Acid gas removal apparatus and method

Patent metadata

Field	Value
Publication number	US-11285431-B2
Application number	US-202017012793-A
Country	US
Kind code	B2
Filing date	Sep 4, 2020
Priority date	Mar 9, 2020
Publication date	Mar 29, 2022
Grant date	Mar 29, 2022

Abstract

The embodiment provides a composite that allows the release of acid gas, even the continuous release of acid gas, at low temperature and with a high acid-gas release rate in a regeneration tower of an acid gas removal apparatus, and a regenerator and an acid gas removal apparatus, in both of which the composite is used, and a method of acid gas removal. The composite according to the embodiment is capable of separating an acid gas from an acid gas absorbent, which has absorbed the acid gas, to regenerate the acid gas absorbent, wherein the composite contains an inorganic layered compound and an aluminum-containing oxide. Also provided are a regenerator using the composite to regenerate an acid gas absorbent that has absorbed an acid gas by allowing the acid gas absorbent to release the acid gas, and an acid gas removal apparatus equipped with the regenerator.

First claim

The invention claimed is:

1. A composite capable of separating an acid gas from an acid gas absorbent, regenerating the absorbent, and comprising an inorganic layered compound and an aluminum-containing oxide.

2. The composite according to claim 1 , wherein the inorganic layered compound is a hydrotalcite-like compound.

3. The composite according to claim 1 , wherein the inorganic layered compound is represented by the following general formula (HT-a) or (HT-b):
[M1 + a1 M 3+ a2 (OH) 6 ][A n− (3-2a1)/n .maH 2 O]  (HT-a),

[M 22+ b1 M3 3+ b2 (OH) 2 ][A n− b2/n .mbH 2 O]  (HT-b)

(wherein
M1 + represents a univalent metal ion;
M2 2+ represents a divalent metal ion;
M3 3+ represents a trivalent metal ion;
A n− represents an anion with a valence of n;
0.70≤a1≤1.00;
2.7≤(a1+a2)≤3.3;
0.10≤b2≤0.40;
0.90≤(b1+b2)≤1.1; and
ma and mb are numbers each representing the amount of interlayer water).

4. The composite according to claim 3 , wherein the univalent metal ion (M1 + ) is selected from the group consisting of Li + , Na + , K + , Rb + , and Cs + , and
the divalent metal ion (M2 2+ ) is selected from the group consisting of Mg 2+ , Ca 2+ , Zn 2+ , Fe 2+ , Cu 2+ , Mn 2+ , Ni 2+ , and CO 2+ , and
the trivalent metal ion (M3 2+ ) is selected from the group consisting of Al 3+ , Cr 3+ , Fe 3+ , Co 3+ , Ga 3+ , V 3+ , and In 3+ .

5. The composite according to claim 4 , wherein the inorganic layered compound contains Li + as the univalent metal ion and Al 3+ as the trivalent metal ion.

6. The composite according to claim 1 , wherein the aluminum-containing oxide further contains at least one metal selected from the group consisting of Ti, Si, and Ce.

7. The composite according to claim 1 , wherein the aluminum-containing oxide is porous.

8. The composite according to claim 1 , wherein, in an X-ray diffraction profile of the composite, the ratio (I 2 /I 1 ) of the maximum intensity I 2 of a diffraction line in the 2θ range from 40 to 45° to the maximum intensity I 1 of a diffraction line in the 2θ range from 10 to 15° is from 0.1 to 1.0.

9. The composite according to claim 1 , wherein the composite has platy or laminar structures derived from the inorganic layered compound.

10. The composite according to claim 1 , wherein the composite has platy or laminar structures derived from the inorganic layered compound and powder structures derived from the aluminum-containing oxide.

11. A regenerator of regenerating an acid gas absorbent, comprising the composite according to claim 1 , wherein the acid gas absorbent that has absorbed an acid gas is brought into contact with the composite to separate the acid gas from the acid gas absorbent.

12. An acid gas removal apparatus comprising:
an acid gas absorbent,
an absorber that brings a subject gas mixture containing an acid gas into contact with the acid gas absorbent to make the acid gas absorbent absorb the acid gas and thereby to remove the acid gas from the subject gas mixture, and
the regenerator according to claim 11 ,
wherein the acid gas absorbent regenerated by the regenerator is reused in the absorber.

13. A method of acid gas removal, comprising:
an acid gas absorption step in which a subject gas mixture containing an acid gas is brought into contact with an acid gas absorbent to make the acid gas absorbent absorb the acid gas and thereby to remove the acid gas from the subject gas mixture, and
an acid gas separation step in which the acid gas absorbent that has absorbed the acid gas is regenerated by allowing the acid gas absorbent to release the acid gas,
wherein the regenerated acid gas absorbent is reused in the acid gas absorption step, and
wherein, in the acid gas separation step, the acid gas absorbent that has absorbed the acid gas is brought into contact with a composite comprising an inorganic layered compound and an aluminum-containing oxide to regenerate the acid gas absorbent.

14. The method according to claim 13 , wherein the acid gas absorbent is brought into contact with the composite under a temperature condition of less than 100° C. in the acid gas removal step.

Assignees

• Toshiba Kk

Inventors

• Saito Hitomi
• Sano Kenji
• Imada Toshihiro
• Suzuki Akiko

Classifications

• B01D2257/504

  Carbon dioxide · CPC title

• B01D53/78

  with gas-liquid contact · CPC title

• B01D53/18

  Absorbing units; Liquid distributors therefor (B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32) · CPC title

• B01D53/265

  by refrigeration (condensation) · CPC title

• B01D2252/204

  Amines · CPC title