Three-dimensional printing

Patent metadata

Field	Value
Publication number	US-11298876-B2
Application number	US-201816605377-A
Country	US
Kind code	B2
Filing date	Jun 19, 2018
Priority date	Jun 19, 2018
Publication date	Apr 12, 2022
Grant date	Apr 12, 2022

Abstract

An example of a three-dimensional (3D) printing kit includes a build material composition and a fusing agent to be applied to at least a portion of the build material composition during 3D printing. The build material composition includes a polyamide having: an avalanche angle ranging from about 35 degrees to about 55 degrees; a break energy ranging from about 25 kJ/kg to about 57 kJ/kg; and an avalanche energy ranging from about 7 kJ/kg to about 22 kJ/kg. The fusing agent includes an energy absorber to absorb electromagnetic radiation to coalesce the polyamide in the at least the portion.

First claim

What is claimed is:

1. A three-dimensional (3D) printing kit, comprising:
a build material composition including a polyamide having:
an avalanche angle ranging from about 35 degrees to about 55 degrees;
a break energy ranging from about 25 kJ/kg to about 57 kJ/kg; and
an avalanche energy ranging from about 7 kJ/kg to about 22 kJ/kg; and

a fusing agent to be applied to at least a portion of the build material composition during 3D printing, the fusing agent including an energy absorber to absorb electromagnetic radiation to coalesce the polyamide in the at least the portion.

2. The 3D printing kit as defined in claim 1 wherein the polyamide has a dynamic density within about 15% of a bulk density of the polyamide.

3. The 3D printing kit as defined in claim 1 wherein one of:
(i) the polyamide is a polyamide 12, the avalanche angle ranges from about 36 degrees to about 40 degrees, the break energy ranges from about 27 kJ/kg to about 37 kJ/kg, and the avalanche energy ranges from about 7 kJ/kg to about 17 kJ/kg; or
(ii) the polyamide is a polyamide 11, the avalanche angle ranges from about 44 degrees to about 52 degrees, the break energy ranges from about 38 kJ/kg to about 57 kJ/kg, and the avalanche energy ranges from about 8 kJ/kg to about 22 kJ/kg; or
(iii) the polyamide is a polyamide 12-GB, the avalanche angle ranges from about 40 degrees to about 48 degrees, the break energy ranges from about 32 kJ/kg to about 50 kJ/kg, and the avalanche energy ranges from about 7 kJ/kg to about 19 kJ/kg; or
(iv) the polyamide is a polyamide 6,13, the avalanche angle ranges from about 38 degrees to about 45 degrees, the break energy ranges from about 28 kJ/kg to about 40 kJ/kg, and the avalanche energy ranges from about 8 kJ/kg to about 15 kJ/kg.

4. The 3D printing kit as defined in claim 1 wherein one of:
(i) the polyamide is a polyamide 12 having a dynamic density ranging from about 0.34 g/cc to about 0.38 g/cc; or
(ii) the polyamide is a polyamide 11 having a dynamic density ranging from about 0.44 g/cc to about 0.48 g/cc; or
(iii) the polyamide is a polyamide 12-GB having a dynamic density ranging from about 0.42 g/cc to about 0.49 g/cc; or
(iv) the polyamide is a polyamide 6,13 having a dynamic density ranging from about 0.43 g/cc to about 0.48 g/cc.

5. The 3D printing kit as defined in claim 1 , further comprising a coloring agent selected from the group consisting of a black agent, a cyan agent, a magenta agent, and a yellow agent.

6. The 3D printing kit as defined in claim 1 , further comprising a detailing agent including a surfactant, a co-solvent, and water.

7. The 3D printing kit as defined in claim 1 wherein the fusing agent is a core fusing agent and the energy absorber has absorption at least at wavelengths ranging from 400 nm to 780 nm.

