Composite material for heat storage, method for preparation and use

Patent metadata

Field	Value
Publication number	US-11292894-B2
Application number	US-201916356495-A
Country	US
Kind code	B2
Filing date	Mar 18, 2019
Priority date	Dec 27, 2012
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

The invention describes a composite material for heat storage comprising a thermochemical material (TCM) encapsulated in a water vapour permeable polymeric material. The thermochemical material preferably comprises at least one salt, at least one salt hydrate or a mixture of these, wherein the salt is preferably capable of binding water in an exothermic reaction, such as calcium chloride. Encapsulation in a water vapour permeable polymeric material results in an improved stability, cyclability of the thermochemical material, a reduced regeneration temperature and reduced corrosion of the environment. The composite according to the invention is particularly suitable for energy storage, preferably in the field of building and construction, and more preferably in the seasonal storage of solar energy.

First claim

The invention claimed is:

1. A method of releasing heat stored in a composite material, wherein the composite material comprises a thermochemical material and a coating of a hydrophobic water vapour permeable polymeric material encapsulating said thermochemical material, and wherein the water vapour permeable polymeric material is impermeable for liquid water and is cellulose or a cellulose derivative,
wherein the method comprises:
allowing water vapor to reach the thermochemical material through said coating, and
reacting said thermochemical material with water vapor thereby releasing heat.

2. The method of claim 1 , wherein the composite material comprises at least 80 wt % of the thermochemical material.

3. The method of claim 1 , wherein the composite material comprises at least 30 wt % of the thermochemical material.

4. The method of claim 1 , wherein the composite material further comprises metal, graphite or carbon nanotubes.

5. A method of storing and releasing energy in a composite material,
wherein the composite material comprises a thermochemical material and a coating of a hydrophobic water vapour permeable polymeric material encapsulating said thermochemical material, wherein the polymeric material is impermeable for liquid water,
wherein the method comprises:
a heat storage step comprising dehydrating said thermochemical material with heat to store heat,
a step of storing the dehydrated composite material, and
a heat releasing step comprising:
allowing water vapor to reach the dehydrated thermochemical material through said coating, and
reacting said dehydrated thermochemical material with water vapour to release heat.

6. The method of claim 5 , wherein the heat storage step is carried out during summer at a temperature below 150° C. and the heat releasing step is carried out during winter.

7. The method of claim 5 , wherein the thermochemical material comprises at least one salt, at least one salt hydrate, or a mixture of these, and wherein the polymeric material has a water vapour permeability of at least 1,000×10 −13 cm 3 *cm/(cm 2 *s*Pa) at 0° C. and 1 atm, and does not absorb and hold water.

8. The method of claim 5 , wherein the heat releasing step is performed in an electric car.

Assignees

• TNO

Inventors

• Cuypers Ruud
• De Jong Adriaan Jan
• Eversdijk Jacobus
• Oversloot Hendrik Pieter
• Van 'T Spijker Johannes Christiaan
• Papen-Botterhuis Nicole Ellen

Classifications

• C08K9/10 Primary

  Encapsulated ingredients · CPC title

• C08K13/02

  Organic and inorganic ingredients · CPC title

• C08K13/04

  Ingredients characterised by their shape and organic or inorganic ingredients · CPC title

• C09K5/063

  Materials absorbing or liberating heat during crystallisation; Heat storage materials · CPC title

• C09K5/16

  Materials undergoing chemical reactions when used · CPC title