Propylene-based polymer, method for producing the same, propylene-based resin composition and molded article

Patent metadata

Field	Value
Publication number	US-11292899-B2
Application number	US-201816620152-A
Country	US
Kind code	B2
Filing date	Jun 29, 2018
Priority date	Jun 30, 2017
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

An object of the present invention is to provide a highly heat resistant and highly rigid propylene-based polymer having unprecedentedly high stereoregularity. The propylene-based polymer of the present invention satisfies requirements (1) to (4) and preferably requirement (5): (1) an average meso chain length is 800 to 100,000; (2) a MFR is 0.5 to 1,000 g/10 minutes; (3) a ratio of Mw to Mn, Mw/Mn, as measured by GPC is 4.2 to 20; (4) when the ratio of a component which elutes at a temperature of 122° C. or more as measured by temperature rising elution fractionation (TREF) is A % by weight and the melt flow rate of the requirement (2) is B g/10 minutes, 100≥A≥20×EXP(−0.01×B); (5) an amount of a component soluble in n-decane at 23° C. is 0.01 to 2% by weight.

First claim

The invention claimed is:

1. A propylene-based polymer (A) which satisfies the following requirements (1) to (4):
(1) an average meso chain length is 800 to 100,000 for the propylene-based polymer (A);
(2) a melt flow rate (MFR) (ASTM D1238, 230° C., under a load of 2.16 kg) is 0.5 to 1,000 g/10 minutes;
(3) a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn), Mw/Mn, as measured by gel permeation chromatography (GPC) is 4.2 to 20; and
(4) when a ratio of a component which elutes at a temperature of 122° C. or more as measured by temperature rising elution fractionation (TREF) of all components is A % by weight and the melt flow rate of the requirement (2) is B g/10 minutes, A and B satisfy the following formula (I):
100 ≥A ≥20×EXP(−0.01 ×B )  (I).

2. A propylene-based polymer (A) which satisfies the following requirements (1) to (5):
(1) an average meso chain length is 800 to 100,000 for the propylene-based polymer (A);
(2) a melt flow rate (MFR) (ASTM D1238, 230° C., under a load of 2.16 kg) is 0.5 to 1,000 g/10 minutes;
(3) a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn), Mw/Mn, as measured by gel permeation chromatography (GPC) is 4.2 to 20;
(4) when a ratio of a component which elutes at a temperature of 122° C. or more as measured by temperature rising elution fractionation (TREF) of all components is A % by weight and the melt flow rate of the requirement (2) is B g/10 minutes, A and B satisfy the following formula (I):
100 ≥A ≥20×EXP(−0.01 ×B )  (I); and

(5) an amount of a component soluble in n-decane at 23° C. is 0.01 to 2% by weight.

3. A method for producing the propylene-based polymer (A) according to claim 1 , the method comprising polymerizing propylene in the presence of a catalyst for olefin polymerization,
wherein the catalyst for olefin polymerization is catalyst [A] comprising:
(i) a solid titanium catalyst component which comprises magnesium, titanium, halogen and an electron donor, and satisfies the following requirements (k1) to (k4),
(ii) an organosilicon compound component represented by the following formula (II) and
(iii) an organometallic compound component comprising an element of group 1, group 2 or group 13 in the periodic table, or
catalyst [B] comprising:
a pre-polymerization catalyst (p) in which propylene is pre-polymerized with the catalyst [A], the organosilicon compound component (ii) and the organometallic compound component (iii);
(k1) a titanium content is 2.5% by weight or less,
(k2) an electron donor content is 8 to 30% by weight,
(k3) an electron donor/titanium weight ratio is 7 or more, and
(k4) substantially no titanium desorbs when washed with hexane at room temperature;
R 1 Si(OR 2 ) 2 (NR 3 R 4 )  (II)

wherein R 1 represents a secondary or tertiary hydrocarbon group having 1 to 20 carbon atoms, R 2 represents a hydrocarbon group having 1 to 4 carbon atoms, R 3 represents a hydrocarbon group having 1 to 12 carbon atoms or a hydrogen atom, and R 4 represents a hydrocarbon group having 1 to 12 carbon atoms.

4. The method for producing the propylene-based polymer (A) according to claim 3 ,
wherein the solid titanium catalyst component (i) is produced by a method comprising the step of bringing, into contact with each other,
(a) solid titanium which comprises magnesium, titanium, halogen and an electron donor, wherein titanium does not desorb when washed with hexane at room temperature,
(b) an aromatic hydrocarbon,
(c) liquid titanium and
(d) an electron donor.

5. A propylene-based resin composition comprising:
20 to 80% by mass of a propylene-based block copolymer (C) comprising a propylene homopolymer unit and a propylene ⋅α-olefin copolymer unit,
1 to 50% by mass of an ethylene ⋅α-olefin copolymer (D) comprising 50 to 95% by mole of a structural unit derived from ethylene and 5 to 50% by mole of a structural unit derived from α-olefin having 3 to 20 carbon atoms, and
0 to 70% by mass of an inorganic filler (E),
the total amount of the components (C), (D) and (E) being 100% by mass,
wherein the propylene-based block copolymer (C) comprises:
60 to 99% by mass of the propylene-based polymer (A) according to claim 1 as the propylene homopolymer unit, and
1 to 40% by mass of a propylene ⋅α-olefin copolymer (B) comprising 55 to 90% by mole of a structural unit derived from propylene and 10 to 45% by mole of a structural unit derived from α-olefin having 2 to 20 carbon atoms other than propylene as the propylene ⋅α-olefin copolymer unit,
the total amount of the components (A) and (B) being 100% by mass.

6. A propylene-based resin composition comprising:
100 parts by mass of the propylene-based polymer (A) according to claim 1 and
0.01 to 10 parts by mass of a nucleating agent (F).

7. A propylene-based resin composition comprising:
70 to 99.5% by mass of at least one component selected from the group consisting of the propylene-based polymer (A) according to claim 1 and a propylene-based block copolymer (C) comprising a propylene homopolymer unit and a propylene ⋅α-olefin copolymer unit, and
0.5 to 30% by mass of an inorganic fiber (G),
the total amount of the components (A), (C) and (G) being 100% by mass,
wherein the propylene-based block copolymer (C) comprises:
60 to 99% by mass of the propylene-based polymer (A) according to claim 1 as the propylene homopolymer unit, and
1 to 40% by mass of a propylene ⋅α-olefin copolymer (B) comprising 55 to 90% by mole of a structural unit derived from propylene and 10 to 45% by mole of a structural unit derived from α-olefin having 2 to 20 carbon atoms other than propylene as the propylene ⋅α-olefin copolymer unit,
the total amount of the components (A) and (B) being 100% by mass.

8. A molded article comprising the propylene-based polymer according to claim 1 .

9. A molded article formed of the propylene-based resin composition according to claim 5 .

Assignees

• Mitsui Chemicals Inc
• Prime Polymer Co Ltd

Inventors

• Kai Yasuhiro
• Noda Naoya
• Michiue Kenji
• Itakura Keita

Classifications

• C08F10/06

  Propene · CPC title

• C08K3/346

  Clay · CPC title

• C08L2205/24

  Crystallisation aids · CPC title

• C08F2500/37

  Elution or crystallisation fractionation, e.g. as determined by. TREF or Crystaf · CPC title

• C08F110/06 Primary

  Propene · CPC title