Morphology modified heterophase propylene copolymers and their products thereof

Patent metadata

Field	Value
Publication number	US-11286317-B2
Application number	US-202016802012-A
Country	US
Kind code	B2
Filing date	Feb 26, 2020
Priority date	Apr 12, 2019
Publication date	Mar 29, 2022
Grant date	Mar 29, 2022

Abstract

The present invention provides a morphology modified heterophase polymer having No-Break impact strength in the range of 500 J/m-700 J/m as per ASTM standard D256, a high melt flow index in the range of 100 g/10 min as per ASTM D1238, and a balanced flexural modulus as per ASTM standard D790. More particularly, the present invention relates to a process for the modification of morphology of heterophase propylene polymer in the presence of an initiator in the form of organic peroxide and a multifunctional unsaturated organic vinyl compound on the ex-reactor Heterophase Propylene Copolymer powder and/or pellet using special extrusion device.

First claim

The invention claimed is:

1. A process for preparing a morphology modified heterophase polymer, the process comprising:
(i) mixing a multifunctional additive and a peroxide, and adding an organic solvent to obtain a morphology modifier composition and mixing the morphology modifier composition with a heterophase polymer to obtain a a final mixture, wherein the organic solvent is added in an amount of 0.5 to 60 ml per kg of morphology modified heterophase polymer; and
(ii) extruding the final mixture to obtain the morphology modified heterophase polymer.

2. The process as claimed in claim 1 , wherein the final mixture is extruded in a twin screw extruder at a temperature in a range of 160-300° C.

3. The process as claimed in claim 1 , wherein the multifunctional additive is an unsaturated organic vinyl compound and selected from the group consisting of pentaerythritol triacrylate, pentaerythritol tetraacrylate, and butanediol diacrylate.

4. The process as claimed in claim 1 , wherein the multifunctional additive is added in an amount of 1000 to 7500 ppm of the morphology modified heterophase polymer.

5. The process as claimed in claim 1 , wherein the peroxide is selected from the group consisting of an alkyl peroxide and a peroxy ester.

6. The process as claimed in claim 1 , wherein the peroxide is added in an amount of 25 to 2000 ppm of the morphology modified heterophase polymer.

7. The process as claimed in claim 1 , wherein the organic solvent is selected from the group consisting of acetone, dichloromethane (DCM), paraffin oil, and ethanol.

8. The process as claimed in claim 1 , wherein the mixing the multifunctional additive and the peroxide is carried out at a temperature in a range of 10 to 35° C. or at a temperature below a boiling point of the organic solvent, peroxide, or multifunctional additive.

9. The process as claimed in claim 1 , wherein the mixing the multifunctional additive and the peroxide is carried out for a time in a range of 2 minutes to 30 minutes.

10. The process as claimed in claim 1 , wherein the step (i) further comprises adding an antioxidant, an acid scavenger, and a nucleating agent additive package.

11. The process as claimed in claim 1 , wherein the heterophase polymer has two different phases:
a first phase that is a propylene phase polymer; and a second phase that is an ethylene phase polymer;
wherein the propylene phase polymer comprises homo polypropylene, a copolymer of propylene and ethylene, and optionally C4-C10 alpha olefin, wherein propylene content in the propylene phase polymer is 90-95% by weight, and,
wherein the ethylene phase polymer comprises homo polyethylene and co-polymers of ethylene and C3-C10 alpha olefins, wherein ethylene content in the ethylene phase polymer is in a range of 20 to 50% by weight.

Assignees

• Indian Oil Corp Ltd

Inventors

• Kottiyath Vimal Kakkarakkal
• Sethuramalingam Saranya
• Shiva Naresh
• Singh Jatinder Dhaliwal
• Goel Vishal
• Chakrawal Ptabhu Narain
• Mishra Abhilasha
• Shashikant
• Kapur Gurpreet Singh
• RAMAKUMAR Sankara Sri Venkata

Classifications

• C08K5/14

  Peroxides · CPC title

• C08L23/12 Primary

  Polypropene · CPC title

• B29K2023/08

  Copolymers of ethylene (B29K2023/16 takes precedence) · CPC title

• C08F255/04 Primary

  on to ethylene-propylene copolymers {(C08F255/023 takes precedence)} · CPC title

• C08L23/14

  Copolymers of propene (C08L23/16 takes precedence) · CPC title