Thermoset porous composites and methods thereof

Patent metadata

Field	Value
Publication number	US-11285643-B2
Application number	US-201917290258-A
Country	US
Kind code	B2
Filing date	Oct 23, 2019
Priority date	Nov 2, 2018
Publication date	Mar 29, 2022
Grant date	Mar 29, 2022

Abstract

There is provided herein thermoset porous polymer composites a methods for producing such composites. The method comprises: preparing a mixture comprising a resin, optionally a curing agent, and dry ice; optionally casting the mixture; curing the mixture to obtain the porous composite; and optionally controlling at least one of a reaction rate and an expansion rate of the mixture during the curing.

First claim

What is claimed is:

1. A method of producing a density-graded porous polymer composite, comprising:
preparing a mixture comprising a resin, a curing agent, dry ice and optionally a filler;
casting the mixture;
curing the casted mixture to obtain the porous composite; and
controlling the reaction rate of the casted mixture to obtain a density gradient in the porous composite.

2. The method of claim 1 , wherein the controlling the reaction rate of the casted mixture comprises decreasing the reaction rate of a portion of the casted mixture.

3. The method of claim 2 , wherein the decreasing the reaction comprises exposing a portion of the casted mixture to a decreased temperature so as to generate a density gradient in the porous composite, the portion of the casted mixture exposed to the decreased temperature having a smaller pore size compared to a portion of the casted mixture not exposed to the decreased temperature.

4. The method of claim 1 , wherein the density-graded porous polymer composite comprises at least two integrally connected layers having different average pore sizes and/or average densities.

5. The method of claim 1 , wherein said method comprises:
preparing a mixture comprising a resin, a curing agent, dry ice and optionally a filler;
adding additional dry ice to the mixture;
casting the mixture;
curing the mixture to obtain the porous composite;
increasing the temperature of the mixture after casting to increase the reaction rate; and
exposing a portion of the casted mixture to a decreased temperature so as to form a density gradient in the polymer composite.

6. A method of producing a density-graded porous polymer composite, comprising:
preparing a mixture comprising a resin, a curing agent, dry ice and optionally a filler;
forming a first polymer composite layer having a first average density and/or a first average pore size; and
varying one or more parameters to obtain a second polymer composite layer having a second average density and/or a second average pore size,
wherein the parameters are chosen from amount of dry ice, time of exposure to dry ice, pressure of the mixture, temperature of the mixture, and viscosity of the mixture;

and wherein the first and second polymer composite layers are formed by a single unitary continuous material.

7. A method of producing a layered porous polymer composite, comprising:
preparing a mixture comprising a resin, a curing agent, dry ice and optionally a filler;
adding additional dry ice to the mixture;
casting the mixture;
curing the mixture to obtain the porous composite; and
exposing top and bottom portions of the casted mixture to a decreased temperature so as to form density gradients in the polymer composite.

Assignees

• Univ Laval

Inventors

• Sharifishourabi Gholamali
• Rodrigue Denis

Classifications

• C08J9/122 Primary

  Hydrogen, oxygen, CO2, nitrogen or noble gases · CPC title

• C08J2300/30

  Polymeric waste or recycled polymer · CPC title

• B29C44/0423 Primary

  by density separation · CPC title

• C08J9/34

  Chemical features in the manufacture of articles consisting of a foamed macromolecular core and a macromolecular surface layer having a higher density than the core · CPC title

• C08J2205/044

  Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter · CPC title