Impregnate with antistatic properties

Patent metadata

Field	Value
Publication number	US-11292926-B2
Application number	US-202016835788-A
Country	US
Kind code	B2
Filing date	Mar 31, 2020
Priority date	Apr 2, 2019
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

An impregnate with antistatic properties for use in laminates or for coating wood-based panels is disclosed. A resin used for impregnating and/or coating paper may include carbon-based particles, at least one compound of the general formula (I) R1aR2bSiX(4-a-b), and/or hydrolysis products thereof. X is H, OH, or a hydrolysable moiety selected from the group including halogen, alkoxy, carboxy, amino, monoalkylamino or dialkylamino, aryloxy, acyloxy, or alkylcarbonyl. R1 is an organic moiety selected from the group including alkyl, aryl, or cycloalkyl, which may be interrupted by —O— or —NH—. R1 has at least one functional group Q1 selected from a group including a hydroxy-, amino, monoalkylamino, carboxy, mercapto, alkoxy, aldehyde, acrylic, acryloxy, methacrylic, methacryloxy, cyano, isocyano or epoxide group. R2 is a non-hydrolyzable organic moiety selected from the group including alkyl, aryl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl; a is 0, 1, 2, or 3, and b is 1, 2, 3, or 4.

First claim

The invention claimed is:

1. An antistatic impregnated and/or coated paper for use in laminates or for coating wood-based panels, wherein at least one resin used for impregnating and/or coating the paper consists of a formaldehyde containing resin and comprises:
carbon-based particles;
at least one compound having the general formula (Ia):
R 1 a SiX (4-a)   (Ia),

and/or hydrolysis products thereof,
wherein X is H, OH, or a hydrolyzable moiety selected from the group comprising halogen, alkoxy, carboxy, amino, monoalkylamino or dialkylamino, aryloxy, acyloxy, and alkylcarbonyl,
wherein R 1 is an organic moiety selected from the group comprising alkyl, aryl, C 2 -C 6 alkenyl, C 3 -C 8 cycloalkenyl, and cycloalkyl, which may be interrupted by —O— or —NH—,
wherein R 1 has at least one functional group Q 1 selected from a group comprising a hydroxy, amino, monoalkylamino, carboxy, mercapto, alkoxy, aldehyde, acrylic, acryloxy, methacrylic, methacryloxy, cyano, isocyano and epoxy group,
wherein a is 1 or 2; and

at least one further compound of the general formula (II):
R 3 c SiX (4-c)   (II),

and/or hydrolysis products thereof,
wherein X has the above meaning,
wherein R 3 is a non-hydrolyzable organic moiety selected from the group comprising alkyl, aryl, alkenyl, alkynyl, cycloalkyl, and cycloalkenyl, and
wherein c is 1, 2, or 3.

2. The antistatic impregnated and/or coated paper according to claim 1 , wherein X is selected from a group comprising H, OH, fluorine, chlorine, bromine, iodine, C 1-6 alkoxy, C 6-10 aryloxy, C 2-7 acyloxy, and C 2-7 alkylcarbonyl.

3. The antistatic impregnated and/or coated paper according to claim 1 , wherein R 1 is selected from a group comprising C 1 -C 30 alkyl, C 2 -C 6 alkenyl, C 3 -C 8 cycloalkyl, and C 3 -C 8 cycloalkenyl.

4. The antistatic impregnated and/or coated paper according to claim 1 , wherein the at least one functional group Q 1 is selected from a group comprising epoxy, hydroxy, ether, acrylic, acryloxy, methacrylic, methacryloxy, amino, alkoxy, cyano, and isocyano group.

5. The antistatic impregnated and/or coated paper according to claim 1 , wherein the non-hydrolyzable organic moiety R 3 is selected from a group comprising C 1 -C 15 alkyl, C 2 -C 6 alkenyl, C 2 -C 6 alkynyl, and C 6 -C 10 aryl.

6. The antistatic impregnated and/or coated paper according to claim 5 , wherein the non-hydrolyzable organic moiety R 3 is selected from a group comprising C 1 -C 10 alkyl.

7. The antistatic impregnated and/or coated paper according to claim 1 , wherein the paper to be impregnated and/or coated with the at least one resin is a decorative, kraft, overlay, or base paper.

8. The antistatic impregnated and/or coated paper according to claim 1 , wherein the at least one resin used for impregnation and/or coating is an aqueous formaldehyde-containing resin.

9. The antistatic impregnated and/or coated paper according to claim 8 , wherein the aqueous formaldehyde-containing resin is a melamine-formaldehyde resin, urea-formaldehyde resin, melamine-urea-formaldehyde resin, phenol-formaldehyde resin or mixtures thereof.

10. The antistatic impregnated and/or coated paper according to claim 1 , wherein the solid content of the resin is between 50 and 75% by weight.

11. The antistatic impregnated and/or coated paper according to claim 10 , wherein the solid content of the resin is between 55 and 70% by weight.

12. The antistatic impregnated and/or coated paper according to claim 11 , wherein the solid content of the resin is between 60 and 65% by weight.

13. A process for producing an antistatic impregnated and/or coated paper according to claim 1 , the process comprising the steps of:
providing a resin suspension consisting of a formaldehyde containing resin and comprising carbon-based particles, at least one compound of the general formula (Ia), and at least one further compound of the general formula (II);
providing a paper layer;
impregnating the paper layer with the resin suspension and/or coating the paper layer with the resin suspension; and
drying the impregnated and/or coated paper layer.

14. The process according to claim 13 , wherein the paper layer is impregnated with the resin suspension in an impregnation channel.

15. A laminate comprising at least one antistatic impregnated and/or coated paper according to claim 1 .

16. The laminate according to claim 15 , wherein the at least one antistatic impregnated and/or coated paper is a Kraft impregnate and/or a decorative impregnate.

17. A wood-based panel comprising at least one carrier board and at least one antistatic impregnated and/or coated paper according to claim 1 arranged on at least one side of the carrier board.

18. The wood-based panel according to claim 17 , wherein the at least one antistatic impregnated and/or coated paper is a decorative impregnate.

19. The antistatic impregnated and/or coated paper according to claim 1 , wherein the carbon based particles are carbon nanotubes or graphene.

Assignees

• Flooring Technologies Ltd

Inventors

• Gier Andreas
• Kalwa Norbert

Classifications

• B32B21/02 Primary

  the layer being formed} of fibres, chips, or particles {, e.g. MDF, HDF, OSB, chipboard, particle board, hardboard · CPC title

• C08K5/54

  Silicon-containing compounds {(C08K5/0091 takes precedence)} · CPC title

• D21H19/62

  Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• D21H21/14

  characterised by function or properties in or on the paper (D21H19/66, D21H27/02 take precedence) · CPC title

• B32B21/06

  of paper or cardboard · CPC title