 1 , wherein the first conjugated diene-based polymer is a lanthanide rare earth element compound catalyzed conjugated diene-based polymer or an alkali metal compound catalyzed conjugated diene-based polymer, and
the second conjugated diene-based polymer is a transition metal compound catalyzed conjugated diene-based polymer.

4. The method of preparing a conjugated diene-based polymer of claim 1 , wherein the fluid discharged from the upper portion of the first column includes C4 compounds and a solvent, and the solvent is included at 10 wt % or more based on a total content of the fluid.

5. The method of preparing a conjugated diene-based polymer of claim 1 , wherein a fluid discharged from a lower portion of the first column is supplied to the first′ column, and the fluid discharged from the lower portion of the first column includes less than 0.5 wt % of C4 compounds.

6. The method of preparing a conjugated diene-based polymer of claim 1 , wherein a fluid discharged from the lower portion of the first column is supplied to the first′ column, and the fluid discharged from the lower portion of the first column includes 0.21 wt % or less of C4 compounds.

7. The method of preparing a conjugated diene-based polymer of claim 1 , wherein a fluid discharged from the lower portion of the first column is supplied to the first′ column, and the fluid discharged from the lower portion of the first column includes less than 40 ppm of moisture.

8. The method of preparing a conjugated diene-based polymer of claim 7 , wherein the fluid discharged from the lower portion of the first column is supplied to the first′ column, and the fluid discharged from the lower portion of the first column includes 25 ppm or less of moisture.

9. The method of preparing a conjugated diene-based polymer of claim 1 , comprising:
supplying a fluid discharged from the lower portion of the first column to the first′ column (S 50 ); supplying a fluid discharged from a lower portion of the second column to the second′ column (S 60 ); supplying a solvent purified from the first′ column to the first polymerization reactor (S 70 ); and supplying a solvent purified from the second′ column to the second polymerization reactor (S 80 ).

10. An apparatus for preparing a conjugated diene-based polymer, comprising:
an apparatus for preparing a first conjugated diene-based polymer comprising a first polymerization reactor for polymerizing a first conjugated diene-based polymer in solution and a first purification unit for purifying a first fluid separated from a first polymer solution prepared in the first polymerization reactor; and
an apparatus for preparing a second conjugated diene-based polymer comprising a second polymerization reactor for polymerizing a second conjugated diene-based polymer in solution and a second purification unit for purifying a second fluid separated from a second polymer solution prepared in the second polymerization reactor, wherein
the first purification unit comprises a first feed tank, a first column connected to the first feed tank, and a first′ column connected to the first column,
the second purification unit comprises a second feed tank, a second column connected to the second feed tank, and a second′ column connected to the second column,
an upper portion of the first column is connected to the second feed tank by a connecting pipe for supplying a fluid discharged from the upper portion of the first column to the second feed tank, and
the second feed tank is connected to the first feed tank by a connecting pipe for supplying a third fluid to the first feed tank.

11. The apparatus for preparing a conjugated diene-based polymer of claim 10 , wherein the first column and the second column comprise a condenser in an upper portion of a tower, respectively.

12. The apparatus for preparing a conjugated diene-based polymer of claim 10 , wherein the first column and the second column comprise a reboiler in a lower portion of a tower, respectively.

13. The method of preparing a conjugated diene-based polymer of claim 1 , wherein the fluid discharged from the upper portion of the first column includes C4 compounds and a solvent, and the solvent is included at 10 wt % to 80 wt % based on a total content of the fluid.

Assignees

• Lg Chemical Ltd

Inventors

• Jeong Hoi In
• Ko Jun Seok
• Hwang Woo Sung
• Kim Dong Min
• Lee Jeong Seok

Classifications

• B01D3/14

  Fractional distillation {or use of a fractionation or rectification column} · CPC title

• C08F2/01

  characterised by special features of the polymerisation apparatus used · CPC title

• C08F36/04 Primary

  conjugated · CPC title

• C08F2/04

  Polymerisation in solution (C08F2/32 takes precedence) · CPC title

• C08F236/10

  with vinyl-aromatic monomers · CPC title