8. The 3D printing kit as defined in claim 7 , further comprising a primer fusing agent including a plasmonic resonance absorber having absorption at wavelengths ranging from 800 nm to 4000 nm and having transparency at wavelengths ranging from 400 nm to 780 nm.

9. The 3D printing kit as defined in claim 1 wherein the fusing agent is a primer fusing agent and the energy absorber is a plasmonic resonance absorber having absorption at wavelengths ranging from 800 nm to 4000 nm and having transparency at wavelengths ranging from 400 nm to 780 nm.

10. A method for three-dimensional (3D) printing, comprising:
applying a build material composition to form a build material layer, the build material composition including a polyamide having:
an avalanche angle ranging from about 35 degrees to about 55 degrees;
a break energy ranging from about 25 kJ/kg to about 57 kJ/kg; and
an avalanche energy ranging from about 7 kJ/kg to about 22 kJ/kg;

based on a 3D object model, selectively applying a fusing agent on at least a portion of the build material layer; and
exposing the build material layer to electromagnetic radiation to coalesce the build material composition in the at least the portion to form a layer of a 3D object.

11. The method as defined in claim 10 , further comprising:
iteratively applying individual build material layers of the build material composition;
based on the 3D object model, selectively applying the fusing agent to at least some of the individual build material layers to define individually patterned layers, wherein the fusing agent is selected from the group consisting of a core fusing agent, a primer fusing agent, or both the core fusing agent and the primer fusing agent; and
iteratively exposing the individually patterned layers to the electromagnetic radiation to form individual object layers, wherein each of the individual object layers is selected from the group consisting of a core layer, a primer layer, or a layer including a core portion and a primer portion.

12. A method for three-dimensional (3D) printing, comprising:
based on a 3D object model, selectively applying a core fusing agent on at least a portion of a first layer of a build material composition, the build material composition including a polyamide having:
an avalanche angle ranging from about 35 degrees to about 55 degrees;
a break energy ranging from about 25 kJ/kg to about 57 kJ/kg; and
an avalanche energy ranging from about 7 kJ/kg to about 22 kJ/kg;

exposing the first layer to electromagnetic radiation to fuse the build material composition in the at least the portion of the first layer to form a core layer;
applying a second layer of the build material composition on the core layer;
based on the 3D object model, selectively applying a primer fusing agent on at least a portion of the second layer, the primer fusing agent including a plasmonic resonance absorber having absorption at wavelengths ranging from 800 nm to 4000 nm and having transparency at wavelengths ranging from 400 nm to 780 nm; and
exposing the second layer to electromagnetic radiation to fuse the build material composition in the at least the portion of the second layer to form a primer layer.

13. The method as defined in claim 12 , further comprising:
applying a third layer of the build material composition on the primer layer;
based on the 3D object model, selectively applying a coloring agent and (i) the core fusing agent or (ii) the primer fusing agent on at least a portion of the third layer; and
exposing the third layer to electromagnetic radiation to fuse the build material composition in the at least the portion of the third layer to form a colored layer having a colorant of the coloring agent embedded therein.

14. The method as defined in claim 13 , further comprising applying the coloring agent on the colored layer.

15. The method as defined in claim 14 , further comprising applying a detailing agent with the coloring agent.

Assignees

• Hewlett Packard Development Co

Inventors

• Fung Erica
• Fleischmann Carolin
• Tandy Jesiska
• Querol Esparch Carmina
• Long Greg S
• Emamjomeh Ali
• Woodruff Shannon Reuben
• Donovan Rachael
• Flack Kenneth

Classifications

• B33Y10/00 Primary

  Processes of additive manufacturing · CPC title

• B29C64/165 Primary

  using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber · CPC title

• B29K2077/00

  Use of {PA, i.e.} polyamides, e.g. polyesteramides {or derivatives thereof}, as moulding material · CPC title

• B29C64/282

  of the same type, e.g. using different energy levels · CPC title

• B29K2995/0063

  Density · CPC title