Hydrogenation catalyst and method for preparing the same

Patent metadata

Field	Value
Publication number	US-11298688-B2
Application number	US-201616063922-A
Country	US
Kind code	B2
Filing date	Dec 20, 2016
Priority date	Dec 21, 2015
Publication date	Apr 12, 2022
Grant date	Apr 12, 2022

Abstract

The invention relates to a method for preparing a hydrogenation catalyst or catalyst precursor comprising a catalytically active material and a carrier material. The method involves the mixing of an acidic solution comprising metal ions of a metal selected from the IUPAC group 8, 9 or 10 metals, preferably cobalt, a suspension comprising the carrier material and an alkaline solution. The invention also relates to a precursor of a hydrogenation catalyst wherein the precursor comprises crystallites of metal oxides having an average size of max. 8 nm.

First claim

That which is claimed is:

1. A method for preparing a hydrogenation catalyst comprising a catalytically active material and a carrier material, the method comprising:
providing an acidic solution comprising cobalt ions, a suspension comprising titania as carrier material, and an alkaline solution comprising a carbonate containing salt,
wherein one or more of the alkaline solution and the suspension further comprises one of a carboxylic acid and a conjugated base thereof,
wherein the conjugated base of the carboxylic acid is present at least in the alkaline solution and wherein the carboxylic acid and the conjugated base thereof have at least two carboxylic acid groups having a pKa value in the range of 4.0-6.5; and
mixing the acidic solution, the suspension, and the alkaline solution causing the cobalt to precipitate in the presence of the carrier material to form a mixture comprising a metal precipitate.

2. The method according to claim 1 , wherein the carboxylic acid and the conjugated base thereof comprise a hydroxyl group on an alpha carbon position.

3. The method according to claim 1 , wherein the carboxylic acid and the conjugated base thereof is selected from the group consisting of citric acid, malic acid, tartaric acid, gluconic acid, and combinations thereof.

4. The method according to claim 1 , wherein the pH of the mixture is raised to a pH of at least 5.5.

5. The method according to claim 1 , wherein the temperature of the mixture is maintained at a temperature of maximally 100° C.

6. The method according to claim 1 , further comprising separating the precipitate from the mixture to obtain a catalyst precursor as a retentate.

7. The method according to claim 6 , further comprising washing the retentate at least once with a washing medium.

8. The method according to claim 7 , further comprising drying the retentate.

9. The method according to claim 1 , wherein the alkaline solution is added after the acidic solution and the suspension have been mixed.

10. The method according to claim 1 , wherein the method is conducted batch wise such that first the alkaline solution is added to the suspension until the mixture reaches a pH of 5.5 or higher, and
wherein once the mixture reaches a pH of 5.5 or higher, the addition of the alkaline solution to the suspension is continued while simultaneously adding the acidic solution and mixing.

11. The method according to claim 1 , wherein the carboxylic acid and the conjugated base to cobalt molar ratio is from 1:15 to 1:10, during mixing.

12. The method according to claim 1 , wherein none of the acidic solution, the suspension and the alkaline solution comprises ammonia, ammonia salt and/or ammonia releasing compound.

Assignees

• Shell Oil Co

Inventors

• Klemt Andreas
• Domokos László
• FRIEDEL Frank Peter
• Boettcher Stefan
• Stobbe Erwin Roderick

Classifications

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J35/393

  Metal or metal oxide crystallite size · CPC title

• C10G2/332

  of the iron-group · CPC title

• B01J21/063

  Titanium; Oxides or hydroxides thereof · CPC title