Method for producing nanoparticles from a liquid mixture

Patent metadata

Field	Value
Publication number	US-11299394-B2
Application number	US-201816494695-A
Country	US
Kind code	B2
Filing date	Mar 16, 2018
Priority date	Mar 17, 2017
Publication date	Apr 12, 2022
Grant date	Apr 12, 2022

Abstract

A process for the production of nanoparticles from a liquid mixture comprising at least one precursor and at least one solvent in a reactor with continuous through-flow comprises the steps of feeding at least one oxygen-containing gas inflow stream having a temperature into the at least one reactor, adding at least one fuel having a temperature to the oxygen-containing gas inflow stream, wherein the fuel and the oxygen-containing gas inflow stream form a homogeneous ignitable mixture having a temperature, wherein the temperature of the homogeneous ignitable mixture is above the autoignition temperature of the homogeneous ignitable mixture, introducing at least one precursor-solvent mixture into the homogeneous ignitable mixture; autoignition of the ignitable mixture of oxygen-containing gas and fuel after an ignition delay time to form a stabilized flame and reacting the precursor-solvent mixture in the stabilized flame to form nanoparticles from the metal salt precursor, removing the formed nanoparticles.

First claim

The invention claimed is:

1. A process for the production of nanoparticles from a liquid mixture comprising at least one precursor and at least one solvent in a reactor with continuous through-flow, comprising:
a) feeding at least one oxygen-containing gas inflow stream having a temperature T I in a range between 900 and 1400 K and a flow velocity v IM of 5 to 200 m/s into a first section A of the at least one reactor,
b) adding at least one fuel having a temperature T F in a range between 300 and 500 K to the oxygen-containing gas inflow stream, wherein the addition of the at least one fuel takes place in a second section B of the reactor provided downstream of the first section A, wherein the fuel and the oxygen-containing gas inflow stream form a homogeneous ignitable mixture having a temperature T IM , wherein the temperature of the homogeneous ignitable mixture T IM is below the temperature T I of the oxygen-containing gas inflow stream and is above the autoignition temperature T AIM of the homogeneous ignitable mixture, wherein the air ratio λ of the ignitable mixture is in a range between 1 and 10,
c) spraying at least one precursor-solvent mixture into the homogeneous ignitable mixture in a third section C of the reactor,
d) autoignition of the ignitable mixture of oxygen-containing gas and fuel after an ignition delay time t ID of 1 ms to 200 ms in a fourth section D of the reactor provided downstream of the second section B and the third section C to form a stabilized flame with a turbulent flame velocity v F , wherein the flow velocity v IM is greater than the turbulent flame velocity v F such that a blowback of the flame to the fuel addition site is prevented, and reacting the precursor-solvent mixture in the stabilized flame to form nanoparticles from the metal salt precursor, and
e) removing the nanoparticles formed from the reactor.

2. The process as claimed in claim 1 , wherein the homogeneous ignitable mixture has a flow velocity v IM in the reactor that is greater than the turbulent flame velocity v F of the flame formed from the ignitable mixture in step d) through autoignition.

3. The process as claimed in claim 1 , wherein the flow velocity v IM of the oxygen-containing gas inflow stream is in a range between 10 and 100 m/s.

4. The process as claimed in claim 1 , wherein the oxygen-containing gas used is air or a mixture of oxygen with at least one inert gas.

5. The process as claimed in claim 1 , wherein the at least one fuel is a gaseous fuel and/or a liquid fuel.

6. The process as claimed in claim 1 , wherein the air ratio λ of the ignitable mixture is in a range between 1 to 3.

7. The process as claimed in claim 1 , wherein the at least one precursor is a metal salt selected from the group of aluminum, barium, bismuth, calcium, cerium, iron, magnesium, platinum, palladium, strontium, titanium, zirconium, manganese, chromium, zinc, copper, nickel, cobalt, yttrium, silver, vanadium, molybdenum or other metals or metalloids.

8. The process as claimed in claim 1 , wherein the precursor-solvent mixture is injected/sprayed into the homogeneous ignition mixture through at least one nozzle or atomizer.

9. The process as claimed in claim 8 , wherein the precursor-solvent mixture is injected using an ultrasonic atomizer or a pressure-controlled injection nozzle.

10. The process as claimed in claim 1 , wherein the solvent for the metal salt-precursor-solvent mixture is selected from a group including water or an organic solvent.

11. The process as claimed in claim 1 , wherein the ignition delay time t ID is in a range between 1 μs to 1 s.

12. The process as claimed in claim 1 , wherein the nanoparticles produced have a particle diameter with a d95 value of less than 1000 nm.

13. The process as claimed in claim 1 , wherein the oxygen-containing gas used is air or a mixture of oxygen with at least one inert gas selected from the group consisting of nitrogen, carbon dioxide, and argon.

Assignees

• Univ Berlin Tech

Inventors

• Schimek Sebastian
• Paschereit Christian Oliver
• Sieber Moritz

Classifications

• B01J21/04

  Alumina · CPC title

• C01F7/304

  of organic aluminium compounds · CPC title

• C01G9/02

  Oxides; Hydroxides · CPC title

• C01G45/02

  Oxides · CPC title

• B01J23/745

  Iron · CPC title