Prepreg, prepreg laminate, and fiber-reinforced composite material

Patent metadata

Field	Value
Publication number	US-11292883-B2
Application number	US-201916372805-A
Country	US
Kind code	B2
Filing date	Apr 2, 2019
Priority date	Oct 4, 2016
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

A prepreg comprising the following constituent elements (A), (B), and (C), the constituent element (C) being present in a surface layer of the prepreg: Constituent element (A): a reinforcing fiber base material; Constituent element (B): an epoxy resin composition containing a curing agent, the epoxy resin composition being cured within the range of from 90° C. to 140° C. (inclusive); and Constituent element (C): particles of a thermoplastic resin having a melting point or a glass transition temperature within the range of from 90° C. to 140° C. (inclusive).

First claim

The invention claimed is:

1. A single prepreg comprising the following constituent elements (A), (B), and (C), the constituent element (C) being present in a surface layer of the prepreg:
Constituent element (A): a reinforcing fiber base material;
Constituent element (B): an epoxy resin composition containing a curing agent, the epoxy resin composition having a cure temperature within the range of from 90° C. to 140° C. (inclusive); and
Constituent element (C): particles of a thermoplastic resin having a melting point within the range of from 90° C. to 140° C. (inclusive),
wherein 60% to 80% by mass of the constituent element (C) is present in the surface layer of the prepreg,
wherein the cure temperature of Constituent element (B) is higher than the melting temperature of Constituent element (C).

2. The prepreg according to claim 1 , wherein an average area Sa obtained by the following test method is 500 μm 2 or more:
<Test Method>
1. The prepreg is cut into a size of 300 mm x 200 mm and 20 sheets thereof are laminated to produce a prepreg laminate,
2. A vacuum bag processing is performed by overlaying the prepreg laminate with a vacuum bag, the prepreg laminate is then heated using an autoclave to 80° C. at a temperature increase rate of 4° C/min, the state of 80° C. is maintained for 4 minutes, the prepreg laminate is further heated to 125° C. at a temperature increase rate of 4° C/min, and the state of 125° C. is maintained for 30 minutes, and during a period of extracting from heating start, a pressure in the autoclave is set to 0 . 6 MPa,
3. The heated prepreg laminate is held in the autoclave until the temperature reaches 50° C. or lower at a temperature decrease rate of 3° C/min to produce a molded plate for evaluation,
4. A 20 mm square test piece is cut from the molded plate for evaluation and the cross-section of the test piece is polished,
5. A photograph of the cross-section of the test piece ( 500 magnifications) is taken using a digital microscope (manufactured by KEYENCE CORPORATION, VHX-5000),
6. Next, areas of all of respective agglomerates derived from the constituent element (C) captured in the photograph are obtained using an area measurement tool of VHX- 5000 , and
7. An average value of all the areas of the agglomerates derived from the constituent element (C) in the captured photograph is obtained as an average area Sa.

3. The prepreg according to claim 1 , wherein an average particle diameter of the constituent element (C) is from 5 μm to 80 μm (inclusive).

4. The prepreg according to claim 1 , wherein the constituent element (C) is particles of a polyamide resin.

5. The prepreg according to claim 1 , wherein a content of the constituent element (C) with respect to 100 parts by mass of the constituent element (B) is from 10 parts by mass to 30 parts by mass (inclusive).

6. The prepreg according to claim 1 wherein the constituent element (B) contains another thermoplastic resin different from the thermoplastic resin constituting the constituent element (C).

7. The prepreg according to claim 6 , wherein the another thermoplastic resin is at least one resin selected from the group consisting of polyether sulfone, a phenoxy resin, polyvinyl formal, and an acrylic block copolymer.

8. The prepreg according to claim 1 , wherein the constituent element (B) contains an epoxy resin having an oxazolidone ring skeleton.

9. The prepreg according to claim 1 , wherein the constituent element (A) is a carbon fiber base material.

10. A prepreg laminate being obtained by laminating two or more sheets of the prepreg according to claim 1 .

11. A fiber-reinforced composite material comprising the following constituent elements (A), (B), and (C′),
two or more layers A, which contains the following constituent element (A) and has the following constituent element (B) as a matrix resin, being present, the fiber-reinforced composite material having a layer of the constituent element (B) containing the following constituent element (C′) between the layers A:
Constituent element (A): a reinforcing fiber base material;
Constituent element (B): an epoxy resin composition containing a curing agent, the epoxy resin composition having a cure temperature within the range of from 90° C. to 140° C. (inclusive); and
Constituent element (C′): a thermoplastic resin having a melting point within the range of from 90° C. to 140° C. (inclusive),
wherein 60% to 80% by mass of the constituent element (C′) is present in the layer having constituent element (B),
wherein the cure temperature of Constituent element (B) is higher than the melting temperature of Constituent element (C).

Assignees

• Mitsubishi Chem Corp

Inventors

• Harada Yukihiro
• Nohara Atsushi

Classifications

• B32B5/26 Primary

  another layer {next to it} also being fibrous or filamentary {(relative arrangement of fibres or filaments of different layers B32B5/12)} · CPC title

• C08J5/243

  using carbon fibres · CPC title

• C08G59/4021 Primary

  Ureas; Thioureas; Guanidines; Dicyandiamides · CPC title

• B32B2260/023

  Two or more layers · CPC title

• B32B2307/748

  Releasability · CPC title