Chemical decontamination method using chelate free chemical decontamination reagent for removal of the dense radioactive oxide layer on the metal surface

Patent metadata

Field	Value
Publication number	US-11289232-B2
Application number	US-201816102797-A
Country	US
Kind code	B2
Filing date	Aug 14, 2018
Priority date	Jan 24, 2013
Publication date	Mar 29, 2022
Grant date	Mar 29, 2022

Abstract

A chemical decontamination reagent containing a reducing agent, a reductive metal ion, and an inorganic acid is provided to remove a radioactive oxide layer on a metal surface. The reagent can dissolve the radioactive oxide layer on the metal surface effectively at a relatively low temperature and enables a simple process of contacting the reagent to the radioactive oxide, thus economically effective in terms of cost and time required for the process. Since the decontamination does not use a conventional organic chelating agent such as oxalic acid, but the reducing agent as a main substance, the residuals of the reducing agent remained after decontamination can be decomposed and removed with an oxidizing agent. Due to the easy decomposition with the chemical decontamination reagent, secondary wastes can be minimized and the radionuclides remained in the decontamination reagent solution can be removed effectively.

First claim

What is claimed is:

1. A chemical decontamination method, comprising a step of contacting a chemical decontamination reagent to a metal of a nuclear power plant covered with a radioactive oxide layer at a temperature range of 70° C. to 140° C. and a pH range of 1.0 to 3.7,
Wherein the chemical decontamination reagent comprises a reducing agent, a reductive metal ion, and an acid, the acid consisting only of inorganic acid, for removal of the radioactive oxide layer on a surface of the metal, the chemical decontamination reagent being devoid of an organic chelating agent, and
wherein the reducing agent is N 2 H 4 , the reductive metal ion is Cu + , and the inorganic acid is HNO 3 or H 2 SO 4 .

2. The chemical decontamination method according to claim 1 , wherein the metal is one or more selected from the group consisting of stainless steel, Inconel steel, and zirconium alloy.

3. The chemical decontamination method according to claim 1 , wherein a concentration of the reducing agent is in a range of 5×10 −4 -0.5 M.

4. The chemical decontamination method according to claim 1 , wherein a concentration of the reductive metal ion is in a range of 1×10 −5 -0.1 M.

5. The chemical decontamination method according to claim 1 , wherein a concentration of the inorganic acid is in a range of 1×10 −4 -0.5 M.

6. The chemical decontamination method according to claim 1 , wherein the reductive metal ion is added in a form of ion or ion pair with the addition of a metal salt.

7. The chemical decontamination method according to claim 1 , wherein the metal is immersed in the chemical decontamination reagent of claim 1 .

8. The chemical decontamination method according to claim 1 , wherein the chemical decontamination reagent of claim 1 is passed through an inside of systems or loop of the nuclear power plant.

9. The chemical decontamination method according to claim 1 , wherein the method is performed for 2-26 hours.

Assignees

• Korea Atomic Energy Res
• Korea Hydro & Nuclear Power Co

Inventors

• Won Hui-Jun
• Jung Chong-Hun
• Park Sang Yoon
• Choi Wangkyu
• Park Jung-Sun
• Moon Jeikwon
• Yoon In-Ho
• Choi Byung-Seon

Classifications

• C23G1/085

  solutions containing HNO3 · CPC title

• C23G1/106

  refractory metals · CPC title

• G21F9/06 Primary

  Processing (separating different isotopes of the same chemical element B01D59/00) · CPC title

• G21F9/004 Primary

  of metallic surfaces · CPC title

• C23G1/02

  with acid solutions · CPC title