Analysis device for determining a measurand representing a silicate concentration in a sample liquid

Patent metadata

Field	Value
Publication number	US-11293874-B2
Application number	US-201916276747-A
Country	US
Kind code	B2
Filing date	Feb 15, 2019
Priority date	Feb 16, 2018
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

The present disclosure includes to an analysis device for determining a measurand representing a silicate concentration in a sample liquid, including a housing divided into an electronics region and a fluidic region, wherein the electronics region is separated from the fluidic region by at least one wall. In the fluidic region are a measuring cell, a sample feed line connected to the measuring cell, at least one liquid container having a liquid therein and connected to the measuring cell via a liquid line, and at least one pump configured to transport at least a portion of the liquid from the liquid container into the measuring cell, in which the sample feed line is connected to an over-pressurized container containing the sample liquid, where the container is arranged outside the housing. The electronics region includes an electronic control system configured to control the operation of the analysis device.

First claim

The invention claimed is:

1. An analysis device for determining a measurand representing a silicate concentration in a sample liquid, the analysis device comprising:
a housing divided into an electronics region and a fluidic region, wherein the electronics region is separated from the fluidic region by at least one wall;
a measuring cell defining a vessel and disposed within the fluidic region;
a sample feed line arranged within the fluidic region and opening into the vessel of the measuring cell, wherein the sample feed line is connected to an over-pressurized container containing the sample liquid, wherein the container is disposed outside the housing;
at least one liquid container disposed within the fluidic region and containing a liquid;
a liquid line arranged within the fluidic region, opening into the vessel of the measuring cell and connected to the at least one liquid container, wherein the liquid of the at least one liquid container is a reagent selected to react with the sample liquid to facilitate determining values of the measurand;
a heater disposed within the fluidic region of the housing and arranged upstream of the measuring cell, wherein a portion of the sample feed line extends through the heater, and wherein the heater, the sample feed line and the liquid line are respectively configured such that the sample liquid in the sample feed line is heated by the heater while the liquid line bypasses the heater;
at least one pump disposed within the fluidic region and configured to transport at least a portion of the liquid from the at least one liquid container into the vessel of the measuring cell;
an optical sensor disposed within the fluidic region, the optical sensor including a radiation source and a radiation receiver, wherein the radiation source and the radiation receiver are arranged with respect to the measuring cell such that measuring radiation emitted by the radiation source passes through the vessel of the measuring cell and impinges on the radiation receiver;
an electronic controller disposed within the electronics region and electrically connected to a drive of the at least one pump, to the radiation source and to the radiation receiver, the electronic controller configured to control the drive of the at least one pump for transporting liquid from the at least one liquid container into the measuring cell, to operate the radiation source for emitting measuring radiation, to detect electrical signals generated by the radiation receiver, and to determine the values of the measurand based upon the signals of the radiation receiver; and
a flow meter arranged fluidically in the sample feed line and configured to detect a flow of the sample liquid through the sample feed line, wherein the flow meter is arranged upstream of the heater.

2. The analysis device of claim 1 , wherein the at least one liquid container includes a plurality of liquid containers containing one liquid each, wherein all of the plurality of liquid containers are disposed within the fluidic region, and wherein the plurality of liquid containers are each connected to the measuring cell via a corresponding liquid line extending within the fluidic region.

3. The analysis device of claim 2 , wherein the at least one pump includes a pump for each of the corresponding liquid lines connecting each of the plurality of liquid containers to the measuring cell such that each pump is connected to its corresponding liquid line and configured to transport liquid from the connected liquid container through the liquid line.

4. The analysis device of claim 3 , wherein at least one of the plurality of liquid containers contains a standard solution containing silicate in a predetermined concentration, and wherein the pump connected to said liquid container via its corresponding liquid line is a peristaltic pump configured to transport standard solution to the measuring cell.

5. The analysis device of claim 2 , wherein the liquid lines of the plurality of liquid containers are each configured to bypass the heater.

6. The analysis device of claim 1 , further comprising a sample discharge line connected to the measuring cell and disposed within the fluidic region.

7. The analysis device of claim 6 , wherein the measuring cell includes an overflow in fluid communication with the sample discharge line, the overflow establishing a maximum fill-level of the measuring cell such that, when the maximum fill-level in the measuring cell is reached, liquid passes from the vessel of the measuring cell via the overflow into the sample discharge line as to ensure that a predetermine amount of the sample liquid is present in the measuring cell.

8. The analysis device of claim 1 , wherein the sample feed line includes a valve configured to selectively open or block the sample feed line to the flow of the sample liquid.

9. The analysis device of claim 1 , further comprising a pressure reducer arranged fluidically between the sample feed line and the container containing the sample liquid.

10. The analysis device of claim 9 , wherein the electronic controller is configured to control the pressure reducer based on a measurement signal from the flow meter.

11. The analysis device of claim 1 , wherein the heater is a heat exchanger or resistance heater.

Assignees

• Endress Hauser Conducta Gmbh Co Kg

Inventors

• Ingelmann Michael
• Steuerwald Ralf

Classifications

• G01N2021/0325

  Cells for testing reactions, e.g. containing reagents · CPC title

• G01N33/182 Primary

  Specific anions in water · CPC title

• G01N21/78 Primary

  producing a change of colour · CPC title

• G01N35/1095

  for supplying the samples to flow-through analysers (for a specific analyser see relevant groups, e.g. under G01N15/00, G01N21/00, G01N27/00, G01N30/00, H01J49/00) · CPC title

• G01N21/0332

  with temperature control (control of temperature G05D23/00; cryostats F17C3/08) · CPC title