Method for manufacturing an electrochemical component comprising a lithium metal anode and an ion-conductive inorganic material layer
US-2024234676-A9 · Jul 11, 2024 · US
US11292064B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11292064-B2 |
| Application number | US-201816642724-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 30, 2018 |
| Priority date | Aug 30, 2017 |
| Publication date | Apr 5, 2022 |
| Grant date | Apr 5, 2022 |
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A coated cutting tool includes a substrate with a coating having a total thickness of 0.25-30 μm. The coating has a first layer and a second layer, the first layer being a wear resistant PVD deposited layer having a thickness of 0.2-15 μm arranged between the substrate and the second layer, and wherein the second layer is a Cr layer.
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The invention claimed is: 1. A coated cutting tool comprising a substrate with a coating having a total thickness of 0.25-30 μm, wherein the coating includes a first layer and a second layer, and wherein the first layer is a wear resistant PVD deposited layer having a thickness of 0.2-15 μm, the first layer being arranged between the substrate and the second layer, the first layer being a (Ti 1−x Al x )N y layer with 0.1<x<0.7 and 0.6<y<1.1, or a NaCl structured (Ti 1−y Al y )N w /(Ti 1−a Si a )N b nanolaminate with sublayer thickness between 5 and 50 nm, where 0.1<v<0.7, 0.7<w<1.1, 0.02<a<0.25, and 0.7<b<1.1, or a (Ti 1−m Si m )N n layer, where 0≤m<0.25, and 0.7<n<1.1, or a (Cr 1−c Al c )N d layer, where 0.5<c<0.9, and 0.7<d<1.1, or a (Cr 1−e Al e ) 2 O 3 layer, where 0.5<e<0.9, and wherein the second layer is a Cr layer, the Cr layer being an outermost layer of the coating. 2. The coated cutting tool according to claim 1 , wherein a thickness of the Cr layer is 0.05-5 μm. 3. The coated cutting tool according to claim 1 , wherein the Cr layer is a PVD deposited layer. 4. The coated cutting tool according to claim 1 , wherein the Cr layer has a body-centered cubic structure with a crystallographic orientation relation of 0.3<R1<1, where R 1 =I (110) /(I (110) +I (200) +I (211) , and where 1 (110) , 1 (200) , and 1 (211) are the XRD peak areas as extracted from the pseudo-Voigt peak profile fitting results of θ-2θ scans obtained with CuKα radiation for the bcc structure Cr layer diffraction peaks. 5. The coated cutting tool according to claim 1 , wherein the first layer is a (Ti 1−x Al x )N y layer with 0.1<x<0.7 and 0.7<y<1.1. 6. The coated cutting tool according to claim 1 , wherein the first layer is a NaCl structure c-(Ti 1−x Al x )N y layer, where 0.1<x<0.7, and 0.7<y<1.1. 7. The coated cutting tool according to claim 5 , wherein 0.5<x<0.6. 8. The coated cutting tool according to claim 1 , wherein the first layer is a NaCl structured (Ti 1−v Al v )N w /(Ti 1−a Si a )N b nanolaminate with a sublayer thickness between 5 and 50 nm, and wherein 0.4<v<0.7 , , 0.7<w<1.1,0.02<a<0.25, and 0.7<b<1.1. 9. The coated cutting tool according to claim 1 , wherein the first layer is a (Ti 1−m Si m )N n layer, where 0<m<0.15, and 0.7<n<1.1. 10. The coated cutting tool according to claim 1 , wherein the first layer is a (Cr 1−c Al c )N d layer, where 0.5<c<0.8, and 0.7<d<1.1. 11. The coated cutting tool according to claim 1 , wherein the first layer is a (Cr 1−e Al e ) 2 O 3 layer, where 0.5<e<0.8. 12. The coated cutting tool according to claim 1 , wherein a ratio between the Cr layer thickness and the total coating thickness is between 0.01 and 2. 13. The coated cutting tool according to claim 1 , wherein the first layer has a hardness H>20 GPa. 14. The coated cutting tool according to claim 1 , wherein the first layer has a NaCl type structure and the Cr layer has a body-centered cubic structure, the ratio, R4, between the XRD peak intensity of the body-centered cubic Cr peak and the XRD peak intensity of the NaCl structure peak originating from the first layer is 0.05<R4<30, where XRD peak intensity is evaluated as the peak area extracted from the pseudo-Voigt peak profile fitting results of θ-2θ scans obtained with CuKα radiation. 15. The coated cutting tool according to claim 1 , wherein the substrate comprises at least one of the following: cemented carbide, cermet, ceramics, steel and cubic boron nitride. 16. The coated cutting tool according to claim 15 , wherein the cemented carbide includes WC and 4-15 wt % Co. 17. A method for producing of a coated cutting tool comprising the steps of: applying a substrate of cemented carbide, cermet, ceramic, steel or cubic boron nitride with a hard and wear resistant coating having a thickness of 0.25-30 μm by means of PVD (physical vapor deposition) techniques, such as cathodic arc deposition, wherein the coating includes a first layer, the first layer being a (Ti 1−x Al x )N y layer with 0.1<x<0.7 and 0.6<y<1.1, or a NaCl structured (Ti 1−y Al v )N w /(Ti 1−a Si a )N b nanolaminate with sublayer thickness between 5 and 50 nm, where 0.1<v<0.7, 0.7<w<1.1, 0.02<a<0.25, and 0.7<b<1.1, or a (Ti 1−m Si m )N n layer, where 0≤m<0.25, and 0.7<n<1.1, or a (Cr 1−c Al c )N d layer, where 0.5<c<0.9, and 0.7<d<1.1, or a (Cr 1−e Al e ) 2 O 3 layer, where 0.5<e<0.9 and a second layer, the second layer being a Cr layer arranged as an outermost layer of the coating; and growing the Cr layer by using pure Cr cathodes applying an evaporation current between 50 A and 200 A, a gas atmosphere containing pure Ar at a total gas pressure between 1.0 Pa and 7.0 Pa, and applying a deposition temperature between room temperature and 500° C. 18. The method according to claim 17 , further comprising growing a first layer being a (Ti 1−x Al x )N y -layer, with 0.1<x<0.7 and 0.7<y<1.1, between the substrate and the Cr layer, by cathodic arc evaporation with an evaporation current between 50 A and 200 A using composite and/or alloyed (Ti,Al) cathodes, and in a reactive gas atmosphere containing N 2 and optionally mixed with Ar, at a total gas pressure between 1.0 Pa and 7.0 Pa, with a negative substrate bias between 0 V and 300 V, at a temperature between 200° C. and 800° C. 19. A coated cutting tool comprising a substrate with a coating having a total thickness of 0.25-30 μm, wherein the coating includes a first layer and a second layer, and wherein the first layer is a wear resistant PVD deposited layer having a thickness of 0.2-15 μm, the first layer being arranged between the substrate and the second layer, and wherein the second layer is a Cr layer, the Cr layer being an outermost layer of the coating, wherein the Cr layer has a body-centered cubic structure with a crystallographic orientation relation of 0.3<R1<1, where R1=I (110) /(I (110) +I (200) +I (211) ), and where I (110) , 1 (200) , and 1 (211) are the XRD peak areas as extracted from the pseudo-Voigt peak profile fitting results of θ-2θ scans obtained with CuKα radiation for the bcc structure Cr layer diffraction peaks.
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