Polyolefin based films suitable for thermoforming

Patent metadata

Field	Value
Publication number	US-11292234-B2
Application number	US-201213613975-A
Country	US
Kind code	B2
Filing date	Sep 13, 2012
Priority date	Sep 13, 2012
Publication date	Apr 5, 2022
Grant date	Apr 5, 2022

Abstract

The present invention relates to a film structure comprising an outer layer, a core and an inner layer (or sealant layer). The outer layer comprises a polyolefinic material having a Vicat softening temperature of 85° C. or greater, and a total crystallinity in the range of 25 to 45%. The core comprises a linear low density polyethylene having a density of 0.925 g/cm3 or less, and a melt index of 4.0 g/10 min or less. The inner layer comprises linear low density polyethylene having a density of from 0.865 to 0.926 g/cm3 and a melt index of less than 4.0 g/10 minutes. The films of the present invention have less than 25% of polyethylenes having a density of 0.930 g/cm3 or greater. Further, the films of the present invention can be characterized by the substantial absence of polyamide, polyester, ethylene vinyl acetate, ionomers, polyvinyl chloride, and/or cyclic olefin polymers.

First claim

What is claimed is:

1. A film structure suitable for use in thermoforming applications, comprising:
a. an outer layer, where the outer layer comprises a combination of high density polyethylene and linear low density polyethylene, where the outer layer has a Vicat softening temperature of 90° C. or greater, a total crystallinity in the range of 25 to 45%, and where the outer layer has a melt index of less than 2.0 g/10 min;
b. a core, where the core layer comprises a linear low density polyethylene having a density of 0.925 g/cm 3 or less, and a melt index of 4.0 g/10 min or less; where the core comprises at least one layer that comprises ultra low density polyethylene or mLLDPE, and where the core layer has an overall density of less than 0.912 g/cm 3 ; and
c. an inner layer, where the inner layer comprises a linear low density polyethylene having a density of from 0.865 to 0.925 g/cm 3 and a melt index of less than 4.0 g/10 min, and up to 30% by weight of the inner layer of high pressure low density polyethylene; wherein the total amount of polyethylene having a density of 0.930 g/cm 3 or greater is less than 25% by weight of the entire film, and wherein the film structure is characterized by comprising less than 5% by weight of the film of polyamide, polyester, ethylene vinyl acetate, ionomers, polyvinyl chloride, and/or cyclic olefin polymers; wherein
the linear low density polyethylene or mLLDPE further reacted to a free radical generator peroxide, an azide or with an alkoxy amine derivative in an amount less than 900 parts derivative per million parts of total polyethylene resin with the polyethylene resin under conditions sufficient to increase the melt strength of the polyethylene resin.

2. The film structure of claim 1 wherein the film is characterized by having a penetration of probe according to ASTM D5748 at 100° C. of at least 190 mm.

3. The film structure of claim 1 wherein the film structure contains from 3 to 14 distinct layers.

4. The film structure of claim 1 wherein the film structure contains from 5 to 9 distinct layers.

5. The film structure of claim 1 wherein the core comprises from 1 to 12 distinct layers: wherein the linear low density polyethylene or mLLDPE further reacted to a free radical generator such as peroxide, an azide or with an alkoxy amine derivative in an amount less than 900 parts derivative per million parts of total polyethylene resin with the polyethylene resin under conditions sufficient to increase the melt strength of the polyethylene resin.

6. The film structure of claim 3 wherein the film structure further comprises a barrier layer, said barrier layer comprising EVOH.

7. The film structure of claim 6 further comprising tie layers on either side of the barrier layer, said tie layers comprising maleic anhydride grafted polyethylene.

8. The film structure of claim 1 wherein the linear low density polyethylene used in the inner layer has a lower density than the linear low density polyethylene used in the core layer.

9. The film structure of claim 1 wherein the film characterized by comprising less than 5% by weight of the film of polyamide, polyester, ethylene vinyl acetate, ionomers, polyvinyl chloride, and/or cyclic olefin polymers and wherein the film is characterized by having a penetration of probe according to ASTM D5748 at 100° C. of at least 190 mm.

10. The film of claim 9 wherein the film has a total thickness of less than 250 μm.

Assignees

• Gargalaka Jr Joao
• Barreneche Felipe Martinez
• Gomes Jorge Caminero
• Mazzola Nicolas Cardoso
• Dow Global Technologies Llc

Inventors

• Gargalaka Jr João
• Barreneche Felipe Martinez
• Gomes Jorge Caminero
• Mazzola Nicolas Cardoso

Classifications

• Y10T428/24992

  Density or compression of components · CPC title

• B32B2250/242

  All polymers belonging to those covered by group B32B27/32 · CPC title

• B29C51/002

  characterised by the choice of material · CPC title

• B29C48/0018

  combined with shaping by orienting, stretching or shrinking, e.g. film blowing (B29C48/0017 takes precedence) · CPC title

• B32B27/32

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title